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81. 发明授权

US06656889B2 Thermoplastic molding compositions containing additive mixtures 有权
标题翻译：含有添加剂混合物的热塑性成型组合物
公开(公告)号：US06656889B2
公开(公告)日：2003-12-02
申请号：US09955785
申请日：2001-09-18
申请人： Herbert Eichenauer
发明人： Herbert Eichenauer
IPC分类号： C08K500
CPC分类号： C08L25/04 , C08K5/01 , C08K5/098 , C08K5/20 , C08K5/372 , C08L25/12 , C08L51/04 , C08L55/02 , C08L2666/24 , C08L2666/04
摘要： A thermoplastic molding composition comprising A) a thermopolastic polymer, e.g., a copolymer of styrene and acyrlonitrile, B) a graft copolymer, e.g., a graft copolymer of styrene, acrylonitrile and polybutadiene, and C) an additive mixture is described. The additive mixture C) comprises a combination of at least three components selected from components (I), (II), (III) and (IV). Component (I) contains carboxylic acid metal salt groups, e.g., magnesium stearate. Component (II) contains both carboxylic acid ester linkages and thio linkages, e.g., esters of &bgr;-thiodipropionic acid with monhydric alcohols. Component (III) contains amide linkages, e.g., ethylenediamine bisstearyl amide. Component (IV) is a compound that is different than components (I)-(III), e.g., a low molecular weight styrene/acrylonitrile copolymer. Also described are molded articles prepared from the thermoplastic molding composition of the present invention.
摘要翻译：一种热塑性模塑组合物，其包含A）热弹性聚合物，例如苯乙烯和丙烯腈的共聚物，B）接枝共聚物，例如苯乙烯，丙烯腈和聚丁二烯的接枝共聚物，和C）添加剂混合物。添加剂混合物C）包含选自组分（I），（II），（III）和（IV）的至少三种组分的组合。组分（I）含有羧酸金属盐基团，例如硬脂酸镁。组分（II）含有羧酸酯键和硫键，例如β-硫代二丙酸与一元醇的酯。组分（III）含有酰胺键，例如乙二胺双硬脂酰胺。组分（IV）是不同于组分（I） - （III）的化合物，例如低分子量苯乙烯/丙烯腈共聚物。还描述了由本发明的热塑性模塑组合物制备的模塑制品。

82. 发明授权

US06646045B2 Thermoplastic molding compositions 失效
标题翻译：热塑性成型组合物
公开(公告)号：US06646045B2
公开(公告)日：2003-11-11
申请号：US09998440
申请日：2001-11-30
申请人： Herbert Eichenauer
发明人： Herbert Eichenauer
IPC分类号： C08F25500
CPC分类号： C08L51/04 , C08F279/02 , C08F279/04 , C08L55/02 , C08L2666/14 , C08L2666/24 , C08L2666/04
摘要： Thermoplastic molding compositions containing graft polymers produced with different initiator systems are disclosed. The compositions are distinguished by a combination of good toughness and reduced opacity. As a result, appreciably smaller quantities of pigment are needed to color the molding composition.
摘要翻译：公开了含有用不同引发剂体系生产的接枝聚合物的热塑性成型组合物。组合物通过良好的韧性和降低的不透明度的组合来区分。结果，需要明显较少量的颜料来着色成型组合物。

83. 发明授权

US06407163B1 Highly impact-resistant ABS moulding materials 失效
标题翻译：耐冲击ABS成型材料
公开(公告)号：US06407163B1
公开(公告)日：2002-06-18
申请号：US09868208
申请日：2001-06-13
申请人： Herbert Eichenauer
发明人： Herbert Eichenauer
IPC分类号： C08L5502
CPC分类号： C08L55/02 , C08F279/04 , C08L2666/24 , C08L2666/04
摘要： The invention provides a combination of specific graft polymers produced by emulsion polymerization on the basis of a mixture of three rubber latices with ABS polymers produced by solution, bulk or suspension polymerization, by which products with extremely high impact strength values are obtained.
摘要翻译：本发明提供了通过乳液聚合制备的特定接枝聚合物的组合，其基于三种橡胶胶乳与通过溶液，本体或悬浮聚合制备的ABS聚合物的混合物，通过该混合物获得具有极高冲击强度值的产品。

84. 发明授权

US06211269B1 Glass-fiber-reinforced thermoplastic ABS compositions 失效
标题翻译：玻璃纤维增强热塑性ABS组合物
公开(公告)号：US06211269B1
公开(公告)日：2001-04-03
申请号：US09178037
申请日：1998-10-23
申请人： Alfred Pischtschan , Herbert Eichenauer , Horst Peters
发明人： Alfred Pischtschan , Herbert Eichenauer , Horst Peters
IPC分类号： C08K557
CPC分类号： C08K5/57 , C08K7/14 , C08L55/02
摘要： Glass-fiber-reinforced ABS molding compounds containing up to 5% by weight of a tin-containing organic compound corresponding to formula (I) and/or (II) in which R1 and R2=C1-12 alkyl, R3, R4=C1-18 alkyl, R5=—(CH2)—n, —CH═CH—, —CH═CR1—, X=H, 1 equivalent of an alkali metal, preferably Na or K, ½ equivalent of an alkaline earth metal, preferably Mg or Ca, n=2-8.
摘要翻译：含有至多5重量％对应于式（I）和/或（II）的含锡有机化合物的玻璃纤维增强ABS模塑料，其中R 1和R 2 = C 1-12烷基，R 3，R 4 = C1- 18烷基，R5 = - （CH2）-n，-CH = CH-，-CH = CR1-，X = H，1当量碱金属，优选Na或K，1/2当量碱土金属，优选Mg 或Ca，n = 2-8。

85. 发明授权

US6140426A Graft polymer moulding compositions with reduced deposit formation 失效
标题翻译：具有降低沉积物形成的接枝聚合物模塑组合物
公开(公告)号：US6140426A
公开(公告)日：2000-10-31
申请号：US47254
申请日：1998-03-24
申请人： Bahman Sarabi , Herbert Eichenauer , Edgar Leitz , Heinrich Alberts , Thomas Eckel , Dieter Wittmann
发明人： Bahman Sarabi , Herbert Eichenauer , Edgar Leitz , Heinrich Alberts , Thomas Eckel , Dieter Wittmann
IPC分类号： B29C45/00 , C08K5/00 , C08L25/04 , C08L25/12 , C08L33/20 , C08L35/00 , C08L51/04 , C08L55/02 , C08F279/02
CPC分类号： C08L25/12 , C08K5/0008 , C08L51/04 , C08L55/02
摘要： The present invention relates to thermoplastic graft polymer moulding compositions for high-gloss applications, which exhibit a reduced tendency of the additives to exude out of the thermoplastic composition during processing, and which exhibit reduced deposit build-up in the mould.
摘要翻译：本发明涉及用于高光泽应用的热塑性接枝聚合物模塑组合物，其在加工过程中表现出添加剂从热塑性组合物中渗出的倾向降低，并且在模具中表现出降低的沉积物积聚。

86. 发明授权

US5883189A Thermoplastic high-gloss moulding compositions of the abs type 失效
标题翻译： abs型热塑性高光泽成型组合物
公开(公告)号：US5883189A
公开(公告)日：1999-03-16
申请号：US975561
申请日：1997-11-21
申请人： Herbert Eichenauer , Edgar Leitz
发明人： Herbert Eichenauer , Edgar Leitz
IPC分类号： C08F279/02 , C08L25/12 , C08L51/04 , C08L55/02 , C08L67/00 , C08L69/00 , C08L77/00
CPC分类号： C08L25/12 , C08F279/02 , C08L51/04 , C08L55/02 , C08L2201/02
摘要： Thermoplastic moulding compositions of the ABS type, containingI) at least one graft polymer, obtainable by emulsion polymerisation of resin-forming monomers in the presence of a mixture comprising a butadiene polymer latex (A) having a particle diameter d.sub.50 of .ltoreq.320 nm, a particle diameter distribution of 30 to 100 nm in width and a gel content of .ltoreq.70 wt. % and a butadiene polymer latex (B) having a particle diameter d.sub.50 of .gtoreq.370 nm, a particle diameter distribution of 50 to 500 nm in width and a gel content of .gtoreq.270 wt. %,II) at least one graft polymer, obtainable by emulsion polymerisation of resin-forming monomers in the presence of a butadiene polymer latex (C) having a particle diameter d.sub.50 of from 110 to 150 nm, a particle diameter distribution of 20 to 50 nm in width and a gel content of from 80 to 98 wt. %, andIII) at least one rubber-free copolymer composed of resin-forming monomersand the use of the moulding compositions for the production of mouldings.
摘要翻译： ABS型的热塑性模塑组合物，其包含I）至少一种接枝聚合物，其可通过在包含粒径d50为/ = 320的丁二烯聚合物胶乳（A）的混合物存在下，通过乳液聚合树脂形成单体获得， nm，宽度为30〜100nm，凝胶含量为70重量％的粒径分布。％和粒径d50> 370nm的丁二烯聚合物胶乳（B），宽度为50〜500nm，凝胶含量≥270wt。％，II）至少一种接枝聚合物，其可通过在具有110至150nm的粒径d50的丁二烯聚合物胶乳（C）的存在下，通过乳液聚合树脂形成单体获得，粒径分布为20至50 宽度为nm，凝胶含量为80至98重量％。％和III）至少一种由树脂形成单体组成的无橡胶共聚物和用于生产模制品的模塑组合物的用途。

87. 发明授权

US5674939A ABS moulding compounds with novel morphology 失效
标题翻译： ABS模塑料具有新颖的形态
公开(公告)号：US5674939A
公开(公告)日：1997-10-07
申请号：US557359
申请日：1995-11-13
申请人： Herbert Eichenauer , Adolf Schmidt , Edgar Leitz , Karl-Erwin Piejko
发明人： Herbert Eichenauer , Adolf Schmidt , Edgar Leitz , Karl-Erwin Piejko
IPC分类号： C08L51/04 , C08F279/00 , C08F279/04 , C08L55/00 , C08L55/02
CPC分类号： C08L55/02 , C08F279/04
摘要： Moulding compounds the ABS type consisting of at least one resin matrix and a particulate graft-rubber polymer distributed therein and produced by emulsion polymerisation, wherein at least 70% of the graft-rubber particles (number) exhibit a structure of the rubber phase which can be detected by photographs taken with the aid of a transmission electron microscope and in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles exhibits an irregularly jagged structure such that, for each particle illustrated, 5 to 30 of such jagged projections are present which differ from an idealised round particle (with a diameter d) by virtue of a diameter d+d/x with x=3 to 15, as well as a process for the manufacture of said moulding compounds.
摘要翻译：成型化合物由至少一种树脂基质和分散在其中的颗粒状接枝橡胶聚合物组成的ABS类型，通过乳液聚合制备，其中至少70％的接枝橡胶颗粒（数量）表现出橡胶相的结构，其可以通过借助透射电子显微镜拍摄的照片进行检测，其中各个颗粒含有不规则的树脂形成性聚合物的细胞夹杂物，并且颗粒的表面呈现不规则的锯齿状结构，使得对于所示的每个颗粒为5〜30 存在这样的锯齿形突起，其与理想化的圆形颗粒（直径d）不同，其直径d = + d / x，x = 3〜15，以及制造所述模塑料的方法。

88. 发明授权

US5302664A ABS molding compounds 失效
标题翻译： ABS模塑料
公开(公告)号：US5302664A
公开(公告)日：1994-04-12
申请号：US74006
申请日：1993-06-08
申请人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
发明人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
IPC分类号： C08L25/02 , C08L25/00 , C08L25/16 , C08L33/00 , C08L33/04 , C08L33/12 , C08L33/20 , C08L35/06 , C08L51/00 , C08L51/04 , C08L51/06 , C08L55/00 , C08L55/02 , C08L69/00 , C08L25/12
CPC分类号： C08L25/16 , C08L35/06 , C08L69/00 , C08L51/04
摘要： Thermoplastic molding compounds comprising three resin components with different molecular weights and two graft rubbers. The thermoplastic molding compounds have good toughness, high heat resistance, adjustable surface gloss and good thermoplastic processability. The invention also relates to a process for the production of the molding compounds.
摘要翻译：包含三种具有不同分子量的树脂组分和两种接枝橡胶的热塑性模塑料。热塑性成型化合物具有良好的韧性，高耐热性，可调表面光泽和良好的热塑性加工性。本发明还涉及一种用于生产模塑料的方法。

89. 发明授权

US5270385A Antistatic, thermoplastic moulding compounds based on aromatic polycarbonates and aromatic vinyl polymers 失效
标题翻译：基于芳族聚碳酸酯和芳族乙烯基聚合物的抗静电，热塑性模塑料
公开(公告)号：US5270385A
公开(公告)日：1993-12-14
申请号：US535184
申请日：1992-06-08
申请人： Hans-Josef Buysch , Norbert Schon , Herbert Eichenauer , Hans-Jurgen Kress , Josef Buekers
发明人： Hans-Josef Buysch , Norbert Schon , Herbert Eichenauer , Hans-Jurgen Kress , Josef Buekers
IPC分类号： C08L69/00 , C08G63/48 , C08G63/91 , C08L51/00
CPC分类号： C08L69/00
摘要： Thermoplastic moulding compounds of 99.8-95% by weight of a mixture consisting of an aromatic polycarbonate, a graft polymer and optionally a thermoplastic vinyl polymer and/or the usual additives and 0.2 to 5% by weight of a polyalkylene ether which has been grafted with a polymer of C.sub.1 -C.sub.6 alkyl(meth)acrylates, cyclo-alkylacrylates or -methacrylates and optionally styrene or .alpha.-methylstyrene.
摘要翻译：由芳族聚碳酸酯，接枝聚合物和任选的热塑性乙烯基聚合物和/或通常的添加剂组成的混合物的99.8-95重量％的热塑性模制化合物和0.2-5重量％已经被接枝的聚亚烷基醚（甲基）丙烯酸C1-C6烷基酯，环烷基丙烯酸酯或甲基丙烯酸酯和任选的苯乙烯或α-甲基苯乙烯的聚合物。

90. 发明授权

US5248727A Vinyl chloride polymer based moulding compositions with reduced fogging 失效
标题翻译：基于氯乙烯聚合物的模塑组合物具有减少的雾化
公开(公告)号：US5248727A
公开(公告)日：1993-09-28
申请号：US892397
申请日：1992-05-18
申请人： Christian Lindner , Adolf Schmidt , Herbert Eichenauer , Karl-Erwin Piejko , Karl-Heinz Ott
发明人： Christian Lindner , Adolf Schmidt , Herbert Eichenauer , Karl-Erwin Piejko , Karl-Heinz Ott
IPC分类号： C08F2/26 , C08F291/02 , C08L27/06
CPC分类号： C08F291/02 , C08F2/26 , C08L27/06
摘要： Thermoplastic molding compositions of a vinyl chloride polymer and one or more emulsion polymers made with special emulsifiers have improved properties for technical application, such as reduced fogging. They are used for the production of molded articles, sheet products and films.
摘要翻译：氯乙烯聚合物和由特殊乳化剂制成的一种或多种乳液聚合物的热塑性模塑组合物具有改进的技术应用性能，例如减少雾化。它们用于生产模制品，片材和薄膜。

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