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    • 82. 发明授权
    • Field-assisted fiber spinning for the preparation of optical fibers
having non-linear optical activity
    • 用于制备具有非线性光学活性的光纤的场辅助纤维纺丝
    • US4917455A
    • 1990-04-17
    • US98533
    • 1987-09-18
    • David S. Soane
    • David S. Soane
    • B29D11/00G02B1/04G02F1/383
    • G02B6/02033B29D11/00663G02B1/045G02F1/383
    • A method for the preparation of polymer-based optical fibers with nonlinear optical activity using a field-assisted fiber spinning technique has been developed. A homogeneous mixture of high-glass-transition-temperature polymer and a rigid-rodlike noncentrosymmetric molecule with nonlinear optical activity is employed in a specialized fiber-spinning operation. Equivalently, the noncentrosymmetric moieties can be chemically attached to the polymer backbone. A special spinneret is designed in such a manner as to allow a strong electric or magnetic field to be externally applied in the die (extrudate) swell region prior to fiber draw-down. In the die swell region, the imposed electric or magnetic field imparts a preferential orientation to the rod-like molecules (segments), where the molecular dipoles acquire an anistropic spatial orientational accentuated and trapped in fiber draw-down, where the mixture cools and vitrifies. Hence, the final product is nonlinearly-active polymer optical fibers doped with non-centrosymmetric rod-like molecules (segments) whose molecular axis is aligned with the fiber axis. In addition, the alignment is such that the net dipole moment of the system as a whole is non-zero due to the strong electromagnetic field imposed prior to fiber draw-down. This invention is useful in a wide variety of electro-optic and opto-electronic applications.
    • 已经开发了使用现场辅助纤维纺丝技术制备具有非线性光学活性的聚合物基光纤的方法。 在特殊的纤维纺丝操作中采用高玻璃化转变温度聚合物和具有非线性光学活性的刚性棒状非中心对称分子的均匀混合物。 等效地,非中心对称部分可以化学连接到聚合物主链上。 特殊的喷丝头被设计成允许在光纤拉伸之前在模具(挤出物)溶胀区域外部施加强电场或磁场。 在模具隆起区域中,施加的电场或磁场给杆状分子(段)赋予优先取向,其中分子偶极子获得强烈的空间取向并且被捕获在纤维拉伸中,其中混合物冷却和玻璃化 。 因此,最终产品是掺杂有分子轴与纤维轴对齐的非中心对称棒状分子(链段)的非线性活性聚合物光纤。 此外,对准是由于在光纤拉伸之前施加的强电磁场,整个系统的净偶极矩不为零。 本发明在各种电光和光电应用中是有用的。