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    • 84. 发明授权
    • Modified zinc oxide particles
    • 改性氧化锌颗粒
    • US08747804B2
    • 2014-06-10
    • US13054636
    • 2009-07-14
    • Andrey KarpovHartmut HibstSimon SchambonyRichard RiggsSylke Haremza
    • Andrey KarpovHartmut HibstSimon SchambonyRichard RiggsSylke Haremza
    • C01G9/02
    • C09C1/043C01G9/02C01P2002/84
    • Process for the preparation of modified ZnO particles in which a zinc salt and a base are mixed in a polar solvent and, if appropriate after the precipitation of a precipitation product, the polar solvent is removed and a residue is obtained, where the residue is taken up in a nonpolar solvent, surface-active substances are added, optionally further effect substances are added and then the modified ZnO particles are separated off from further by-products. Materials such as plastics, coatings or paints comprising modified ZnO particles. Methods for the incorporation of modified ZnO particles into materials, where the modified ZnO particles are incorporated into the materials in the form of dispersions or suspensions. Use of modified ZnO particles for protecting material against the effect of light, heat, oxygen or free radicals, as catalysts, for semiconductive films or cosmetic applications.
    • 制备其中将锌盐和碱在极性溶剂中混合的改性ZnO颗粒的制备方法,并且如果适当,在析出产物沉淀后,除去极性溶剂,得到残留物,其中残留物被 在非极性溶剂中加入表面活性物质,任选地添加另外的效果物质,然后将改性的ZnO颗粒与进一步的副产物分离。 诸如塑料,涂料或包含改性ZnO颗粒的涂料的材料。 将改性的ZnO颗粒引入到材料中的方法,其中将改性的ZnO颗粒以分散体或悬浮液的形式引入材料中。 使用改性ZnO颗粒来保护材料免受光,热,氧或自由基作为半导体膜或化妆品应用的催化剂的影响。
    • 88. 发明申请
    • SYNTHESIS OF LITHIUM-METAL-PHOSPHATES UNDER HYDROTHERMAL CONDITIONS
    • 在氢热条件下合成硫酸金属磷酸盐
    • US20110272639A1
    • 2011-11-10
    • US13142606
    • 2009-12-22
    • Kirill BramnikHartmut HibstJordan Keith LampertSimon Schroedle
    • Kirill BramnikHartmut HibstJordan Keith LampertSimon Schroedle
    • H01M4/58H01B1/12H01B1/18H01M4/04H01B1/14
    • C01B25/45H01M4/5825H01M4/625H01M10/0525
    • The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1bQ1-cM2cPd-eM3eOx (l), wherein Q has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: Q: Fe, Mn, Co, Ni, M1: Na, K, Rb and/or Cs, M2: Mg, Al, Ca, Ti, Co, Ni, Cr, V, Fe, Mn, wherein Q and M2 are different from each other, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.0-8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one Q-comprising compound, in which Q has at least partially an oxidation state higher than +2, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500° C. and at an autogeneous pressure to reduce Q to oxidation state +2 and to obtain a compound of general formula (I).
    • 本发明涉及制备通式(I)Lia-bM1bQ1-cM2cPd-eM3eOx(1)的化合物的方法,其中Q具有氧化态+2和M1,M2,M3,a,b,c, d,e和x为:Q:Fe,Mn,Co,Ni,M1:Na,K,Rb和/或Cs,M2:Mg,Al,Ca,Ti,Co,Ni,Cr,V,Fe,Mn 其中Q和M2彼此不同,M3:Si,S,F a:0.8-1.9,b:0-0.3,c:0-0.9,d:0.8-1.9,e:0-0.5,x: 取决于Li,M1,M2,P,M3的量和氧化态,其中通式(I)的化合物是中性带电的,包括以下步骤(A),提供包含至少一种锂 - 包含化合物,至少一种含Q的化合物,其中Q至少部分具有高于+2的氧化态,以及至少一种含M1化合物(如果存在)和/或至少一种含M2化合物,如果 存在和/或至少一种含M3化合物(如果存在)和至少一种被氧化成至少一种化合物c的还原剂 处于氧化态+5以上的至少一个磷原子,(B)在100〜500℃的温度和自动压力下加热步骤(A)中得到的混合物,将Q降低至氧化态+2,将 得到通式(I)的化合物。