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81. 发明授权

US5490967A Low heat release polymeric composites 失效
标题翻译：低放热聚合物复合材料
公开(公告)号：US5490967A
公开(公告)日：1996-02-13
申请号：US371332
申请日：1995-01-11
申请人： Patrick H. Martin , Stephen E. Bales , Peter K. Kim , Ritchie A. Wessling
发明人： Patrick H. Martin , Stephen E. Bales , Peter K. Kim , Ritchie A. Wessling
IPC分类号： B32B27/08 , C08K7/02 , B32B5/24
CPC分类号： B32B27/08 , C08K7/02 , Y10T428/249962 , Y10T428/249964 , Y10T428/249989
摘要： This invention relates to a low heat release, low density, fiber-reinforced composite comprising a matrix comprising a thermoplastic polymer selected from the group consisting of polyarylsulfone, polyethersulfone, polyetheretherketone, polyetherketoneketone, a copolycarbonate of 4,4'-thiodiphenol and at least one member of the group consisting of bisphenol A, 9,9-bis(4-hydroxyphenyl) fluorene, and 1,1-bis-(4-hydroxyphenyl)-1-phenyl ethane, a copolycarbonate of bisphenol A and 9,9-bis(4-hydroxyphenyl) fluorene, 1,1-bis(4-hydroxyphenyl)-1-phenyl ethane polycarbonate, bisphenol A polycarbonate, and polyetherimide, and from about 10 to about 70 percent by weight of the composite of randomly oriented reinforcing fibers, less than 0.5 inch in length, distributed throughout the matrix. The matrix has a void volume of from about 20 to about 90 percent by volume. The composite has a thermoplastic skin layer on each of the major surfaces thereof. A process for making the composite is also disclosed.
摘要翻译：本发明涉及一种低放热，低密度纤维增强复合材料，其包含基质，其包含选自聚芳基砜，聚醚砜，聚醚醚酮，聚醚酮酮，4,4'-硫代二酚的共聚碳酸酯和至少一种由双酚A，9,9-双（4-羟基苯基）芴和1,1-双 - （4-羟基苯基）-1-苯基乙烷组成的组的成员，双酚A的共聚碳酸酯和9,9-双（4-羟基苯基）芴，1,1-双（4-羟基苯基）-1-苯基乙烷聚碳酸酯，双酚A聚碳酸酯和聚醚酰亚胺，和约10至约70重量％的无规取向增强纤维的复合材料，长度小于0.5英寸，分布在整个矩阵中。基质具有约20至约90体积％的空隙体积。复合材料在其每个主表面上具有热塑性表层。还公开了制备复合材料的方法。

82. 发明授权

US5034026A Polybenzazole polymers containing indan moieties 失效
标题翻译：含吲哚部分的聚吲哚聚合物
公开(公告)号：US5034026A
公开(公告)日：1991-07-23
申请号：US513316
申请日：1990-04-20
申请人： John D. Summers , Ritchie A. Wessling
发明人： John D. Summers , Ritchie A. Wessling
IPC分类号： B01D71/62 , C08G73/06 , C08G73/22
CPC分类号： C08G73/22 , B01D71/62
摘要： Polybenzazole polymer containing indan moieties may be synthesized. Those polymers can be fabricated into membranes, which are useful for gas separations.
摘要翻译：可以合成含吲哚部分的聚吲哚聚合物。那些聚合物可以制成膜，这对于气体分离是有用的。

83. 发明授权

US4992485A Microporous peek membranes and the preparation thereof 失效
标题翻译：微孔窥镜膜及其制备
公开(公告)号：US4992485A
公开(公告)日：1991-02-12
申请号：US255220
申请日：1988-10-11
申请人： Ja-Young Koo , Chieh-Chun Chau , Joel R. Racchini , Ritchie A. Wessling , Matthew T. Bishop
发明人： Ja-Young Koo , Chieh-Chun Chau , Joel R. Racchini , Ritchie A. Wessling , Matthew T. Bishop
IPC分类号： B01D71/52 , B29C67/06 , B29C70/06 , B29K71/00 , B29K105/04 , B29K105/08 , B29L31/14 , C08J5/18 , C08J9/28 , D01D5/24 , D01F6/76 , D01F6/78
CPC分类号： C08J9/28 , B01D71/52 , D01D5/24 , C08J2371/00 , Y10T428/24504
摘要： A microporous polyetheretherketone (PEEK) membrane in the form of films and hollow fibers formed without sulfonating the PEEK polymer. Solid fibers and articles are also claimed. A method of making membranes, fibers and articles from solutions of PEEK in non-sulfonating acid solvents in claimed. Solvents include methane sulfonic acid and trifluoromethane sulfonic acid. Sulfuric acid may be used as a diluent in non-sulfonating amounts. PEEK membranes are used as supports for composite ultrafiltration and reverse osmosis membranes. A method of making membranes, fibers, and articles is also described.

84. 发明授权

US4904385A Porous filter media and membrane support means 失效
标题翻译：多孔过滤介质和膜支撑装置
公开(公告)号：US4904385A
公开(公告)日：1990-02-27
申请号：US196176
申请日：1988-05-19
申请人： Ritchie A. Wessling , Larry D. Yats , Alan F. Burmester
发明人： Ritchie A. Wessling , Larry D. Yats , Alan F. Burmester
IPC分类号： B01D39/16 , B01D39/20 , B01D69/10 , D21H27/08
CPC分类号： D21H27/08 , B01D39/163 , B01D39/2024 , B01D69/10
摘要： A method for filtering liquid or gaseous materials where the filtration is conducted with a porous filter media prepared from an aqueous wet-laid, lofted fiber-reinforced composite sheet, the composite sheet comprising a heat fusible polymer, reinforcing fibers and a binder. The random fiber composite sheet can be selectively lofted or recompressed to form filter media having variable porosity. Also, a membrane support means prepared by applying or treating the fiber-reinforced composite sheet with a discriminating membrane layer.
摘要翻译：一种用于过滤液体或气体材料的方法，其中用由湿法成网的高纬纤维增强复合片材制备的多孔过滤介质进行过滤，所述复合片材包含热熔聚合物，增强纤维和粘合剂。无规纤维复合片材可以选择性地放置或再压缩以形成具有可变孔隙率的过滤介质。而且，通过用鉴别膜层施加或处理纤维增强复合片而制备的膜支撑装置。

85. 发明授权

US4839203A Semi-permeable membranes prepared via reaction of cationic groups with nucleophilic groups 失效
标题翻译：通过阳离子基团与亲核基团反应制备的半透膜
公开(公告)号：US4839203A
公开(公告)日：1989-06-13
申请号：US86122
申请日：1987-08-17
申请人： Thomas E. Davis , Donald L. Schmidt , Jee I. Kau , Ritchie A. Wessling , Sharon S. Whipple , Richard F. Fibiger , Dale M. Pickelman
发明人： Thomas E. Davis , Donald L. Schmidt , Jee I. Kau , Ritchie A. Wessling , Sharon S. Whipple , Richard F. Fibiger , Dale M. Pickelman
IPC分类号： B01D67/00 , B01D69/08 , B01D69/12 , B01D69/14 , B01D71/40 , B01D71/44 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/72 , B01D71/80 , B01D71/82
CPC分类号： B01D67/0088 , B01D67/0093 , B01D69/08 , B01D69/125 , B01D69/14 , B01D71/40 , B01D71/44 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/72 , B01D71/80 , B01D71/82 , B01D2323/30
摘要： A novel composite membrane and methods of making the membrane are described. The discriminating layer of the membrane is prepared by reaction of a reactive cationic compound group with a compound bearing a nucleophilic moiety. At least one of the reactants bears an average of two or more reactive groups. The reaction product contains covalent bonds formed via charge eliminating reactions.In a preferred embodiment of the invention, the nucleophilic group is anionic and a coacervate is formed initially on a microporous substrate. The resulting membrane may be useful for reverse osmosis, gas or ultrafiltration separations.
摘要翻译：描述了一种新型复合膜及其制备方法。膜的鉴别层通过反应性阳离子化合物基团与带有亲核部分的化合物的反应来制备。至少一种反应物平均具有两个或更多个反应性基团。反应产物含有通过电荷消除反应形成的共价键。在本发明的优选实施方案中，亲核基团是阴离子的，并且最初在微孔基材上形成凝聚层。所得的膜可用于反渗透，气体或超滤分离。

86. 发明授权

US4806439A Temporary barrier layer in batteries 失效
标题翻译：电池中的临时阻隔层
公开(公告)号：US4806439A
公开(公告)日：1989-02-21
申请号：US152125
申请日：1988-02-04
申请人： Ritchie A. Wessling , Jang-hi Im
发明人： Ritchie A. Wessling , Jang-hi Im
IPC分类号： H01M2/16 , H01M6/14 , H01M6/30
CPC分类号： H01M2/1686 , H01M2/1653 , H01M6/14 , H01M6/30 , H01M2300/002
摘要： There is disclosed a separator medium for fluid-activated primary electrochemical battery cells of the reserve type. The separator medium comprises a thin, substantially impermeable film of a Lewis base polymer which is soluble in the activating electrolyte solution.
摘要翻译：公开了一种用于储备型流体活化的初级电化学电池单元的隔离介质。分离器介质包括可溶于活化电解质溶液的路易斯碱聚合物薄的基本上不可渗透的薄膜。

87. 发明授权

US4477640A Addition polymerizable aromatic sulfonium salts and polymers thereof 失效
标题翻译：加成可聚合芳族锍盐及其聚合物
公开(公告)号：US4477640A
公开(公告)日：1984-10-16
申请号：US422775
申请日：1982-09-24
申请人： Donald L. Schmidt , Thomas C. Klingler , Ritchie A. Wessling
发明人： Donald L. Schmidt , Thomas C. Klingler , Ritchie A. Wessling
IPC分类号： C08F2/28 , C08F12/32 , C08F228/00 , C08F220/38
CPC分类号： C08F2/28 , C08F12/32
摘要： Novel polymers having high activity as cationic surface-active agents are prepared by the addition polymerization of ethylenically unsaturated aromatic sulfonium salts, e.g., ##STR1## When such polymers are heated and/or dried, they are irreversibly converted to inert, nonionic residues without the elimination of odorous by-products. The novel sulfonium salt polymers having relatively low molecular weight and low charge density are particularly useful as surfactants or emulsifiers in the emulsion polymerization of ethylenically unsaturated monomers such as styrene, butadiene, alkyl acrylates and the like. The polymers having high molecular weight and high charge density are useful as thickeners and flocculants.
摘要翻译：通过烯键式不饱和芳族锍盐的加成聚合制备具有高活性的阳离子表面活性剂的新型聚合物，例如，当加热和/或干燥这些聚合物时，它们不可逆地转化为惰性的非离子残余物，消除恶臭副产品。具有相对低分子量和低电荷密度的新型锍盐聚合物在烯属不饱和单体如苯乙烯，丁二烯，丙烯酸烷基酯等的乳液聚合中特别可用作表面活性剂或乳化剂。具有高分子量和高电荷密度的聚合物可用作增稠剂和絮凝剂。

88. 发明授权

US4426470A Aqueous method of making reinforced composite material from latex, solid polymer and reinforcing material 失效
标题翻译：从胶乳，固体聚合物和增强材料制备增强复合材料的水性方法
公开(公告)号：US4426470A
公开(公告)日：1984-01-17
申请号：US418934
申请日：1982-09-16
申请人： Ritchie A. Wessling , Larry D. Yats , Darryl K. Tolbert
发明人： Ritchie A. Wessling , Larry D. Yats , Darryl K. Tolbert
IPC分类号： C08J3/215 , D21H13/40 , C08K3/40 , B32B17/08 , C08K7/14 , C08L1/00
CPC分类号： D21H13/40 , C08J3/215 , Y10T428/24994
摘要： Reinforced polymer composites having a uniform mix of fiber, polymer and binder and having good physical properties are prepared by forming dilute aqueous slurries of a solid heat fusible organic polymer, a reinforcing material and a bound charge latex binder.
摘要翻译：通过形成固体热熔性有机聚合物，增强材料和结合电荷胶乳粘合剂的稀释水性浆料，制备具有纤维，聚合物和粘合剂的均匀混合物并且具有良好物理性能的增强聚合物复合材料。

89. 发明授权

US4352766A Scrapless forming of plastic articles 失效
标题翻译：塑料制品的无缝成型
公开(公告)号：US4352766A
公开(公告)日：1982-10-05
申请号：US209639
申请日：1980-11-24
申请人： Norbert L. Bradley , Kenneth J. Cleereman , Ritchie A. Wessling
发明人： Norbert L. Bradley , Kenneth J. Cleereman , Ritchie A. Wessling
IPC分类号： B29C43/16 , B29C51/02 , B29C67/20 , B29D9/00
CPC分类号： B29C43/16 , B29C51/02 , B29C67/205 , B29C2791/001 , B29K2023/0683 , B29K2105/251
摘要： A scrap-free, substantially solid phase, relatively low temperature economical process for rapidly making plastic articles from resinous powders wherein the resultant articles can comprise various polymers including oriented polymers; polymers with a high practical heat distortion temperature; expanded polymers; ultra high molecular weight polymers; blended structures of two or more materials; or multilayered structures. The resinous powders are initially compressed into briquettes, which briquettes are heated to a temperature in the range from about the alpha transition temperature to less than the melting point or melt temperature of the polymer therein to both somewhat soften and sinter the briquettes. The sintered briquettes are forged under conditions which permit substantial plug flow deformation into preforms whereby fusion of the sintered resin powder particles occurs. The resulting preforms can then be cooled for later thermoforming or can be directly transferred to thermoforming molds for forming into desired shaped articles. It is also possible to form at least shallow cans, lids or other items directly in the forging step.
摘要翻译：用于从树脂粉末快速制造塑料制品的无废料，基本上固相，相对低温的经济方法，其中所得制品可包含各种聚合物，包括取向聚合物; 具有高实际热变形温度的聚合物; 膨胀聚合物; 超高分子量聚合物; 两种或多种材料的混合结构; 或多层结构。树脂粉末最初被压缩成团块，将该团块加热到从大约α转变温度到低于其中聚合物的熔点或熔融温度范围内的温度，以使两者稍微软化并烧结团块。烧结的团块在允许大量塞子流动变形成预制件的条件下锻造，从而发生烧结树脂粉末颗粒的熔融。然后将所得的预成型件冷却以用于随后的热成型，或者可以直接转移到热成型模具中以形成所需的成型制品。还可以在锻造步骤中直接形成至少浅的罐，盖或其它物品。

90. 发明授权

US4337185A Process for making cationic structured particle latexes using reactive polymeric surfactants 失效
标题翻译：使用反应性聚合物表面活性剂制备阳离子结构化颗粒胶乳的方法
公开(公告)号：US4337185A
公开(公告)日：1982-06-29
申请号：US162289
申请日：1980-06-23
申请人： Ritchie A. Wessling , Dale M. Pickelman, Sr.
发明人： Ritchie A. Wessling , Dale M. Pickelman, Sr.
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/28 , C08F291/00 , C08L41/00
CPC分类号： C08F2/28 , C08F2/24 , C08F291/00
摘要： Structured particle latexes are prepared by emulsion polymerizing monomeric materials in aqueous media in one or more stages wherein in at least one of the stages a reactive polymeric surfactant is used. The resulting latex contains nonionic particles to which are bound the reactive polymeric surfactant which forms a layer containing stabilizing "ionic" groups such as sulfonium groups, quaternary ammonium groups or sulfonate groups chemically bound at or near the surface of the polymer particles, which are dispersed in aqueous media. The cationic latexes are particularly suitable for beater additives and organic pigments.
摘要翻译：通过在一个或多个阶段中将水性介质中的单体材料乳化聚合制备结构化颗粒胶乳，其中在至少一个阶段中使用反应性聚合物表面活性剂。所得胶乳含有非离子颗粒，其结合反应性聚合物表面活性剂，其形成包含稳定“离子”基团的层，例如在聚合物颗粒表面或附近化学键合的锍基，季铵基或磺酸盐基，其分散在水性介质中。阳离子胶乳特别适用于搅拌添加剂和有机颜料。

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