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    • 81. 发明授权
    • Polyester polyols and their use in two-component polyurethane lacquers
    • 聚酯多元醇及其在双组分聚氨酯漆中的应用
    • US6162891A
    • 2000-12-19
    • US352664
    • 1994-12-09
    • Christian WamprechtMichael SonntagJurgen Meixner
    • Christian WamprechtMichael SonntagJurgen Meixner
    • C08G18/68C08G18/78C08G63/52C09D175/14C08G18/42
    • C09D175/14C08G18/68C08G18/7831C08G63/52
    • The present invention relates to polyester polyols having hydroxyl numbers of 175 to 520 which are the reaction products ofa) 50 to 60 mole % of a polyol component containing(i) 0 to 39 mole % of one or more dihydric aliphatic or cycloaliphatic alcohols having at least 2 carbon atoms other than neopentyl glycol,(ii) 20 to 59 mole % of neopentyl glycol and(iii) 41 to 80 mole % of one or more at least trihydric aliphatic alcohols containing at least 3 carbon atoms andb) 40 to 50 mole % of a dicarboxylic acid component containing(iv) 0 to 60 mole % of one or more aliphatic or cycloaliphatic, saturated or unsaturated dicarboxylic acids or their anhydrides having at least 2 carbon atoms other than fumaric acid, itaconic acid and maleic acid or their anhydrides and(v) 40 to 100 mole % of one or more of fumaric acid, itaconic acid, maleic acid or their anhydrides,wherein the percentages set forth in a) and b) each add up to 100.The present invention also relates to the use of these polyester polyols, optionally in admixture with other organic polyhydroxyl compounds, as a binder component for two-component polyurethane lacquers also containing lacquer polyisocyanates, more particularly for the production of lacquer coatings on large vehicles and in car repair lacquering.
    • 本发明涉及羟基数为175〜520的聚酯多元醇,其为a)50〜60摩尔%的多元醇成分的反应产物,所述多元醇成分含有(i)0〜39摩尔%的一种或多种二元脂肪族或脂环族醇, 除新戊二醇以外的至少2个碳原子,(ii)20〜59摩尔%的新戊二醇和(iii)41〜80摩尔%的含有至少3个碳原子的一种以上至少三元脂肪醇,b)40〜 50摩尔%的含有(iv)0至60摩尔%的一种或多种脂族或脂环族饱和或不饱和二羧酸或其酸酐的二羧酸组分,其中除了富马酸,衣康酸和马来酸以外具有至少2个碳原子,或 它们的酸酐和(v)40至100摩尔%的富马酸,衣康酸,马来酸或其酸酐中的一种或多种,​​其中a)和b)中列出的百分比各自加到100上。本发明还涉及 使用这些p 醇酯多元醇,任选与其它有机多羟基化合物混合,作为也包含漆多异氰酸酯的双组分聚氨酯漆的粘合剂组分,更特别地用于在大型车辆和汽车修漆上生产漆涂料。
    • 84. 发明授权
    • Binder compositions and their use in coating compositions and sealing
compositions
    • 粘合剂组合物及其在涂料组合物和密封组合物中的用途
    • US5268428A
    • 1993-12-07
    • US748297
    • 1991-08-21
    • Christian WamprechtHarald BlumJosef Pedain
    • Christian WamprechtHarald BlumJosef Pedain
    • C08G59/20C08G59/00C08G59/32C08K5/05C08L35/00C08L63/00C08L75/04C09D5/34C09D133/14C09D163/00C09D167/00C08F8/14C08L33/08
    • C09D133/14C09D167/00C09D5/34C08L75/04
    • The present invention relates to binder compositions containingA) 10 to 99 parts by weight of a copolymer component containing at least one copolymer prepared from olefinically unsaturated compositions having a weight average molecular weight of 1,500 to 75,000 and having in chemically bound form both(i) 1 to 30% by weight of cyclic carboxylic anhydride groups (calculated as C.sub.4 H.sub.2 O.sub.3) and(ii) 1 to 29% by weight of epoxide groups (calculated as C.sub.2 H.sub.3 O) andB) 1 to 90 parts by weight of a hydroxyl component containing at least one organic polyol having at least two hydroxyl groups per molecule,provided that for every anhydride group of component A) there are 0.1 to 10 hydroxyl groups of component B).The present invention also relates to the use of these binder compositions as binders for heat-curing coating compositions or sealing compositions optionally containing paint auxiliaries and additives or as binders for room-temperature-curing sealing or coating compositions containing catalysts and, optionally, other paint auxiliaries and additives.
    • 本发明涉及粘合剂组合物,其包含A)10至99重量份的共聚物组分,所述共聚物组分含有至少一种由烯属不饱和组合物制备的共聚物,其重均分子量为1,500至75,000,并具有化学键合形式,(i) 1至30重量%的环状羧酸酐基团(以C 4 H 2 O 3计)和(ii)1至29重量%的环氧基团(以C 2 H 3 O计算)和B)1至90重量份的至少含有至少 一个每分子具有至少两个羟基的有机多元醇,条件是对于组分A)的每个酸酐基团,组分B)中都有0.1至10个羟基。 本发明还涉及这些粘合剂组合物作为粘合剂用于热固化涂料组合物或任选地含有涂料助剂和添加剂的密封组合物或用作室温固化密封剂的粘合剂或含有催化剂和任选的其它涂料的涂料组合物的粘合剂 助剂和助剂。