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81. 发明授权

US5525689A Process for preparing ethylene copolymers 失效
标题翻译：制备乙烯共聚物的方法
公开(公告)号：US5525689A
公开(公告)日：1996-06-11
申请号：US458696
申请日：1995-06-02
申请人： Toshiyuki Tsutsui , Ken Yoshitsugu , Akinori Toyota
发明人： Toshiyuki Tsutsui , Ken Yoshitsugu , Akinori Toyota
IPC分类号： C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F210/08 , C08F210/16 , C08F4/643 , C08F210/14
CPC分类号： C08F210/16 , C08F10/00 , C08F10/06 , C08F210/08 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/916 , Y10S526/943
摘要： In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3.about.20 carbon atoms, said ethylene copolymers having[A] density of 0.85.about.0.92 g/cm.sup.3,[B] an intrinsic viscosity [.eta.] as measured in decalin at 135.degree. C. of 0.1.about.10 dl/g,[C] a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2.about.4, and[D] a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8.about.50, and being narrow in molecular weight distribution and excellent in flowability.
摘要翻译：根据本发明，提供由乙烯衍生的结构单元（a）和衍生自碳原子数3〜20的α-烯烃的结构单元（b）组成的乙烯共聚物，所述乙烯共聚物的[A]密度为0.85 差异0.92g / cm 3，[B]在135℃的十氢化萘中测得的特性粘度η为0.1Dd / g，[C]重均分子量的比率（＆lt;上升＆Mw /＆lt;上升＆（＆Upbar＆Mw）与通过1.2DIFFERENCE 4的GPC测定的数均分子量（＆Upbar＆Mn）和[D]在10kg负荷下MFR10的MFR10与MFR2在2.16kg负荷下的比（MFR 10 / MFR 2）在190℃，差异为50，分子量分布窄，流动性好。

82. 发明授权

US5519091A Method for the preparation of ethylene polymer compositions 失效
标题翻译：乙烯聚合物组合物的制备方法
公开(公告)号：US5519091A
公开(公告)日：1996-05-21
申请号：US455109
申请日：1995-05-31
申请人： Toshiyuki Tsutsui , Takashi Ueda
发明人： Toshiyuki Tsutsui , Takashi Ueda
IPC分类号： C08F10/02 , C08F297/08 , C08L23/08 , C08L23/20
CPC分类号： C08F297/08 , C08F10/02 , C08F210/16
摘要： In accordance with the present invention, there is provided a method for the preparation of an ethylene polymer composition having a density of 0.86-0.94 g/cm.sup.3 and an intrinsic viscosity [.eta.] of 1-6 dl/g using an olefin polymerization catalyst composed of a transition metal compound containing a ligand having a cycloalkadienyl skeleton and an organoaluminium oxy-compound, and there is also provided a method for the preparation of an ethylene polymer composition having density of 0.87-0.93 g/cm3 and an intrinsic viscosity [.eta.] of 0.5-6 dl/g.
摘要翻译：根据本发明，提供一种制备乙烯聚合物组合物的方法，该组合物的密度为0.86-0.94g / cm3，特性粘度η为1-6dl / g，使用的烯烃聚合催化剂组成的含有具有环二烯基骨架的配体和有机铝氧化合物的过渡金属化合物，还提供了一种制备密度为0.87-0.93g / cm3和特性粘度η的乙烯聚合物组合物的方法，为0.5-6 dl / g。

83. 发明授权

US5464905A Ethylene/.alpha.-olefin copolymer composition, graft modified ethylene/.alpha.-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process 失效
标题翻译：乙烯/α-烯烃共聚物组合物，接枝改性乙烯/α-烯烃共聚物组合物，乙烯共聚物组合物和多阶段烯烃聚合方法
公开(公告)号：US5464905A
公开(公告)日：1995-11-07
申请号：US154467
申请日：1993-11-18
申请人： Toshiyuki Tsutsui , Ken Yoshitsugu , Mamoru Takahashi , Akira Todo , Seiji Ohta , Hajime Inagaki
发明人： Toshiyuki Tsutsui , Ken Yoshitsugu , Mamoru Takahashi , Akira Todo , Seiji Ohta , Hajime Inagaki
IPC分类号： C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F255/02 , C08F255/04 , C08F255/08 , C08F287/00 , C08F297/08 , C08L23/04 , C08L23/08 , C08L51/06 , C08L23/16 , C08L23/18
CPC分类号： C08F10/00 , C08F210/16 , C08F255/02 , C08F255/04 , C08F255/08 , C08F287/00 , C08F297/08 , C08L23/04 , C08L23/0815 , C08L51/06 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08L2205/02 , C08L2314/04 , C08L2314/06
摘要： An ethylene/.alpha.-olefin copolymer composition containing a first and second ethylene/.alpha.-olefin copolymer is disclosed. The first ethylene/.alpha.-olefin copolymer is prepared in the prsence of a polymerization catalyst containing an organoaluminum oxy compound and at least two kinds of metallocene compounds (b) and the second ethylene/.alpha.-olefin copolymer, which differs from the first in at least one physical property, is prepared in the presence of a polymerization catalyst containing an organoaluminum oxy compound and a metallocene compound (b'). The ethylene/.alpha.-olefin copolymer composition has excellent moldability and heat stability properties and forms films having high transparency and mechanical strength.
摘要翻译：公开了含有第一和第二乙烯/α-烯烃共聚物的乙烯/α-烯烃共聚物组合物。第一种乙烯/α-烯烃共聚物是在含有有机铝氧化合物和至少两种茂金属化合物（b）和第二种乙烯/α-烯烃共聚物的聚合催化剂的前提下制备的，其与第一种乙烯/ 在含有有机铝氧化合物和茂金属化合物（b'）的聚合催化剂的存在下制备至少一种物理性质。乙烯/α-烯烃共聚物组合物具有优异的成型性和热稳定性，并形成具有高透明度和机械强度的薄膜。

84. 发明授权

US5340786A Olefin polymerization catalyst and process for the polymerization of olefins 失效
标题翻译：烯烃聚合催化剂和烯烃聚合方法
公开(公告)号：US5340786A
公开(公告)日：1994-08-23
申请号：US151765
申请日：1993-11-15
申请人： Toshiyuki Tsutsui , Kazunori Okawa , Akinori Toyota
发明人： Toshiyuki Tsutsui , Kazunori Okawa , Akinori Toyota
IPC分类号： C08F4/659 , C08F4/6592 , C08F10/00 , C08F4/648
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： In accordance with the present invention, there are provided an olefin polymerization catalyst formed from:[A] a compound of a transition metal belonging to Group IV B of the periodic table,[B] an aluminoxane, and[C] water,an olefin polymerization catalyst formed from [D] an organoaluminum compound in addition to the above-mentioned [A], [B] and [D] components, and processes for the polymerization of olefins using the above-mentioned olefin polymerization catalysts, respectively.
摘要翻译：根据本发明，提供了由以下物质形成的烯烃聚合催化剂：[A]属于周期表第IVB族的过渡金属的化合物，[B]铝氧烷和[C]水，烯烃除了上述[A]，[B]和[D]成分之外，由[D]有机铝化合物形成的聚合催化剂以及使用上述烯烃聚合催化剂聚合烯烃的方法。

85. 发明授权

US5336746A Propylene random copolymers and processes for preparing same 失效
标题翻译：丙烯无规共聚物及其制备方法
公开(公告)号：US5336746A
公开(公告)日：1994-08-09
申请号：US901972
申请日：1992-06-22
申请人： Toshiyuki Tsutsui , Akinori Toyota
发明人： Toshiyuki Tsutsui , Akinori Toyota
IPC分类号： C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F210/08 , C08F210/16
CPC分类号： C08F210/16 , C08F10/00 , C08F10/06 , C08F210/08 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/916 , Y10S526/943
摘要： A random copolymer of propylene with from 1 to 10 mol % of a C.sub.4 to C.sub.20 .alpha.-olefin and an intrinsic viscosity of 0.5 to 6 dl/g is also characterized by a melting point (Tm) measured by a differential scanning calorimeter falling within the range of 90
摘要翻译：丙烯与1至10mol％的C 4至C 20α-烯烃的无规共聚物和特性粘度为0.5至6dl / g的特征还在于通过差示扫描量热计测量的熔点（Tm）范围为90

86. 发明授权

US5308816A Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization 失效
标题翻译：烯烃聚合固体催化剂，烯烃聚合催化剂和烯烃聚合
公开(公告)号：US5308816A
公开(公告)日：1994-05-03
申请号：US890271
申请日：1992-05-29
申请人： Toshiyuki Tsutsui , Ken Yoshitsugu , Kunio Yamamoto
发明人： Toshiyuki Tsutsui , Ken Yoshitsugu , Kunio Yamamoto
IPC分类号： C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/904 , Y10S526/941 , Y10S526/943
摘要： The present invention relates to a solid catalyst composed of a specific solid catalyst component [A-1], the catalyst containing the solid catalyst and the olefin polymerization process using the solid catalyst, in which the solid catalyst component [A-1] comprises; (a-1) a particulate carrier composed of a specific oxide of a metal; (a-2) an organoaluminum oxy compound; and (a-3) a specific transition metal compound containing a specific ligand, wherein the organoaluminum oxy compound (a-2) and the transition metal compound (a-3) are supported on the particulate carrier (a-1).The catalysts are applicable to a suspension polymerization and a vapor phase polymerization, and capable of preparing spherical olefin polymers excellent in particle characteristics at high polymerization activity.
摘要翻译：本发明涉及一种固体催化剂组分[A-1]，含有固体催化剂的催化剂和使用固体催化剂的烯烃聚合方法，其中固体催化剂组分[A-1]包括的固体催化剂组分[A-1] （a-1）由金属的特定氧化物构成的颗粒状载体; （a-2）有机铝氧化合物; 和（a-3）含有特定配体的特定过渡金属化合物，其中有机铝氧化合物（a-2）和过渡金属化合物（a-3）负载在颗粒载体（a-1）上。该催化剂适用于悬浮聚合和气相聚合，并且能够制备在高聚合活性下颗粒特性优异的球形烯烃聚合物。

87. 发明授权

US5120696A Olefin polymerization catalyst and process for the polymerization of olefins 失效
公开(公告)号：US5120696A
公开(公告)日：1992-06-09
申请号：US634696
申请日：1990-12-27
申请人： Toshiyuki Tsutsui , Takashi Ueda
发明人： Toshiyuki Tsutsui , Takashi Ueda
IPC分类号： C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/654 , C08F10/00
CPC分类号： C08F10/00 , C08F4/63904 , C08F4/63916 , C08F4/63922 , Y10S526/943
摘要： In accordance with the present invention, there are provided olefin polymerization solid catalysts comprising[A] a solid titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients, said catalyst component having supported thereon[B] a transition metal compound containing a ligand having a cycloalkadienyl skeleton and, if necessary,[C] an organoaluminum oxy-compound.In accordance with the invention, there are also provided olefin polymerization solid catalysts comprising[i] a solid containing a transition metal compound containing a ligand having a cycloalkadienyl skeleton, said solid having supported thereon[ii] a titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients and, if necessary,[iii] an organoaluminum oxy-compound.

88. 发明申请

US20100324239A1 SOLID TITANIUM CATALYST COMPONENT, OLEFIN POLYMERIZATION CATALYST, AND PROCESS FOR PRODUCING OLEFIN POLYMER 有权
标题翻译：固体钛催化剂组分，烯烃聚合催化剂和生产烯烃聚合物的方法
公开(公告)号：US20100324239A1
公开(公告)日：2010-12-23
申请号：US12851901
申请日：2010-08-06
申请人： Tetsuhiro Matsumoto , Toshiyuki Tsutsui , Kisu Ro , Kourei Kuroiwa , Takushi Nagata , Atsushi Shibahara , Tatsuya Nakamura , Tetsunori Shinozaki
发明人： Tetsuhiro Matsumoto , Toshiyuki Tsutsui , Kisu Ro , Kourei Kuroiwa , Takushi Nagata , Atsushi Shibahara , Tatsuya Nakamura , Tetsunori Shinozaki
IPC分类号： C08F4/50 , B01J31/26
CPC分类号： C08F10/00 , C08F210/14 , C08F2500/26 , C08J5/18 , C08J2323/20 , C08F4/651 , C08F2500/15
摘要： The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher α-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.
摘要翻译：本发明提供了一种制备α-烯烃聚合物的方法，其包括在包含含有钛，镁，镁的固体钛催化剂组分（I）的烯烃聚合催化剂的存在下聚合或共聚（a）C3或更高级的α-烯烃，卤素和具有两个或更多个醚键的特定结构的化合物和具有高催化活性的有机金属催化剂组分（II）。在该方法中，特别是即使在（共）聚合（a）较高级烯烃中，也不需要脱矿质。使用本发明的催化剂进行聚合得到的4-甲基-1-戊烯类聚合物的立构规整度，透明性，耐热性，脱模性优异，特别适用于脱模膜。

89. 发明授权

US07687579B2 Ethylene (co) polymer and its use 有权
标题翻译：乙烯（共）聚合物及其用途
公开(公告)号：US07687579B2
公开(公告)日：2010-03-30
申请号：US11211477
申请日：2005-08-26
申请人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
发明人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
IPC分类号： C08F23/04 , C08F23/08
CPC分类号： C08F255/02 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08F4/64048 , C08L2666/04 , C08F2500/10 , C08F2500/17 , C08F2500/12 , C08F2500/03 , C08F2500/07 , C08F2500/11 , C08F2500/14 , C08F210/14 , C08F210/08
摘要： An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9−7.15×SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η]>1.85×MFR−0.192 in the case of MFR 1.85×MFR−0.213 in the case of MFR≧1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.
摘要翻译：本发明的乙烯（共）聚合物是具有优异的成型性和机械性能的（共）聚合物，乙烯均聚物或乙烯与4-20个碳原子的α-烯烃的共聚物。（共）聚合物具有通过13 C-NMR测量的甲基支链，每1000个碳原子数小于0.1，GPC测得的Mw / Mn不低于1.8，低于4.5。（共）聚合物是乙烯均聚物或乙烯与3-20个碳原子的α-烯烃的共聚物。熔体张力（MT）和溶胀比（SR）满足关系; log（MT）> 12.9-7.15×SR; 并且特性粘度（[＆eggr]）和熔体流动速率（MFR）满足关系; 在MFR <1的情况下为1.85×MFR-0.192，关系为在MFR≥1的情况下为1.85×MFR-0.213。这种乙烯（共）聚合物可用于各种模塑应用，特别适用于管道。

90. 发明授权

US07669761B2 Sales shop system 有权
标题翻译：销售店系统
公开(公告)号：US07669761B2
公开(公告)日：2010-03-02
申请号：US11259260
申请日：2005-10-27
申请人： Toshiyuki Tsutsui , Masataka Itakura , Tomohiro Hamada , Akihito Itou , Kazuma Kurata
发明人： Toshiyuki Tsutsui , Masataka Itakura , Tomohiro Hamada , Akihito Itou , Kazuma Kurata
IPC分类号： G06K15/00
CPC分类号： G06Q20/40 , G06Q20/4014 , G06Q20/40145 , G06Q30/02
摘要： Conventionally, to acquire specific information of a customer, acquisition of the information is only possible by using information such as a bank account number owned by the customer, and further it is not possible to present information beneficial to the customer unless information owned by the customer is acquired from the customer. More specifically, there is a problem in that much time is necessary for a customer or a system operator to input such information.To solve the above-stated problem, the present invention outputs information associated with a customer by using biometric information including a face image. More specifically, biometric information is acquired from a user of a first terminal unit included in a plurality of terminal units, and information associated with an operation made by the user is identified. Then, when the user is going to use a second terminal unit (or when the second terminal unit executes processing of information on the user based on inputs by a third party, etc.), biometric information is acquired from the user, and information that is identified by an operation made on the first terminal unit is retrieved for output by using the biometric information.
摘要翻译：通常，为了获取客户的具体信息，只能通过使用客户拥有的银行帐号等信息来获取信息，而且除了客户所拥有的信息之外，还不可能提供有益于客户的信息是从客户那里获得的。更具体地说，存在客户或系统操作员输入这样的信息需要很多时间的问题。为了解决上述问题，本发明通过使用包括脸部图像的生物信息来输出与顾客相关联的信息。更具体地，从包括在多个终端单元中的第一终端单元的用户获取生物特征信息，并且识别与由用户进行的操作相关联的信息。然后，当用户要使用第二终端单元（或者当第二终端单元基于第三方的输入来执行对用户的信息的处理等）时，从用户获取生物特征信息，以及信息通过在第一终端单元上进行的操作来识别，通过使用生物特征信息被检索以输出。

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