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81. 发明授权

US5827612A Aqueous coating compositions for glass fibers, fiber strands coated with such compositions and optical fiber cable assemblies including such fiber strands 失效
公开(公告)号：US5827612A
公开(公告)日：1998-10-27
申请号：US522766
申请日：1995-09-01
申请人： Mikhail M. Girgis
发明人： Mikhail M. Girgis
IPC分类号： C03C25/28 , C03C25/30 , C03C25/50 , G02B6/44 , D02G3/00
CPC分类号： C03C25/50 , C03C25/28 , C03C25/285 , C03C25/30 , G02B6/443 , Y10T428/2933 , Y10T428/2938 , Y10T428/294 , Y10T428/2964 , Y10T428/2967
摘要： The present invention provides a secondary aqueous coating composition for coating sized glass fibers of a glass fiber strand, including a first water soluble, emulsifiable or dispersible curable acrylic polymer and a second water soluble, emulsifiable or dispersible curable acrylic polymer different from the first acrylic polymer, the secondary aqueous coating composition being essentially free of a urethane-containing polymer. Other aspects of the present invention include a strand of sized glass fibers having thereon the aforementioned coating composition and an optical fiber cable assembly including an optical fiber and a reinforcement strand of the sized and secondarily coated glass fibers. In an alternative embodiment of the present invention, the sized glass fibers of the reinforcement strand of the optical fiber cable assembly have thereon the dried residue of a secondary aqueous coating composition which includes a water soluble, emulsifiable or dispersible curable acrylic polymer and a wax material, the secondary aqueous coating composition being essentially free of a urethane-containing polymer.

82. 发明授权

US5665470A Glass fibers and fiber-reinforced plastics 失效
标题翻译：玻璃纤维和纤维增强塑料
公开(公告)号：US5665470A
公开(公告)日：1997-09-09
申请号：US558299
申请日：1995-11-15
申请人： Charles R. Key , Yen-Jer Shih
发明人： Charles R. Key , Yen-Jer Shih
IPC分类号： C08J5/08 , C03C25/28 , C08F212/08 , C08F218/08 , C08F220/18 , C08K9/08 , D06M13/02 , D06M13/188 , D06M13/503 , D06M13/507 , D06M15/263 , D06M15/333 , D06M101/00 , C08K9/04
CPC分类号： C03C25/28 , C03C25/285 , C08F212/08 , C08F218/08 , C08F220/18 , C08K9/08 , Y10T428/2938
摘要： The present invention is directed to sizing compositions for use on glass fibers which are used to reinforce lamination resins used in the formation of glass laminates. The sizing compositions contain a low molecular weight, polymer latex prepared by polymerizing at least one monomer(s) selected from the group consisting of acrylic acid, methacrylic acid, C.sub.1 -C.sub.18 alkyl esters of acrylic acid, C.sub.1 -C.sub.18 alkyl esters of methacrylic acid, glycidyl acrylate, glycidyl methacrylate, C.sub.1 -C.sub.4 hydroxyalkyl esters of acrylic acid, C.sub.1 -C.sub.4 hydroxyalkyl esters of methacrylic acid, vinyl esters of saturated aliphatic monocarboxylic acids containing up to 10 carbon atoms, (meth)acrylamide and their N-substituted derivatives, vinyl ethers, N-vinyl lactams, halogenated vinyl compounds, alkyl vinyl ketones, (meth)allyl ester of saturated aliphatic monocarboxylic acids, vinyl compounds such as vinyl pyrrole, olefins, diesters of itaconic, maleic and/or fumaric acid, and styrene. The polymers have a molecular weight effective to provide both improved wettability of the glass fibers by the lamination resins and improved clarity of reinforced glass laminates prepared from the sized glass fibers and the lamination resins, when compared to sizing compositions known heretofore. The invention is also directed to glass fibers treated with such compositions, and fiber-reinforced plastics prepared from such treated glass fibers.
摘要翻译：本发明涉及用于玻璃纤维的上胶组合物，其用于加强用于形成玻璃层压材料的层压树脂。上胶组合物含有低分子量的聚合物胶乳，其通过聚合至少一种选自丙烯酸，甲基丙烯酸，丙烯酸的C1-C18烷基酯，甲基丙烯酸的C1-C18烷基酯，，丙烯酸缩水甘油酯，甲基丙烯酸缩水甘油酯，丙烯酸的C1-C4羟烷基酯，甲基丙烯酸的C1-C4羟烷基酯，含有至多10个碳原子的饱和脂肪族单羧酸的乙烯基酯，（甲基）丙烯酰胺及其N-取代的衍生物，乙烯基醚，N-乙烯基内酰胺，卤代乙烯基化合物，烷基乙烯基酮，饱和脂族一元羧酸的（甲基）烯丙酯，乙烯基吡咯，烯烃，衣康酸二酯，马来酸和/或富马酸的乙烯基化合物和苯乙烯。聚合物具有分子量，其有效地通过层压树脂提供玻璃纤维的改善的润湿性，并且与迄今为止已知的施胶组合物相比，可提高由尺寸的玻璃纤维和层压树脂制备的增强玻璃层压体的透明度。本发明还涉及用这种组合物处理的玻璃纤维，以及由这种经处理的玻璃纤维制备的纤维增强塑料。

83. 发明授权

US4562115A Composites and size coated glass fibers used therein 失效
标题翻译：其中使用的复合材料和尺寸涂覆的玻璃纤维
公开(公告)号：US4562115A
公开(公告)日：1985-12-31
申请号：US656211
申请日：1984-10-01
申请人： William L. Hergenrother
发明人： William L. Hergenrother
IPC分类号： C03C25/28 , C08J5/08 , D02G3/00
CPC分类号： C03C25/28 , C08J5/08 , Y10T428/249948 , Y10T428/2938 , Y10T428/2964
摘要： A composite which has a high flexural strength to density ratio and which is resistant to strength loss incident to exposure to water, is formed by reinforcing unsaturated thermosetting resin with glass fibers sized with selected maleic anhydride adduct of polybutadiene utilized in critical amounts.
摘要翻译：具有高弯曲强度与密度比并且耐受暴露于水的强度损失的复合材料通过用以临界量使用的聚丁二烯选择的马来酸酐加合物的玻璃纤维增强不饱和热固性树脂而形成。

84. 发明授权

US4413085A Storage stable polyolefin compatible non-crosslinking size for fiber glass strands 失效
标题翻译：储存稳定的聚烯烃相容的非交联尺寸的玻璃纤维股线
公开(公告)号：US4413085A
公开(公告)日：1983-11-01
申请号：US329442
申请日：1981-12-10
申请人： Chester S. Temple
发明人： Chester S. Temple
IPC分类号： C03C25/26 , C03C25/28 , C08J5/08 , C08K7/14 , C08K9/06 , C08K5/09
CPC分类号： C08J5/08 , C03C25/26 , C03C25/28 , C08K7/14 , C08K9/06 , C08J2323/02 , Y10T428/2938 , Y10T428/2962
摘要： Continuous glass fiber with a polyolefin compatible sizing composed of a coupling agent, a stabilizer, a lubricant, a non-crosslinking film forming polymer, softening agent and surfactant are disclosed for utilization in polyolefin polymer reinforcement. The article formed and formation method for fiber combination with a polyolefin polymer are also disclosed.
摘要翻译：公开了具有由偶联剂，稳定剂，润滑剂，非交联成膜聚合物，软化剂和表面活性剂组成的聚烯烃相容尺寸的连续玻璃纤维用于聚烯烃聚合物增强。还公开了与聚烯烃聚合物的纤维组合的制品和形成方法。

85. 发明授权

US4235764A Size composition 失效
标题翻译：尺寸组成
公开(公告)号：US4235764A
公开(公告)日：1980-11-25
申请号：US866141
申请日：1977-12-30
申请人： Ernst H. Dereser , Jean-Marie Meulders
发明人： Ernst H. Dereser , Jean-Marie Meulders
IPC分类号： C03C25/26 , C03C25/28 , C08L77/00
CPC分类号： C03C25/26 , C03C25/28 , Y10T428/2964
摘要： A size composition for glass fibers is disclosed. The composition consists essentially of an aqueous dispersion of a polyvinyl alcohol, a water dispersible cationic epichlorohydrin polyamide copolymer and a flocculent polymer. The polyvinyl alcohol has a degree of hydrolysis ranging from 85 percent to 90 percent and a molecular weight such that a 4 percent by weight aqueous solution thereof has a viscosity of from 4 to 6 centipoises. The cationic epichlorohydrin polyamide copolymer is one wherein the polyamide can be based upon diethylene triamine. The flocculent polymer is a medium-high to high cationic polymer or copolymer having a quaternized amine function. The polymer or copolymer is of at least 40 percent by weight of a monomer having an acrylic function and an amine function where the acrylic function is acrylate or methacrylate, any co-monomer being an acrylamide. The quaternized copolymer has a molecular weight sufficiently high that a 1 percent solution thereof in water has a Brookfield viscosity from 1200 to 1600 centipoises.
摘要翻译：公开了玻璃纤维的尺寸组成。该组合物基本上由聚乙烯醇的水性分散体，水分散性阳离子表氯醇聚酰胺共聚物和絮状聚合物组成。聚乙烯醇的水解度为85〜90％，分子量为4重量％，其粘度为4〜6厘泊。阳离子表氯醇聚酰胺共聚物是聚酰胺可以基于二亚乙基三胺的共聚物。絮状聚合物是具有季铵化胺官能团的中高分子阳离子聚合物或共聚物。聚合物或共聚物具有至少40重量％的具有丙烯酸功能和胺官能团的单体，其中丙烯酸官能团是丙烯酸酯或甲基丙烯酸酯，任何共聚单体均为丙烯酰胺。季铵化共聚物具有足够高的分子量，使得其1％的水溶液的布氏粘度为1200至1600厘泊。

86. 发明授权

US4119477A Size compositions for glass fiber reinforced cementitious products 失效
标题翻译：玻璃纤维增强胶结产品的尺寸组成
公开(公告)号：US4119477A
公开(公告)日：1978-10-10
申请号：US820200
申请日：1977-07-29
申请人： Eleanor B. Cohen , William N. Stassen , James C. Wintgens
发明人： Eleanor B. Cohen , William N. Stassen , James C. Wintgens
IPC分类号： C03C25/10 , C03C25/28 , C04B31/06 , C08L7/00
CPC分类号： C03C25/103 , C03C25/28 , Y10T428/2962 , Y10T428/2964
摘要： Elastomeric size compositions for glass fiber reinforced cementitious products are disclosed. These size compositions show strong improvements in all phases of strand integrity with especially improved performance in wet integrity. This in turn improves the strand's workability in a cementitious matrix.
摘要翻译：公开了用于玻璃纤维增强水泥质产品的弹性体组合物。这些尺寸的组合物显示出在整个纱线完整性的所有阶段都有很强的改进，并且在湿润完整性方这又改善了在水泥基质中的股线的可加工性。

87. 发明授权

US3650818A Glass fibers coated with vinyl polymers containing an amine 失效
标题翻译：涂有含有胺的乙烯基聚合物的玻璃纤维
公开(公告)号：US3650818A
公开(公告)日：1972-03-21
申请号：US3650818D
申请日：1965-07-08
申请人： OWENS CORNING FIBERGLASS CORP
发明人： MARZOCCHI ALFRED , HORTON RICHARD C
IPC分类号： C03C25/28 , C03C25/00 , C08G41/04
CPC分类号： C03C25/28 , Y10T428/23943 , Y10T428/23979 , Y10T428/2817 , Y10T428/2938 , Y10T428/2964
摘要： Glass fibers are coated with a formulation containing vinyl polymer. 2-10% by weight of an amine compound is added to the vinyl polymer. A typical formulation contains 100 pts. PVC, 6 pts. undecyl benzyl phthalate, 21 pts. tri-o-phosphate, 21 pts. epoxidized tall oil ester, 4 pts. paste aluminum pigment, 2 pts. Sb2O3, a heat stabilizer, a barium-cadmium coupler, an ulta violet stabilizer, and a hydrocarbon thinner. The amines may be vinyl pyrrolidone monomer, propylamine, polyvinyl pyrrolidone acrylamide, aminopolyethylene, polyvinyl pyridine, polyacrylonitrile, hexamethylenediamine, and diphenyl guanidine.
摘要翻译：用含有乙烯基聚合物的制剂涂覆玻璃纤维。向乙烯基聚合物中加入2-10重量％的胺化合物。典型的配方包含100个点。 PVC，6点邻苯二甲酸十一烷基苄酯，21份。三磷酸盐，21点。环氧化妥尔油酯，4份。糊状铝颜料，2份。 Sb 2 O 3，热稳定剂，钡镉成色剂，超紫色稳定剂和烃类稀释剂。胺可以是乙烯基吡咯烷酮单体，丙胺，聚乙烯吡咯烷酮丙烯酰胺，氨基聚乙烯，聚乙烯基吡啶，聚丙烯腈，六亚甲基二胺和二苯胍。

88. 发明授权

US3553050A Promoting the adhesion of halogen-containing resins to textiles 失效
标题翻译：促进含卤素树脂与纺织品的粘合
公开(公告)号：US3553050A
公开(公告)日：1971-01-05
申请号：US3553050D
申请日：1969-06-02
申请人： HARDMAN & HELDEN LTD
发明人： HARRIS JAMES D , ASHURST COLIN D
IPC分类号： C03C25/28 , C08K5/13 , D06M15/244 , C09J5/06
CPC分类号： D06M15/244 , C03C25/28 , C08K5/13 , Y10T428/31855 , Y10T442/2861 , Y10T442/2893 , Y10T442/2934 , C08L27/04
摘要： THE ADHESION OF HALOGEN-CONTAINING VINYL RESINS TO SYNTHETIC AND GLASS FIBRE TEXTILES IS PROMOTED BY INCORPORATION IN THE SAID RESIN OF A POLYHYDRIC PHENOL AND HEXAMETHYLENE TETRAMINE.

89. 发明授权

US3274136A Preparation of reinforced resins using glass fibers coated with plasticized vinyl chloride polymers 失效
标题翻译：使用涂有增塑氯乙烯聚合物的玻璃纤维制备增强树脂
公开(公告)号：US3274136A
公开(公告)日：1966-09-20
申请号：US24292062
申请日：1962-12-07
申请人： DOW CHEMICAL CO
发明人： GLESNER WILLIAM K , THOMPSON CLIFFORD F , KUBISIAK DONALD P
IPC分类号： C03C25/28 , C08F259/04 , C08J5/08
CPC分类号： C03C25/28 , C08F259/04 , C08J5/08

90. 发明授权

US2958614A Resin coatings for glass materials 失效
标题翻译：玻璃材料树脂涂料
公开(公告)号：US2958614A
公开(公告)日：1960-11-01
申请号：US51603355
申请日：1955-06-16
申请人： GEN ANILINE & FILM CORP
发明人： PERRY WILLIAM M
IPC分类号： C03C25/28 , C08F226/10
CPC分类号： C08F226/10 , C03C25/28

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