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81. 发明授权

US6018007A Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst 失效
标题翻译：使用镧系元素有机酸盐催化剂合成1,4-反式聚丁二烯
公开(公告)号：US6018007A
公开(公告)日：2000-01-25
申请号：US934608
申请日：1997-09-22
申请人： Thomas J. Lynch
发明人： Thomas J. Lynch
IPC分类号： C08F4/48 , C08F4/54 , C08F36/04 , C08F36/06
CPC分类号： C08F36/04
摘要： The invention provides a catalyst composition, comprising: (a) an organolithium compound; and, (b) an organic acid salt of lanthanide series element; wherein: (1) only components (a) and (b) are required to promote the synthesis of 1,4-trans-polybutadiene; (2) the ratio of component (a) to component (b) is selected to maximize formation of the trans structure of said 1,4-trans-polybutadiene; and, (3) components (a) and (b) are selected for enabling further diblock synthesis. The invention further contemplates a process for using the catalyst to synthesize 1,4-trans-polybutadiene and other polymers and copolymers having trans configuration in the conjugated diene monomer contributed units.
摘要翻译：本发明提供一种催化剂组合物，其包含：（a）有机锂化合物; 和（b）镧系元素有机酸盐; 其中：（1）仅需要组分（a）和（b）促进1,4-反式聚丁二烯的合成; （2）选择组分（a）与组分（b）的比例以使所述1,4-反式聚丁二烯的反式结构的形成最大化; 并且（3）组分（a）和（b）被选择用于进一步进行二嵌段合成。本发明进一步考虑了使用该催化剂合成1,4-反式聚丁二烯和其它在共轭二烯单体贡献单元中具有反式构型的聚合物和共聚物的方法。

82. 发明授权

US5958820A Gas-phase polymerisation of conjugated dienes in the presence of rare earth allyl compounds 失效
标题翻译：在稀土烯丙基化合物存在下，共轭二烯的气相聚合
公开(公告)号：US5958820A
公开(公告)日：1999-09-28
申请号：US930725
申请日：1997-10-02
申请人： Rudolf Taube , Steffen Maiwald , Thomas Ruhmer , Heike Windisch , Jurgen Giesemann , Gerd Sylvester
发明人： Rudolf Taube , Steffen Maiwald , Thomas Ruhmer , Heike Windisch , Jurgen Giesemann , Gerd Sylvester
IPC分类号： C08F2/34 , C08F4/02 , C08F4/54 , C08F4/60 , C08F36/00 , C08F36/04 , C08F36/06 , B01J31/00 , B01J37/00
CPC分类号： C08F36/04
摘要： A process for polymerizing a gaseous conjugated diene by bringing it in contact with a catalyst consisting of a rare earth allyl compound, an organic aluminum compound, an inorganic support and optionally, the same or a different conjugated diene. The resulting polymers possess elevated proportions of cis-1,4 units.
摘要翻译： PCT No.PCT / EP96 / 01276 Sec。 371 1997年10月2日第 102（e）日期1997年10月2日PCT 1996年3月22日PCT公布。出版物WO96 / 31544 PCT 日期：1996年10月10日通过使气态共轭二烯与由稀土烯丙基化合物，有机铝化合物，无机载体和任选相同或不同的共轭二烯组成的催化剂接触而使气态共聚二烯聚合的方法。所得聚合物具有升高的顺式-1,4单元比例。

83. 发明授权

US5955531A Pneumatic tires having reduced rolling resistance 失效
标题翻译：具有降低滚动阻力的气动轮胎
公开(公告)号：US5955531A
公开(公告)日：1999-09-21
申请号：US120314
申请日：1993-09-13
申请人： Shingo Futamura
发明人： Shingo Futamura
IPC分类号： B60C1/00 , B60C11/00 , C08F4/58 , C08F36/06 , C08K3/04 , C08L21/00 , C08L21/02
CPC分类号： C08F36/06 , B60C1/00 , B60C1/0016 , B60C1/0025 , Y10T152/10819 , Y10T152/10846 , Y10T152/10855
摘要： An improved pneumatic tire having decreased rolling resistance employing at least one tire component selected from the group consisting of subtreads, black sidewall, body ply skims and bead fillers, prepared from a vulcanizable elastomeric composition having reduced hysteresis comprises from about 10 to 100 parts by weight of an elastomer comprising a plurality of polymer molecules, wherein substantially each polymer molecule contains at least one functional group at the site of initiation, and having a hysteresis reduction of at least about 10 percent compared to the same elastomer without a functional group on substantially each polymer molecule; from about 0 to 90 parts by weight of an elastomer having greater hysteresis than the elastomer having reduced hysteresis and selected from the group consisting of natural rubber, synthetic rubber and blends thereof; and, from about 20 to about 100 parts by weight of carbon black, per 100 parts of the elastomer. A method is also provided for reducing the rolling resistance of tires.
摘要翻译：具有降低滚动阻力的改进的充气轮胎使用至少一种选自由具有减小的滞后性的可硫化弹性体组合物制成的组，由子窗帘，黑色侧壁，身体帘布层和胎圈填料组成的组中的轮胎组分包括约10至100重量份的弹性体，其包含多个聚合物分子，其中基本上每个聚合物分子在起始位点处含有至少一个官能团，并且与基本上每个上没有官能团的相同弹性体相比，具有至少约10％的滞后减小聚合物分子; 约0至90重量份具有比具有减小的滞后性的弹性体具有更大磁滞的弹性体，并且选自天然橡胶，合成橡胶及其共混物; 和约20至约100重量份的炭黑，每100份弹性体。还提供了一种降低轮胎滚动阻力的方法。

84. 发明授权

US5877109A Catalyst for the gas-phase polymerisation of conjugated dienes 失效
标题翻译：用于共轭二烯的气相聚合的催化剂
公开(公告)号：US5877109A
公开(公告)日：1999-03-02
申请号：US930016
申请日：1997-11-10
申请人： Karl-Heinz Reichert , Peter Marquardt , Christopher Eberstein , Birgit Garmatter , Gerd Sylvester
发明人： Karl-Heinz Reichert , Peter Marquardt , Christopher Eberstein , Birgit Garmatter , Gerd Sylvester
IPC分类号： C08F4/60 , C08F2/34 , C08F4/44 , C08F4/54 , C08F36/00 , C08F36/04 , C08F36/06
CPC分类号： C08F4/54 , C08F36/04 , Y10S526/901
摘要： Catalysts comprisingA) a rare earth alkoxide, a rare earth carboxylate and/or a rare earth coordination compound with diketones,B) an alumoxane andC) an inert, particulate, inorganic solid with a specific surface area of greater than 10 m.sup.2 /g and a pore volume of 0.3 to 15 ml/gare excellently suited to the polymerisation of conjugated dienes, in particular butadiene, in the gas phase.
摘要翻译： PCT No.PCT / EP96 / 01275 Sec。 371日期：1997年11月10日 102（e）日期1997年11月10日PCT 1996年3月22日PCT公布。公开号WO96 / 31543 日期1996年10月10日催化剂包括A）稀土醇盐，稀土羧酸盐和/或与二酮的稀土配位化合物，B）铝氧烷和C）具有比表面积更大的惰性，颗粒状无机固体超过10m 2 / g，孔体积为0.3-15ml / g非常适合在气相中共轭二烯，特别是丁二烯的聚合。

86. 发明授权

US5811499A Synthesis of cis-1,4-polybutadiene rubber in presence of cobalt containing catalyst system 失效
标题翻译：在含钴催化剂体系的存在下合成顺式-1,4-聚丁二烯橡胶
公开(公告)号：US5811499A
公开(公告)日：1998-09-22
申请号：US944399
申请日：1997-10-06
申请人： Kenneth Floyd Castner
发明人： Kenneth Floyd Castner
IPC分类号： C08F4/60 , C08F4/70 , C08F36/06 , C08F136/06
CPC分类号： C08F136/06 , Y10S526/903
摘要： It has been determined that 1,3-butadiene monomer can be polymerized into cis-l,4-polybutadiene rubber utilizing a cobalt-based catalyst system which is comprised of (a) an organocobalt compound, (b) a trialkylaluminum compound and (c) hexafluoro-2-propanol. The use of this catalyst system results in extremely fast rates of polymerization. The molecular weight of the cis-1,4- polybutadiene rubber made utilizing this cobalt-based catalyst system can be regulated by conducting the polymerization in the presence of 1,5-cyclooctadiene. This present invention more specifically discloses a catalyst system which is particularly useful for polymerizing 1,3-butadiene monomer into cis-1,4-polybutadiene, said catalyst system being comprised of (a) an organocobalt compound, (b) a trialkylaluminum compound and (c) hexafluoro-2-propanol. The subject invention further discloses a process for synthesizing cis-1,4-polybutadiene rubber which comprises polymerizing 1,3-butadiene in the presence of (a) an organocobalt compound, (b) a trialkylaluminum compound and (c) hexafluoro-2-propanol.
摘要翻译：已经确定，使用钴基催化剂体系，可以将1,3-丁二烯单体聚合成顺式-1,4-聚丁二烯橡胶，所述钴基催化剂体系包括（a）有机钴化合物，（b）三烷基铝化合物和（c ）六氟-2-丙醇。使用该催化剂体系导致极快的聚合速率。使用该钴基催化剂体系制备的顺式-1,4-聚丁二烯橡胶的分子量可以通过在1,5-环辛二烯存在下进行聚合来调节。本发明更具体地公开了一种特别可用于将1,3-丁二烯单体聚合成顺式-1,4-聚丁二烯的催化剂体系，所述催化剂体系包括（a）有机钴化合物，（b）三烷基铝化合物和（c）六氟-2-丙醇。本发明还公开了一种合成顺式-1,4-聚丁二烯橡胶的方法，该方法包括在（a）有机钴化合物，（b）三烷基铝化合物和（c）六氟-2- 丙醇。

87. 发明授权

US5756606A Means to control particle size and eliminate fouling in the synthesis of syndiotactic 1,2 - polybutadiene 失效
标题翻译：控制间规1,2-聚丁二烯合成过程中颗粒尺寸和消除结垢的手段
公开(公告)号：US5756606A
公开(公告)日：1998-05-26
申请号：US861668
申请日：1997-05-22
申请人： Tang Hong Wong
发明人： Tang Hong Wong
IPC分类号： C08F2/00 , C08F2/16 , C08F4/70 , C08F136/06 , C08F36/06
CPC分类号： C08F136/06 , Y10S526/912
摘要： Syndiotactic 1,2-polybutadiene is a thermoplastic resin which has double bonds attached in an alternating fashion to its polymeric backbone. Films, fibers and molded articles can be made utilizing syndiotactic 1,2-polybutadiene. It can also be blended into rubbers and cocured therewith. It is generally preferred to synthesize syndiotactic 1,2-polybutadiene in an aqueous medium by suspension or emulsion polymerization. In such aqueous polymerization techniques reactor fouling and particle size control problems are frequently encountered. This invention is based upon the unexpected finding that reactor fouling can be greatly reduced or eliminated and that particle size can be regulated by conducting such aqueous polymerizations in the presence of a controlled amount of dissolved oxygen which is within the range of about 0.01 ppm to about 4 ppm. This invention more specifically discloses a process for preparing syndiotactic 1,2-polybutadiene in an aqueous medium with minimal reactor fouling which comprises polymerizing 1,3-butadiene monomer in the aqueous medium in the presence of (1) a catalyst system which is comprised of (a) transition metal compound, (b) an organoaluminum compound and (c) at least one member selected from the group consisting of carbon disulfide, phenyl isothiocyanate and xanthic acid and (2) from about 0.01 ppm to about 4 ppm of oxygen.
摘要翻译：间同立构1,2-聚丁二烯是一种热塑性树脂，其具有以其聚合物主链交替形式连接的双键。膜，纤维和模塑制品可以利用间同立构1,2-聚丁二烯制备。它也可以混合到橡胶中并与其共混。通常优选通过悬浮或乳液聚合在水性介质中合成间规1,2-聚丁二烯。在这种水性聚合技术中，经常遇到反应器结垢和颗粒尺寸控制问题。本发明基于意想不到的发现，即可以大大减少或消除反应器结垢，并且可以通过在受控量的溶解氧的存在下进行这种水性聚合来调节颗粒尺寸，所述溶解氧在约0.01ppm至约 4 ppm。本发明更具体地公开了一种在具有最小的反应器结垢的水性介质中制备间同立构1,2-聚丁二烯的方法，其包括在（1）催化剂体系存在下，在水介质中聚合1,3-丁二烯单体，所述催化剂体系由（a）过渡金属化合物，（b）有机铝化合物和（c）选自二硫化碳，异硫氰酸苯酯和黄原酸中的至少一种，和（2）约0.01ppm至约4ppm的氧。 \！

88. 发明授权

US5612435A Terminally functionalized polymers produced using protected functional initiators 失效
标题翻译：使用保护的官能引发剂制备终端官能化聚合物
公开(公告)号：US5612435A
公开(公告)日：1997-03-18
申请号：US539467
申请日：1995-10-05
申请人： Robert C. Bening , Carl L. Willis
发明人： Robert C. Bening , Carl L. Willis
IPC分类号： C07F7/18 , C08F4/46 , C08F4/48 , C08F36/06 , C08F136/06 , C08F8/04
CPC分类号： C08F4/48 , C07F7/1864 , C08F36/06
摘要： The anionic polymerization of unsaturated monomers with functionalized initiators having the structure R.sup.1 R.sup.2 R.sup.3 Si--O--A'--Li is improved by selecting A' from the structures --CH.sub.2 --CH.sub.2 --CH.sub.2 -- (1,3-propyl), --CH.sub.2 --CH(CH.sub.3)--CH.sub.2 -- (2-methyl-1,3-propyl), --CH.sub.2 --C(CH.sub.3).sub.2 --CH.sub.2 --(2,2-dimethyl-1,3-propyl), or --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,8-octyl). This narrow class of polymerization initiators operate at surprisingly higher polymerization temperatures with surprisingly lower amounts of dead initiator than similar initiators wherein A' is --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,4-butyl), --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,5-pentyl), or --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,6-hexyl).
摘要翻译：通过从结构-CH 2 -CH 2 -CH 2 - （1,3-丙基），-CH 2 -CH（CH 3）2中选择A'来改善不饱和单体与具有结构R1R2R3Si-O-A'-Li的官能化引发剂的阴离子聚合）-CH 2 - （2-甲基-1,3-丙基），-CH 2 -C（CH 3）2 -CH 2 - （2,2-二甲基-1,3-丙基）或-CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 - （1,8-辛基）。这种窄类聚合引发剂在令人惊奇的更高的聚合温度下操作，其中A'是-CH 2 -CH 2 -CH 2 - （1-丁基），-CH 2 -CH 2 -CH 2 - CH 2 -CH 2 - （1,5-戊基）或-CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 - （1,6-己基）。

89. 发明授权

US5587433A Esters of hydroxy terminated polybutadiene compositions and methods for making same 失效
标题翻译：羟基封端的聚丁二烯组合物的酯及其制备方法
公开(公告)号：US5587433A
公开(公告)日：1996-12-24
申请号：US516144
申请日：1995-08-17
申请人： Rudolph H. Boeckeler
发明人： Rudolph H. Boeckeler
IPC分类号： C08C19/36 , C08C19/34 , C08C19/38 , C08C19/40 , C08F279/02 , C08F290/04 , C08F299/00 , C08F36/06
CPC分类号： C08F290/048 , C08C19/34 , C08C19/38 , C08F279/02
摘要： A method for producing esters of hydroxy terminated polybutadiene, including the steps of: (a) providing an anhydride; (b) reacting a hydroxy terminated polybutadiene with the anhydride to form a carboxyl terminated polybutadiene derivative; (c) reacting the derivative with an epoxide. Also a curable composition, including: (a) an ester of hydroxy terminated polybutadiene; (b) a copolymerizable ethylenically unsaturated monomer; and (c) a drier.
摘要翻译：一种生产羟基封端的聚丁二烯酯的方法，包括以下步骤：（a）提供酸酐; （b）使羟基封端的聚丁二烯与酸酐反应形成羧基封端的聚丁二烯衍生物; （c）使该衍生物与环氧化物反应。还有一种可固化组合物，包括：（a）羟基封端的聚丁二烯的酯; （b）可共聚的烯属不饱和单体; 和（c）干燥剂。

90. 发明授权

US5534592A High performance blend for tire treads 失效
标题翻译：高性能混合轮胎胎面
公开(公告)号：US5534592A
公开(公告)日：1996-07-09
申请号：US531841
申请日：1995-09-22
申请人： Adel F. Halasa , Wen-Liang Hsu , David J. Zanzig , Paul H. Sandstrom , Steven K. Henning , Danielle Lucas
发明人： Adel F. Halasa , Wen-Liang Hsu , David J. Zanzig , Paul H. Sandstrom , Steven K. Henning , Danielle Lucas
IPC分类号： B60C1/00 , C08F2/38 , C08F2/44 , C08F4/48 , C08F36/00 , C08F36/04 , C08F36/06 , C08F136/06 , C08L9/00 , C08L21/00 , C08K5/54
CPC分类号： C08F36/04 , C08F136/06 , C08L9/00 , C08K5/06 , C08K5/17 , Y10S152/905
摘要： This invention reveals a high performance polybutadiene rubber blend comprised of (a) a first polybutadiene rubber, (b) a second polybutadiene rubber, and (c) a third polybutadiene rubber; wherein the first polybutadiene rubber, the second polybutadiene rubber, and the third polybutadiene rubber are selected from the group of consisting of super-high vinyl polybutadiene rubbers having a vinyl content which is within the range of 80 percent to 100 percent, high vinyl polybutadiene rubbers having a vinyl content which is within the range of 60 percent to 79 percent, medium vinyl polybutadiene rubbers having a vinyl content which is within the range of 35 percent to 59 percent, and low vinyl polybutadiene rubbers having a vinyl content which is within the range of 8 percent to 34 percent; wherein at least three members selected from the group consisting of super-high vinyl polybutadiene rubbers, high vinyl polybutadiene rubbers, medium vinyl polybutadiene rubbers, and low vinyl polybutadiene rubbers are included in the blend, wherein at least one of the polybutadiene rubbers in the blend has a vinyl content which is within 35 percentage points of the vinyl content of at least one other polybutadiene rubber in the blend, wherein the blend as a whole has a vinyl content of at least 40 percent, and wherein the blend contains at least 10 parts of the first polybutadiene rubber, at least 10 parts of the second polybutadiene rubber and at least 10 parts of the third polybutadiene rubber, based upon a total of 100 parts of rubber in the blend.
摘要翻译：本发明揭示了一种高性能聚丁二烯橡胶共混物，其包含（a）第一聚丁二烯橡胶，（b）第二聚丁二烯橡胶和（c）第三聚丁二烯橡胶; 其中第一聚丁二烯橡胶，第二聚丁二烯橡胶和第三聚丁二烯橡胶选自乙烯基含量在80％至100％范围内的超高乙烯基聚丁二烯橡胶，高乙烯基聚丁二烯橡胶乙烯基含量在60％至79％的范围内，乙烯基含量在35％至59％的范围内的中等乙烯基聚丁二烯橡胶和乙烯基含量在该范围内的低乙烯基聚丁二烯橡胶为8％至34％; 其中选自由超高乙烯基聚丁二烯橡胶，高乙烯基聚丁二烯橡胶，中乙烯基聚丁二烯橡胶和低乙烯基聚丁二烯橡胶组成的组中的至少三种组分包括在共混物中，其中混合物中的至少一种聚丁二烯橡胶乙烯基含量在共混物中至少一种其它聚丁二烯橡胶的乙烯基含量的35个百分点以内，其中该共混物整体具有至少40％的乙烯基含量，并且其中该共混物含有至少10份的第一聚丁二烯橡胶，至少10份第二聚丁二烯橡胶和至少10份第三聚丁二烯橡胶，基于共混物中的100份橡胶。

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