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    • 81. 发明授权
    • Sn based alloys with fine compound inclusions for Nb3Sn superconducting wires
    • 用于Nb3Sn超导线材的具有精细复合夹杂物的Sn基合金
    • US08765053B2
    • 2014-07-01
    • US12656347
    • 2010-01-27
    • Florin Buta
    • Florin Buta
    • C22C13/00C22C1/00
    • C22C1/00C22C13/00Y10S420/901Y10T428/12014
    • A method for producing a Sn based alloy (15) comprising a metal matrix of a metal matrix material, wherein the metal matrix material comprises Sn, and inclusions of a compound material, further referred to as compound inclusions, wherein the compound material contains one element or a combination of elements of the group Ti, V, Zr, Hf, further referred to as dopant, and one or a plurality of other elements, in particular Sn, Cu and/or Nb. Particles of the metal matrix material, further referred to as matrix particles, are mixed with particles of the compound material, further referred to as compound particles, and the matrix particles and the compound particles are compacted during and/or after their mixing. A Sn based alloy containing finer compound inclusion of a dopant can be prepared, in order to produce Nb3Sn superconductor material with a superior current carrying capacity.
    • 1.一种用于制造包含金属基体材料的金属基体的Sn基合金(15)的方法,其中所述金属基体材料包括Sn,以及化合物材料的夹杂物,进一步称为化合物夹杂物,其中所述复合材料包含一种元素 或组合Ti,V,Zr,Hf的元素,进一步称为掺杂剂,以及一种或多种其它元素,特别是Sn,Cu和/或Nb。 金属基质材料的颗粒,进一步称为基质颗粒,与化合物材料的颗粒混合,进一步称为化合物颗粒,并且基体颗粒和化合物颗粒在其混合期间和/或之后被压实。 可以制备含有掺杂剂的更精细化合物的Sn基合金,以便制备具有优良载流能力的Nb 3 Sn超导体材料。
    • 85. 发明授权
    • Sample frame for preparation of a plurality of sample vessels, in particular NMR sample tubes
    • 用于制备多个样品容器的样品框架,特别是NMR样品管
    • US08312781B2
    • 2012-11-20
    • US12379210
    • 2009-02-17
    • Kurt HimmelsbachBeat Grossniklaus
    • Kurt HimmelsbachBeat Grossniklaus
    • B01L9/06
    • G01N35/04B01L3/50825B01L3/50853B01L9/06B01L2200/0689B01L2200/141B01L2200/142B01L2300/049B01L2300/0832G01N35/0099G01N35/028G01N2035/0405G01R33/30
    • A sample frame (30; 81) for preparing a plurality of sample vessels (41, 42), in particular sample tubes, having a plurality of retainers, in each of which a sample vessel (41, 42) is situated, is characterized in that the sample vessels (41, 42) each have a cap (43, 44), which is put over the open end of the sample vessel (41, 42), the cap (41, 42) having a drilled hole (53, 54), through which the interior of the sample vessel (41, 42) is accessible, the sample frame (30; 81) has a removable cover plate (8), whose bottom side faces toward the caps (43, 44) of the sample vessels (41, 42) in the put-on state of the cover plate (8), and the cover plate (8) has an approximately funnel-shaped depression (11, 71) on the top side for each retainer, in whose center a through opening (57) through the cover plate (8) is provided, the through opening (57) aligning with the drilled hole (53, 54) of a cap (43, 44) of a sample vessel (41, 42) retained underneath when the cover plate (8) is put on. The sample frame according to the invention eases the closure of sample vessels, which have a cap with hole, in the context of an automated sample preparation.
    • 其特征在于,用于制备多个样品容器(41,42)的样品架(41,42),特别是具有多个保持器的样品管(41,42),其中每个样品容器(41,42) 样品容器(41,42)各自具有盖(43,44),其盖在样品容器(41,42)的开口端上,所述盖(41,42)具有钻孔(53,44) 54),样品容器(41,42)的内部可通过其进行,样品框架(30; 81)具有可移除的盖板(8),其底侧朝向所述盖板(43,44) 在盖板(8)的放置状态下的样品容器(41,42)和盖板(8)在每个保持器的顶侧上具有大致漏斗状的凹部(11,71),其中 设置有穿过盖板(8)的通孔(57)的中心,通孔(57)与样品容器(41,42)的盖(43,44)的钻孔对齐, 当盖板(8)被放置时保留在下面。 根据本发明的样品框架在自动化样品制备的情况下简化了带有孔的样品容器的封闭。
    • 88. 发明申请
    • Device for highly precise synchronization of the NMR transmission frequency to the resonance frequency of an NMR line while taking into consideration a non-constant RF phase
    • 用于在考虑非恒定RF相位时将NMR传输频率与NMR谱线的谐振频率进行高精度同步的装置
    • US20100271025A1
    • 2010-10-28
    • US12662388
    • 2010-04-14
    • Arthur SchwilchMichael Schenkel
    • Arthur SchwilchMichael Schenkel
    • G01R33/48
    • G01R33/31G01R33/36G01R33/3607G01R33/389
    • A device that comprises an RF generator (29), an NMR transmission (20) and reception system (21) and a first control loop (28), with which the frequency fRF of the RF generator is synchronized with the resonance frequency f0 of an NMR line, wherein, from the signal of the RF generator, a train of excitation pulses (EX) of the repetition frequency fm is generated, with which nuclear spins of a certain resonance frequency of an associated NMR line are excited quasi-continuously (CW) and, in the times between the excitation pulses, the NMR signal is received (AQ), wherein the period time 1/fm is chosen to be much smaller than the relaxation time of the NMR line, preferably shorter than 1/10 of the relaxation time, and the NMR signal UD mixed down into the low-frequency range is used, with the help of the first control loop, to closed-loop-control the value of the transmission frequency (=frequency lock) or the value of the B0 field (=field lock) in such a way that the frequency and phase of the RF generator and the NMR line match as precisely as possible, characterized in that a phase shifter (22) that rotates the radio-frequency phase of the NMR transmission and reception system in the first control loop by the value Δφ is controlled by a second control loop (27) whose input signal comes from a signal extraction stage (25, 26) that extracts the saw-tooth AC component of the signal UD and maintains this input signal at zero by closed-loop control. In this way, the influence of the RF phase on the synchronization process can be taken into consideration to improve the precision with which the resonance frequency of an NMR line is synchronized.
    • 一种包括RF发生器(29),NMR传输(20)和接收系统(21)以及第一控制环路(28)的装置,RF发生器的频率fRF与RF发生器的谐振频率f0同步 NMR线,其中,根据RF发生器的信号,产生一系列重复频率f m的激励脉冲(EX),与之相关联的NMR线的某个共振频率的核自旋被准星激励(CW ),并且在激发脉冲之间的时间内接收NMR信号(AQ),其中周期时间1 / fm被选择为远小于NMR线的弛豫时间,优选短于NMR线的1/10 松弛时间和混合到低频范围内的NMR信号UD,在第一个控制环路的帮助下,使用闭环控制传输频率(=频率锁定)的值或 B0字段(=字段锁)以这样的方式使频率和相位 射频发生器和NMR线路尽可能精确地匹配,其特征在于:使所述第一控制回路中的所述NMR发射和接收系统的射频相位旋转的移相器(22)的值&Dgr; 由第二控制回路(27)控制,其输入信号来自提取信号UD的锯齿AC分量的信号提取级(25,26),并通过闭环控制将该输入信号保持在零。 以这种方式,可以考虑RF相对同步过程的影响,以提高NMR线的共振频率同步的精度。
    • 90. 发明授权
    • Sample holder for holding and transporting a sample vial within an NMR apparatus and automatic supply device for the automated exchange of NMR sample vials and method of operation thereof
    • 用于在NMR装置内保持和运送样品瓶的样品架和用于NMR样品瓶的自动交换的自动供给装置及其操作方法
    • US07718135B2
    • 2010-05-18
    • US11700944
    • 2007-02-01
    • Kurt HimmelsbachFranco Sestito
    • Kurt HimmelsbachFranco Sestito
    • B01L9/00
    • G01R33/307Y10S505/844Y10T436/24
    • A sample holder for fixing and transporting a sample vial (1) within an NMR configuration comprising an outer shell (4) and a continuous hollow space disposed inside the outer shell (4) and extending along its axis for receiving the sample vial, is characterized in that a clamping device that can be switched on and off and a switching element (6) are provided inside the hollow space, wherein, in the activated state, the clamping device fixes a sample vial (1) that is introduced into the sample holder, the switching element (6) can be operated from the outside, and the clamping device can be deactivated using the switching element (6) such that, in the deactivated state, the sample vial (1) inserted into- or removed from the sample holder is not fixed. Such a sample holder may be used to realize an automatic supply device for changing NMR sample vials which has a very compact structure and can be mounted using little space.
    • 用于在包括外壳(4)和布置在外壳(4)内部并沿着其轴线延伸以接收样品瓶的连续中空空间的NMR构型内固定和运送样品瓶(1)的样品保持器被表征 其特征在于,可以在所述中空空间内设置能够接通和断开的夹紧装置和开关元件(6),其中,在所述启动状态下,所述夹紧装置固定导入到所述样品架中的样品瓶(1) ,可以从外部操作开关元件(6),并且可以使用开关元件(6)使夹紧装置停用,使得在停用状态下,样品瓶(1)插入或从样品中移出 持有人不固定 这种样品保持器可以用于实现用于改变NMR样品瓶的自动供应装置,其具有非常紧凑的结构并且可以使用很小的空间来安装。