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    • 83. 发明申请
    • Internal Cooling of Electrolytic Smelting Cell
    • 电解冶炼电池的内部冷却
    • US20070187230A1
    • 2007-08-16
    • US11697035
    • 2007-04-05
    • Ingo Bayer
    • Ingo Bayer
    • C25C7/00
    • C25C3/085
    • An electrolytic cell for the production of metal by electrolytic reduction of a metal bearing material dissolved in a molten salt bath, the cell including a shell, and a lining on the interior of the shell, the lining including a bottom cathode lining and a side wall lining including a plurality of fluid ducts positioned against the interior surface of the shell for conducting fluid there through, the fluid ducts extending along the sides of the shell, and communicating with pump means to flow fluid through the fluid ducts.
    • 一种用于通过电解还原溶解在熔融盐浴中的金属轴承材料来生产金属的电解槽,所述电池包括壳体和壳体内部的衬里,衬里包括底部阴极衬里和侧壁 衬里包括多个流体管道,其抵靠壳体的内表面定位,用于在其中导通流体,流体管道沿着壳体的侧面延伸,并与泵装置连通以使流体流过流体管道。
    • 87. 发明授权
    • Method of producing aluminum
    • 生产铝的方法
    • US5876584A
    • 1999-03-02
    • US930082
    • 1997-10-11
    • Edmund A. Cortellini
    • Edmund A. Cortellini
    • C25C3/06C25C3/08
    • C25C3/06C25C3/085
    • A method of producing aluminum, comprising the steps of:a) providing an aluminum reduction Hall cell for reduction of alumina in molten fluoride electrolyte containing cryolite, the cell comprising a cathode, an anode and a sidewall, the sidewall having a thickness and comprising:i) a lining consisting essentially of a material selected from the group consisting of silicon nitride, silicon carbide, and boron carbide, and having a density of at least 95% of theoretical density, and no apparent porosity, andii) an insulating layer backing the lining,b) contacting the lining with an electrolyte comprising at least 60% cryolite and having a temperature of between 650.degree. C. and 1100.degree. C., andc) providing an electric current from the cathode to the anode through the electrolyte, thereby producing aluminum at the cathode, wherein the electrolyte temperature, the cryolite concentration and the thickness of the sidewall are predetermined so that the cryolite does not form a frozen crust anywhere on the lining.
    • PCT No.PCT / US96 / 07514 Sec。 371日期:1997年11月10日 102(e)1997年11月10日日期PCT提交1996年5月23日PCT公布。 公开号WO96 / 37637 日期:1996年11月28日一种生产铝的方法,包括以下步骤:a)提供铝还原霍尔电池,用于还原含氟化氢电解质的冰晶石中的氧化铝,该电池包括阴极,阳极和侧壁,侧壁具有 厚度并且包括:i)基本上由选自氮化硅,碳化硅和碳化硼的材料组成的衬里,并且具有理论密度的至少95%的密度,并且没有表观孔隙率,以及ii )衬垫衬里的绝缘层,b)使衬里与包含至少60%冰晶石并且具有在650℃和1100℃之间的温度的电解质接触,以及c)提供从阴极到 阳极通过电解质,从而在阴极处产生铝,其中电解质温度,冰晶石浓度和侧壁的厚度被预先确定,使得冰晶石不是f 在地板上的任何地方放置一个冰冻的地壳。
    • 89. 发明授权
    • Aluminum electrolytic cell method with application of refractory
protective coatings on cello components
    • 铝电解槽法在电池组件上应用耐火保护涂层
    • US5340448A
    • 1994-08-23
    • US143177
    • 1993-10-26
    • Jainagesh SekharVittorio de Nora
    • Jainagesh SekharVittorio de Nora
    • C04B41/50C04B41/52C04B41/87C04B41/89C25C3/08C25C3/12C25C3/06C25D3/66
    • C04B41/507C04B41/5025C04B41/5062C04B41/52C04B41/87C04B41/89C25C3/08C25C3/085C25C3/125Y10T428/12486Y10T428/12576Y10T428/12618Y10T428/12674Y10T428/12806Y10T428/12812Y10T428/12819Y10T428/12826Y10T428/12854
    • An adherent protective coating of a refractory material is produced on the surface of carbonaceous, refractory, ceramic, metallic or other materials serving as components of electrolytic cells operating at high temperature, by applying to such surfaces a well chosen micropyretic reaction layer from a slurry, which when dried is ignited to initiate a self-sustaining micropyretic reaction, along a combustion front, to produce condensed matter forming such refractory protective adherent coating. The slurry is preferably applied in several layers, the first layer(s) to facilitate adherence and the last layer(s) to provide protection and may contain some preformed non-reactant materials. The electrolytic cells whose components require such coatings are especially those operating at high temperature with a molten salt electrolyte, particularly those for the production of metals, aluminum being the most important. For these cells the invention provides an aluminum-wettable, adherent, refractory, protective coating for the cell-bottom carbon cathode, containing RHM material such as titanium diboride, as well as other refractory protective coatings for cell wall lining and for other cell components. Novel cell designs for the utilization of the different coatings are also provided.
    • 在碳质,耐火材料,陶瓷,金属或其他材料的表面上产生耐火材料的粘附保护涂层,其作为在高温下运行的电解池的组分,通过将这种表面从浆料中施加良好选择的微解释反应层, 当干燥时,其被点燃以开始自燃维持微反应,沿着燃烧前沿,以产生形成这种难熔保护性粘附涂层的凝聚物。 浆料优选以几层施加,第一层以促进粘合,最后一层提供保护,并且可以含有一些预先形成的非反应物材料。 其组分需要这种涂层的电解槽尤其是在熔融盐电解质,特别是用于生产金属的电解液中,在高温下运行的电解槽是最重要的。 对于这些电池,本发明为含有RHM材料如二硼化钛的电池底部碳阴极以及用于电池壁衬里和其它电池组件的其它耐火保护涂层提供了铝可润湿,粘附,耐火的保护涂层。 还提供了用于不同涂层的新型电池设计。
    • 90. 发明授权
    • Linings for aluminum reduction cells
    • 铝还原电池衬片
    • US5167787A
    • 1992-12-01
    • US696356
    • 1991-05-06
    • Tom J. HudsonJohn McIntyrePierre TremblayClaude AllaireBohdan Gnyra
    • Tom J. HudsonJohn McIntyrePierre TremblayClaude AllaireBohdan Gnyra
    • C25C3/08
    • C25C3/085
    • The amount of electrically conductive material in the bottom floor lining of a conventional aluminum reduction cell is reduced by using a non-conductive lining material in its place. The non-conductive material separates the remaining electrically conductive regions from the sidewall linings of the cell and preferably confines the electrically conductive material to the "anode shadow" region of the cell floor. In another embodiment joints between the conductive and non-conductive regions are positioned such that they are covered by cell freeze (solid electrolyte) during operation of the cell. This prevents liquid cell contents penetrating the joint and adversely affecting the cell lining, thus shortening the life of the cell. The non-conductive material preferably comprises a particulate alumina mixture made up of large shapes which firmly compact together and smaller particles which fill the remaining voids. Optionally, the mixture may be bonded together with amorphous alumina, in which case the mixture can also be used for cell wall linings. The linings can be used in reduction cells of conventional design and reduces undesirable magnetohydrodynamic effects as well as pollution hazards caused by conventional carbonaceous cell linings.
    • 传统的铝还原电池的底层衬里中的导电材料的量通过在其位置使用非导电衬里材料来减少。 不导电材料将剩余的导电区域与电池的侧壁衬里分开,并且优选将导电材料限制在电池板底板的“阳极阴影”区域。 在另一个实施例中,导电区域和非导电区域之间的接头被定位成使得它们在电池工作期间被细胞冷冻(固体电解质)覆盖。 这防止液体细胞内含物穿透关节并且不利地影响细胞衬里,从而缩短细胞的寿命。 非导电材料优选包括由大的形状组成的颗粒状氧化铝混合物,其牢固地压实在一起,并且填充剩余空隙的较小的颗粒。 任选地,混合物可以与无定形氧化铝结合在一起,在这种情况下,混合物也可用于细胞壁衬里。 衬里可用于常规设计的还原电池,并减少不期望的磁流体动力学影响以及由常规碳质电池衬垫引起的污染危害。