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    • 83. 发明授权
    • Method for producing water absorbent resin particle
    • 吸水性树脂颗粒的制造方法
    • US09593212B2
    • 2017-03-14
    • US12296808
    • 2007-09-28
    • Shigeru SakamotoYoshio IrieHiroyuki IkeuchiMakoto NagasawaKunihiko IshizakiSayaka Machida
    • Shigeru SakamotoYoshio IrieHiroyuki IkeuchiMakoto NagasawaKunihiko IshizakiSayaka Machida
    • C08J3/12B29B17/00
    • C08J3/12B29B9/06B29B17/00C08J2300/14Y02W30/62
    • The present invention provides a method for producing a water absorbent resin particle, in high productivity, not only in a controlled manner of particle size but also enhancing fundamental property (absorption capacity or absorption capacity against pressure) of a water absorbent resin. A method for producing a water absorbent resin particle having the cross-linking polymerization step for an aqueous solution of an unsaturated monomer; the grain refining step for water-swellable, water-containing gel-like cross-linked polymer (a) obtained in the cross-linking polymerization step; the drying step for grain refined gel; and the crushing step for a dried substance, wherein, in the grain refining step for the water-swellable, water-containing gel-like cross-linked polymer (a), water-swellable, water-containing gel-like cross-linked polymer (b), having solid content or centrifuge retention capacity different from solid content or centrifuge retention capacity of the cross-linked polymer (a) by equal to or larger than 1%, is subjected to coexistence.
    • 本发明提供了一种生产吸水性树脂颗粒的方法,不仅以受控的粒度控制,而且提高了吸水性树脂的基本性能(吸收能力或抗吸收能力)。 一种制备具有用于不饱和单体的水溶液的交联聚合步骤的吸水性树脂颗粒的方法; 在交联聚合步骤中获得的水溶胀性含水凝胶状交联聚合物(a)的晶粒细化步骤; 颗粒精制凝胶的干燥步骤; 和干物质的破碎步骤,其中在水溶胀性含水凝胶状交联聚合物(a)的晶粒细化工序中,水溶胀性含水凝胶状交联聚合物 (b)具有不同于交联聚合物(a)的固体含量或离心保留能力等于或大于1%的固体含量或离心保留能力共存。
    • 84. 发明申请
    • BLENDED FLUOROPOLYMER COMPOSITIONS
    • 混合氟聚合物组合物
    • US20170066914A1
    • 2017-03-09
    • US15211453
    • 2016-07-15
    • WHITFORD CORPORATION
    • Leonard W. HarveyMichael CoatesJulie K. Wright
    • C08L27/18C09D127/18C08J3/00C09D5/03
    • C08L27/18C08J3/005C08J3/12C08J2327/18C08L27/12C08L27/24C08L29/10C08L2201/50C08L2205/02C08L2205/025C09D5/03C09D127/12C09D127/18C09D129/10Y10T428/2982C08L2666/04
    • Blended fluoropolymer compositions are provided. In one embodiment, a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) that has been polymerized via a dispersion or emulsion polymerization process, and which has not been agglomerated, irradiated, or thermally degraded. The LPTFE may be in the form of an aqueous dispersion, having a mean particle size of less than 1.0 microns (□m), with the LPTFE having a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processable fluoropolymer (MPF), such as methylfluoroalkoxy (MFA), fluorinated ethylene propylene (FEP), or perfluoroalkoxy (PFA), for example, in the form of an aqueous dispersion, and having a mean particle size of less than 1.0 microns (□m). Blending of the dispersions facilitates interaction of the LPTFE and MPF on a submicron level to facilitate intimate blending such that, when the blended fluoropolymer composition is dried, a crystal structure representing a true alloy of the fluoropolymers is formed, having melt characteristics that differ from those of the individual fluoropolymers. The blended fluoropolymer composition may be used to provide a coating having improved impermeability, stain resistance, abrasion resistance, smoothness, and higher contact angles.
    • 提供混合的含氟聚合物组合物。 在一个实施方案中,将第一含氟聚合物的液体分散体与第二含氟聚合物的液体分散体共混。 第一含氟聚合物可以是聚四氟乙烯(PTFE),例如已经通过分散体或乳液聚合方法聚合并且未被聚集,照射或热降解的低分子量PTFE(LPTFE)。 LPTFE可以是水分散体的形式,其平均粒度小于1.0微米(□m),LPTFE的第一熔融温度(Tm)为332℃或更低。 第二含氟聚合物可以是可熔融加工的含氟聚合物(MPF),例如甲基氟代烷氧基(MFA),氟化乙烯丙烯(FEP)或全氟烷氧基(PFA),例如以水分散体的形式,并且具有平均粒径 小于1.0微米(□m)。 分散体的混合促进了LPTFE和MPF在亚微米级的相互作用,以促进紧密共混,使得当混合的含氟聚合物组合物被干燥时,形成表示含氟聚合物的真正合金的晶体结构,其熔体特性与那些 的各种含氟聚合物。 混合的含氟聚合物组合物可用于提供具有改进的不渗透性,耐污性,耐磨性,光滑度和更高接触角的涂层。