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81. 发明申请

US20050043443A1 Molding compositions and their use 审中-公开
标题翻译：成型组合物及其用途
公开(公告)号：US20050043443A1
公开(公告)日：2005-02-24
申请号：US10919044
申请日：2004-08-16
申请人： Robert Van Mullekom , Detlev Joachimi , Alexander Karbach , Peter Persigehl , Maarten De Bock
发明人： Robert Van Mullekom , Detlev Joachimi , Alexander Karbach , Peter Persigehl , Maarten De Bock
IPC分类号： C03C25/36 , C08K7/14 , C08K9/08 , H05K1/03 , C08K9/00 , C08K3/40
CPC分类号： C08K7/14 , C03C25/36 , C08K9/08 , H05K1/0373 , H05K2201/0239 , H05K2201/0251 , H05K2201/09118
摘要： A thermoplastic glass fibers reinforced molding composition that exhibits improved mechanical properties and resistance to hydrolysis is disclosed. The composition contains at least one thermoplastic polymer, sized glass fibers, and optional conventional additives and auxiliary substances. The sizing agent that is substantially free of emulsifiers not bound to the resin contains (a) at least one epoxide-functional, oligomeric resin, having epoxide group content of 0.15 to 0.75 mole per 100 g of resin, average functionality of at least 2.3 epoxide groups per molecule, (b) at least one epoxide curing agents, and (c) at least one silane coupling agent.
摘要翻译：公开了一种具有改进的机械性能和抗水解性的热塑性玻璃纤维增强模塑组合物。该组合物含有至少一种热塑性聚合物，尺寸的玻璃纤维和任选的常规添加剂和辅助物质。基本上不含与树脂结合的乳化剂的上浆剂包含（a）至少一种环氧官能的低聚树脂，其环氧基团含量为每100克树脂0.15至0.75摩尔，平均官能度至少为2.3环氧化物（b）至少一种环氧化物固化剂，和（c）至少一种硅烷偶联剂。

82. 发明授权

US5877240A Sizing composition for glass fibers for reinforcement of engineered thermoplastic materials 失效
标题翻译：用于加强工程热塑性材料的玻璃纤维的施胶组合物
公开(公告)号：US5877240A
公开(公告)日：1999-03-02
申请号：US939031
申请日：1997-09-26
申请人： Willy H. Piret , Nadia Masson
发明人： Willy H. Piret , Nadia Masson
IPC分类号： C08J5/06 , C03C25/10 , C03C25/26 , C03C25/32 , C03C25/36 , C08J5/08 , D06M15/564 , C08L63/04 , C08K5/54 , C08L75/06
CPC分类号： C03C25/36 , C03C25/26 , C03C25/326 , C08J5/08 , Y10T428/2938 , Y10T428/2962
摘要： An epoxy and polyurethane-based sizing composition for fibers used in the reinforcement of engineered thermoplastic molded composites, which exhibits improved hydrolytic stability and reduced discoloration.
摘要翻译：用于增强工程热塑性塑料复合材料的纤维的环氧树脂和聚氨酯基上胶组合物，其表现出改善的水解稳定性和减少的变色。

83. 发明授权

US5605757A Glass fiber sizing compositions, sized glass fibers and methods of reinforcing polymeric materials using the same 失效
标题翻译：玻璃纤维施胶组合物，尺寸的玻璃纤维和使用其的增强聚合材料的方法
公开(公告)号：US5605757A
公开(公告)日：1997-02-25
申请号：US359778
申请日：1994-12-20
申请人： Michael W. Klett
发明人： Michael W. Klett
IPC分类号： C08J5/08 , C03C25/10 , C03C25/36 , B32B9/00 , B05D3/00
CPC分类号： C03C25/36 , Y10T428/2933 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964
摘要： An aqueous glass fiber sizing composition is provided which provides high strength and wet-out to composites prepared using glass fibers having the sizing composition of the present invention applied thereto. When used to reinforce a thermosetting polymeric material, the glass fibers sized with this composition provide a composite useful in making pultrusion profiles having high compressive, shear and flexural strengths. The aqueous composition includes a non-ionic thermosetting urethane-modified epoxy polymer; a water soluble, dispersible or emulsifiable epoxy film-forming polymer different from the urethane-modified epoxy polymer; an emulsifying agent; an organo functional silane coupling agent; and a fiber lubricant.
摘要翻译：提供一种水玻璃纤维施胶组合物，其对应用本发明的施胶组合物的玻璃纤维制备的复合材料提供高强度和湿润性。当用于增强热固性聚合物材料时，用该组合物大小的玻璃纤维提供了一种可用于制造具有高压缩，剪切和弯曲强度的拉挤型材的复合材料。水性组合物包括非离子型热固性聚氨酯改性环氧聚合物; 与氨基甲酸酯改性的环氧聚合物不同的水溶性，可分散或可乳化的环氧成膜聚合物; 乳化剂; 有机官能硅烷偶联剂; 和纤维润滑剂。

84. 发明授权

US5178657A Binder and binder-based size for mineral fibers 失效
标题翻译：矿物纤维的粘合剂和粘合剂大小
公开(公告)号：US5178657A
公开(公告)日：1993-01-12
申请号：US686509
申请日：1991-04-17
申请人： Bernard Gicquel
发明人： Bernard Gicquel
IPC分类号： C03C25/36
CPC分类号： C03C25/36 , Y10T428/2964 , Y10T428/31525 , Y10T442/604
摘要： A method of sizing insulating glass fibers, comprising: preparing glass fibers by a high temperature aerodynamic procedure in which glass fibers are drawn out by a gas current and collected in a hood; spraying a size diluted in water onto said glass fibers in said collection hood, said size consisting essentially of an epoxy resin, an amino hardening agent and, as additives, 0.1 to 2.0% of a silane and 0 to 15% of a mineral oil, each calculated on 100 parts of dry resin, wherein said epoxy resin is a condensation product of epichlorohydrin and bisphenol A having a polymerization index n of less than 1 and the equivalent molar mass of the hardening agent is less than 100 g and said size is free of formaldehyde and components which release formaldehyde when baked; and recovering a sized insulating glass fiber product.
摘要翻译：一种中空玻璃纤维尺寸的方法，包括：通过高温空气动力学程序制备玻璃纤维，其中玻璃纤维由气流引出并收集在罩中; 将在水中稀释的尺寸喷洒在所述收集罩中的所述玻璃纤维上，所述尺寸基本上由环氧树脂，氨基硬化剂和作为添加剂的0.1-2.0％的硅烷和0至15％的矿物油组成，每100份干树脂计算，其中所述环氧树脂是聚合指数n小于1的表氯醇和双酚A的缩合产物，硬化剂的当量摩尔质量小于100g，并且所述尺寸是游离的的甲醛和烘烤时释放甲醛的成分; 并回收大小的绝缘玻璃纤维制品。

85. 发明授权

US4608304A Glass fibers coated with aqueously dispersed coating compositions 失效
标题翻译：涂布有高分散涂层组合物的玻璃纤维
公开(公告)号：US4608304A
公开(公告)日：1986-08-26
申请号：US699531
申请日：1985-02-08
申请人： James W. Rosthauser
发明人： James W. Rosthauser
IPC分类号： C03C25/36 , C08G18/08 , C08G18/58 , C08G18/80 , C08G59/06 , C08G59/40 , C08L63/00 , D02G3/00
CPC分类号： C08G59/4028 , C03C25/36 , C08G18/0823 , C08G18/58 , C08G18/8003 , C08G59/066 , C08L63/00 , Y10T428/2938 , Y10T428/2964 , Y10T428/2967
摘要： The present invention is directed to a process for coating glass fibers by(1) applying an aqueously dispersed, heat-curable coating composition containing(a) a water-dispersible epoxy resin component containing external and/or chemically incorporated non-ionic emulsifiers and(b) a water-dispersible, block polyisocyanate component containing chemically incorporated anionic hydrophilic groups in a weight ratio of component (a) to component (b) of about 1:10 to 10:1 to glass fibers and(2) curing the coating composition at elevated temperature.The present invention is also directed to the coated glass fibers produced therefrom.
摘要翻译：本发明涉及一种涂覆玻璃纤维的方法，该方法包括：（1）涂布含有（a）含有外部和/或化学结合的非离子乳化剂的水分散性环氧树脂组分的高分散的可热固化的涂料组合物，和 b）含有化学引入的阴离子亲水基团的水分散性嵌段多异氰酸酯组分，其中组分（a）与组分（b）的重量比为约1:10至10:1，并且（2）固化涂料组合物在高温下。本发明还涉及由其制备的涂覆玻璃纤维。

86. 发明授权

US4391876A Aqueous peroxide emulsion for use with glass fibers 失效
标题翻译：用于玻璃纤维的过氧化氢乳液
公开(公告)号：US4391876A
公开(公告)日：1983-07-05
申请号：US136645
申请日：1980-04-02
申请人： Albert E. Tamosauskas , Chester S. Temple
发明人： Albert E. Tamosauskas , Chester S. Temple
IPC分类号： C08K9/00 , B01F17/00 , B01F17/42 , C03C25/10 , C03C25/36 , C08J5/08 , C08K9/04 , C08L23/00 , C08L67/00 , C08L101/00 , B32B9/00 , C08K3/40
CPC分类号： C08J5/08 , B01F17/0028 , B01F17/0092 , C03C25/36 , Y10S516/93 , Y10T428/2964
摘要： An aqueous emulsion of an organic peroxide that is liquid at a temperature of 20.degree. C. and that is insoluble or has limited solubility in water is provided that has improved shelf-stability, shear-stability and process stability and has good dilutability and has a particle size of around 1.5 microns or less. The emulsion has from 1 weight percent of the emulsion to about 70 weight percent of the emulsion of an organic peroxide that is a liquid at 20.degree. C. and in particular that has a half-life exceeding 60 hours at 212.degree. F. (100.degree. C.) and 20 minutes at 300.degree. F. (149.degree. C.) The emulsion also has about 0.005 to about 15 weight percent of the emulsion of a nonionic emulsifier blend. The emulsifier blend has three emulsifiers selected from polyalkylene glycol ethers, dialkylaryl polyether alcohols, and polyoxy-propylene-polyoxyethylene condensates and the like nonionic emulsifiers having a particluar HLB range for each of the three emulsifiers. The remaining weight percent of the emulsion is water.The method of preparing the aqueous emulsion involves the addition of the emulsifier blend to the liquid peroxide. One of the emulsions is split into two portions for the addition.The aqueous organic peroxide-containing emulsion is incorporated into a sizing composition for treating glass fibers to produce treated glass fibers for use as reinforcement in polymers.
摘要翻译：提供在20℃温度为液体并且不溶于或在水中具有有限溶解度的有机过氧化物的水乳液，其具有改进的储存稳定性，剪切稳定性和工艺稳定性，并具有良好的可稀释性，并具有粒径约1.5微米或更小。该乳液具有1重量％的乳液至约70重量％的有机过氧化物乳液，该有机过氧化物在20℃是液体，特别是在212°F时半衰期超过60小时。（100 ℃）和在300°F（149℃）下20分钟。乳液还具有约0.005至约15重量％的非离子乳化剂共混物的乳液。乳化剂共混物具有选自聚亚烷基二醇醚，二烷基芳基聚醚醇和聚氧丙烯 - 聚氧乙烯缩合物等三种乳化剂，以及三种乳化剂中的每一种具有特定HLB范围的非离子乳化剂。乳液的剩余重量百分比是水。制备水性乳液的方法包括将乳化剂共混物加入到液体过氧化物中。将一种乳液分成两部分用于添加。将含有机含水过氧化物的乳液掺入用于处理玻璃纤维的施胶组合物中以生产用作聚合物增强剂的处理过的玻璃纤维。

87. 发明授权

US3789049A Glass fiber-reinforced epoxy resin or polyester resin composition and method for manufacturing same 失效
标题翻译：玻璃纤维增强环氧树脂或聚酯树脂组合物及其制造方法
公开(公告)号：US3789049A
公开(公告)日：1974-01-29
申请号：US3789049D
申请日：1971-12-20
申请人： NITTO BOSEKI CO LTD
发明人： NARITA K , NAGASAWA T , KUROIWA K
IPC分类号： C03C25/36 , C08C19/40 , C08G59/34 , C08G59/40 , C08J5/08 , C08L63/00 , C08G51/10
CPC分类号： C08G59/027 , C03C25/36 , C08C19/40 , C08G59/4085 , C08J5/08 , C08J2363/00 , C08J2367/06 , C08L63/00
摘要： A GLASS FIBER-REINFORCED, EPOXY RESIN OR UNSATURATED POLYESTER RESIN COMPOSITION COMPRISING GLASS FIBER, AN EPOXY RESIN OR AN UNSATURATED POLYESTER RESIN, AND, AT THE INTERFACE OF SAID GLASS FIBER AND RESIN, A REACTION PRODUCT OF A PARTIALLY EPOXIDIED POLYBUTADIENE HAVING AT LEAST ABOUT 50 MOLE PERCENT OF 1,2-STRUCTURE WITH A MERCAPTOORGANOSILANE OF THE FORMULA,

HS-(CH2)N-SI(-R1)(-R2)-R3

WHEREIN R1, R2 AND R3, WHICH MAY BE THE SAMD OR DIFFERENT, REPRESENT HYDROLYZABLE RADICALS CAPABLE OF REACTING WITH GLASS FIBER, FOR EXAMPLE, ALKOXY GROUPS HAVING 1 TO 3 CARBON ATOMS, ACETOXY GROUPS OR HALOGEN ATOMS, AND N IS AN INTEGER OF FROM 1 TO 4. BY THE PRESENCE OF SAID REACTION PRODUCT AT THE INTERFACE, THE ADHESION BETWEEN THE GLASS FIBER AND THE RESIN IS IMPROVED AND THERE IS OBTAINED A REINFORCED PLASTIC HAVING A HIGH STRENGTH AND EXCELLENT TRANSPARENCY.

88. 发明授权

US3652326A Sizing composition and glass fibers treated therewith 失效
标题翻译：尺寸组合物和玻璃纤维经过处理
公开(公告)号：US3652326A
公开(公告)日：1972-03-28
申请号：US3652326D
申请日：1970-04-03
申请人： OWENS CORNING FIBERGLASS CORP
发明人： WARD JOHN E
IPC分类号： C03C25/36 , C08J5/08 , C08J5/24 , C03C25/02
CPC分类号： C03C25/26 , C03C25/28 , C03C25/36 , C08J5/08 , C08J5/24 , Y10T428/2958 , Y10T428/2962 , Y10T428/31525
摘要： A sizing for glass fibers, comprising water soluble epoxy resins, an organosilane, polyvinyl acetate copolymer and a lubricant is provided, whereby the sized glass fibers in the form of strands possess excellent integrity.
摘要翻译：提供了包含水溶性环氧树脂，有机硅烷，聚乙酸乙烯酯共聚物和润滑剂的玻璃纤维的尺寸，由此形成股线的尺寸的玻璃纤维具有优异的完整性。

89. 发明授权

US3459585A Novel reaction product and use thereof as a glass fiber size 失效
标题翻译：新型反应产物及其作为玻璃纤维尺寸使用
公开(公告)号：US3459585A
公开(公告)日：1969-08-05
申请号：US3459585D
申请日：1966-12-05
申请人： PPG INDUSTRIES INC
发明人： KILLMEYER CHARLES W , EILERMAN GEORGE E
IPC分类号： C03C25/36 , C08J5/08 , C03C25/02 , B44D1/14
CPC分类号： C08J5/08 , C03C25/36 , Y10T428/2938 , Y10T428/31627 , Y10T428/31641

90. 发明授权

US3444120A Glass fabric having improved yarn slippage and hand 失效
标题翻译：玻璃织物有改进的纱线拖鞋和手
公开(公告)号：US3444120A
公开(公告)日：1969-05-13
申请号：US3444120D
申请日：1966-03-14
申请人： OWENS CORNING FIBERGLASS CORP
发明人： BOYES DAVID W , POTTER DOUGLAS E
IPC分类号： C03C25/10 , C03C25/36 , C03C25/02 , D06C25/00
CPC分类号： C03C25/36 , C03C25/475 , Y10T428/254 , Y10T428/2962 , Y10T428/2964 , Y10T442/2311 , Y10T442/2402 , Y10T442/2992
摘要： 1,168,555. Coated glass fabrics. OWENSCORNING FIBERGLAS CORP. 6 March, 1967 [14 March, 1966]. No. 10456/67. Heading B2E. [Also in Divisions C3 and Dl] A finish coating on glass fabrics is obtained by applying to the fabric an aqueous composition comprising (a) an organopolysiloxane containing silicon-bonded hydrogen, (b) an incompletely cured water-insoluble fabric-finishing resin in emulsified form, the resin having reactive groups, and (e) a water-soluble difunctional organic compound, the functional groups of which are separated by more than 10 carbon atoms, a first of the functional groups being reactive with the silicon-bonded hydrogen of (a) and the other being reactive with the groups of (b). The proportions of (a), (b) and (c) are preferably 5 to 50%, 0.5 to 20% and 5 to 20%, respectively of the weight of the aqueous composition. Pigments and dyes may be added. Examples of fabricfinishing resins (b) are acrylic acid polymers and copolymers which may contain amino groups, and also mentioned are polyesters, polyamides, phenol-, urea- and melamine-formaldehyde resins, epoxy polymers and polyurethanes. The compounds specified as difunctional compounds (c) are water-soluble epoxy resins which have been modified by reaction with diethanolamine to replace one terminal glycidyl group by a hydroxyamine group or with a polyglycol to provide a hydroxypolyethenoxy group at one end. Other materials which may be used as (e) are polyglycols and straight chain polyesters, polyamines and polyamides. After drying and curing to form a film on the fabric, a water-proofing solution of a chromium organo complex may be applied.

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