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    • 83. 发明授权
    • Methods of forming conductive copper-based structures using a copper-based nitride seed layer without a barrier layer and the resulting device
    • 使用没有阻挡层的铜基氮化物种子层形成导电铜基结构的方法和所得到的器件
    • US08753975B1
    • 2014-06-17
    • US13757288
    • 2013-02-01
    • GLOBALFOUNDRIES Inc.
    • Xunyuan ZhangLarry ZhaoMing HeSean LinJohn IacoponiErrol Todd Ryan
    • H01L21/4763
    • H01L21/76873H01L21/76843H01L21/76855H01L21/76856H01L23/53238H01L2924/0002H01L2924/00
    • A method includes forming a trench/via in a layer of insulating material, forming a first layer comprised of silicon or germanium on the insulating material in the trench/via, forming a copper-based seed layer on the first layer, converting at least a portion of the copper-based seed layer into a copper-based nitride layer, depositing a bulk copper-based material on the copper-based nitride layer so as to overfill the trench/via and performing at least one chemical mechanical polishing process to remove excess materials positioned outside of the trench/via to thereby define a copper-based conductive structure. A device includes a layer of insulating material, a copper-based conductive structure positioned in a trench/via within the layer of insulating material and a copper-based nitride layer positioned between the copper-based conductive structure and the layer of insulating material, wherein the copper-based nitride layer contacts both of the copper-based conductive structure and the layer of insulating material.
    • 一种方法包括在绝缘材料层中形成沟槽/通孔,在沟槽/通孔中的绝缘材料上形成由硅或锗构成的第一层,在第一层上形成铜基种子层,至少转化为 铜基种子层的一部分成为铜基氮化物层,在铜基氮化物层上沉积大量铜基材料,以覆盖沟槽/通孔,并执行至少一种化学机械抛光工艺以除去过量的 位于沟槽/通孔外部的材料,从而限定铜基导电结构。 一种器件包括绝缘材料层,位于绝缘材料层内的沟槽/通孔中的铜基导电结构以及位于铜基导电结构和绝缘材料层之间的铜基氮化物层,其中 铜基氮化物层接触铜基导电结构和绝缘材料层。