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71. 发明授权

US4083829A Melt processable thermotropic wholly aromatic polyester 失效
标题翻译：熔融加工热性全芳族聚酯
公开(公告)号：US4083829A
公开(公告)日：1978-04-11
申请号：US789374
申请日：1977-04-20
申请人： Gordon W. Calundann , Herbert L. Davis , Frederick J. Gorman , Robert M. Mininni
发明人： Gordon W. Calundann , Herbert L. Davis , Frederick J. Gorman , Robert M. Mininni
IPC分类号： C08G63/60 , D01F6/84 , C08G63/06 , C08G63/18
CPC分类号： D01F6/84 , C08G63/60
摘要： A wholly aromatic polyester is provided which has been found to be highly amenable to melt extrusion to yield high performance fibers. Such fibers following thermal treatment exhibit high tenacity and tensile modulus properties which are well retained at elevated temperatures while exhibiting a low degree of shrinkage. Unlike wholly aromatic polyesters normally encountered in the prior art, the polymer of the present invention is not intractable and may be melt extruded with ease at temperatures below approximately 300.degree. C., and preferably below approximately 280.degree. C. The aromatic polyester of the present invention consists essentially of recurring units (a) p-oxybenzoyl moiety, (b) 2,6-dicarboxynaphthalene moiety, (c) symmetrical dioxy aryl moiety (as defined), and (d) isophthaloyl moiety and/or metal-dioxy phenylene moiety, and is free of units which possess ring substitution. The wholly aromatic polyester of the present invention forms an atypical thermotropic melt phase which is exhibited in the absence of ring substitution at a relatively low temperature which facilitates fiber formation with ease. The wholly aromatic polyester of the present invention following melt spinning and thermal treatment commonly can exhibit an average single filament tenacity of at least 15 grams per denier, and an average single filament tensile modulus of at least 300 grams per denier.
摘要翻译：提供了一种全芳族聚酯，已被发现是高度易于熔融挤出以产生高性能纤维。热处理后的这种纤维表现出高强度和拉伸模量性能，它们在升高的温度下良好地保持，同时表现出低的收缩率。与现有技术中通常遇到的全芳族聚酯不同，本发明的聚合物不难处理，并且可以在低于约300℃，优选低于约280℃的温度下容易地熔融挤出。本发明的芳族聚酯本发明基本上由重复单元（a）对羟基苯甲酰部分，（b）2,6-二羧基萘部分，（c）对称的二氧基芳基部分（如所定义））和（d）间苯二酰部分和/或金属二氧基亚苯基部分并且没有具有环取代的单元。本发明的全芳族聚酯形成非典型的热致熔融相，其在相对较低的温度下在不存在环取代的情况下表现出来，这便于轻松形成纤维。熔融纺丝和热处理后本发明的全芳族聚酯通常可显示至少15克/旦尼尔的平均单丝强度，平均单丝拉伸模量至少为300克/旦尼尔。

72. 发明授权

US4035542A Flame retardant fiber blend containing fibers which if present apart from the admixture undergo burning 失效
标题翻译：含有纤维的阻燃纤维混合物（如果存在于混合物之外）经历燃烧
公开(公告)号：US4035542A
公开(公告)日：1977-07-12
申请号：US470420
申请日：1974-05-16
申请人： Arnold J. Rosenthal , Alex S. Forschirm , Bruce P. Barnes
发明人： Arnold J. Rosenthal , Alex S. Forschirm , Bruce P. Barnes
IPC分类号： D06M15/248 , D01F1/07 , D01F6/62 , D01F6/84 , D02G3/04 , D02G3/44 , D04H1/42 , D06M15/252 , D06M15/673 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/10 , D06M101/16 , D06M101/18 , D06M101/30 , D06M101/32 , D06M101/34 , D06M101/36 , D03D25/00
CPC分类号： D06M15/673 , D01F1/07 , D01F6/84 , D02G3/443 , D04H1/425 , D04H1/4266 , D04H1/4291 , D04H1/4334 , D04H1/435 , D04H1/4382 , Y10S260/24 , Y10T442/3171 , Y10T442/3984 , Y10T442/444
摘要： An assemblage of fibers is provided which exhibits highly satisfactory flame retardant characteristics in spite of the fact that discrete fibers are included within the admixture which would normally burn when exposed to flame. Included in intimate physical admixture with the fibers which would normally undergo combustion are discrete additive fibers consisting primarily of a chlorinated and/or brominated aromatic polymer having the inherent ability to render the admixture as a whole non-burning when subjected to the flame. Particularly preferred additive fibers are formed primarily of an aromatic polyester formed from the reaction of tetrabromobisphenol A, isophthalic acid, and terephthalic acid or the esterforming derivatives thereof. Also, in a particularly preferred embodiment a minor concentration of an oxide of antimony (e.g. antimony trioxide or antimony pentoxide) is intimately dispersed throughout the additive fibers. Flame retardant fiber blends readily may be formed without a diminution of the textile properties thereof, e.g. hand and aesthetic appeal.
摘要翻译：提供了一种纤维组合物，尽管分散的纤维包含在通常在暴露于火焰中时燃烧的混合物中，但是其具有非常令人满意的阻燃特性。包括在与通常经历燃烧的纤维的亲密物理混合物中的是离散的添加剂纤维，其主要由氯化和/或溴化芳族聚合物组成，其具有当混合物在经受火焰时作为整体不燃烧的固有能力。特别优选的添加剂纤维主要由四溴双酚A，间苯二甲酸和对苯二甲酸或其成酯衍生物的反应形成的芳族聚酯形成。此外，在特别优选的实施方案中，锑（例如三氧化锑或五氧化二锑）的氧化物的微量浓度紧密地分散在整个添加剂纤维中。可以形成阻燃性纤维共混物，而不会降低其纺织品性能，例如，手感和审美魅力。

73. 发明授权

US4032993A Bioresorbable surgical articles 失效
标题翻译：生物可吸收外科用品
公开(公告)号：US4032993A
公开(公告)日：1977-07-05
申请号：US590284
申请日：1975-06-25
申请人： Jean Coquard , Pierre Sedivy , Michel Ruaud , Jean Verrier
发明人： Jean Coquard , Pierre Sedivy , Michel Ruaud , Jean Verrier
IPC分类号： A61L17/00 , A61L17/10 , A61L17/12 , A61L27/18 , A61L27/58 , C08G63/12 , D01F6/84 , A61F1/24 , A61F1/00
CPC分类号： A61L27/58 , A61L17/105 , A61L17/12 , A61L27/18
摘要： Implantable surgical articles are provided which are at least partially bioresorbable and which consist at least partially of a copolyester of succinic acid and oxalic acid possessing receiving units of the general formulae: ##STR1## in which each R radical in the chain, which may be identical or different, represents a linear or branched alkylene radical possessing 2 to 6 carbon atoms, at least 2 of which carbon atoms form part of the polymer chain, a cyclo-alkylene radical possessing 5 to 8 carbon atoms, or a radical of the general formula: ##STR2## in which each of R.sub.1 and R.sub.2, which may be identical or different, represents a methylene or ethylene radical. They are particularly suitable as sutures.
摘要翻译：提供了至少部分可生物再吸收并且至少部分由琥珀酸和草酸的共聚酯组成的可植入手术制品，其具有以下通式的接收单元：其中每个可以相同或不同的链中的R基团表示具有2-6个碳原子的直链或支链亚烷基，其中至少2个碳原子形成聚合物链的一部分，环 - 亚烷基具有5至8个碳原子或以下通式的基团：其中R 1和R 2各自可以相同或不同，表示亚甲基或亚乙基。它们特别适合作为缝线。

74. 发明授权

US4007247A Production of fibrils 失效
标题翻译：原纤维的生产
公开(公告)号：US4007247A
公开(公告)日：1977-02-08
申请号：US399273
申请日：1973-09-20
申请人： Denis George Harold Ballard , Robert Thomas Murray , George Michael Fingland Jeffs
发明人： Denis George Harold Ballard , Robert Thomas Murray , George Michael Fingland Jeffs
IPC分类号： D01F6/92 , D01D5/04 , D01D5/11 , D01D5/26 , D01D5/40 , D01F6/04 , D01F6/60 , D01F6/62 , D01F6/84 , D21H13/10
CPC分类号： D01D5/11 , D01D1/02 , D01D5/04 , D01F6/04
摘要： Fibrils of thermoplastic polymer, particularly crystalline thermoplastic polymers such as polyethylene and polypropylene, are prepared by forcing a dispersion of heat softened polymer particles in a liquid medium through a pair of opposed co-axial orifices. The liquid medium is preferably aqueous and is pressurized to prevent boiling. The resulting fibrils have some degree of molecular orientation, and may be useful in the production of reinforced paper.
摘要翻译：热塑性聚合物，特别是结晶热塑性聚合物如聚乙烯和聚丙烯的原纤维通过强制通过一对相对的同轴孔的热软化聚合物颗粒在液体介质中的分散体来制备。液体介质优选是水性的并被加压以防止沸腾。所得的原纤维具有一定程度的分子取向，并且可用于生产增强纸。

75. 发明授权

US3997510A Flame-resistant, thermoplastic polyesters 失效
标题翻译：耐火，热塑性聚酯
公开(公告)号：US3997510A
公开(公告)日：1976-12-14
申请号：US521126
申请日：1974-11-05
申请人： Jurgen Habermeier
发明人： Jurgen Habermeier
IPC分类号： C07D235/26 , C08G63/00 , C08G63/18 , C08G63/68 , C08G63/685 , D01F6/84
CPC分类号： C08G63/6856 , Y10S260/24
摘要： Linear thermoplastic polyesters which contain condensed N,N-di-(hydroxyalkyl)-halogenobenzimidazolones, are flame-resistant or flameproof and can be used for the manufacture of shaped articles of all kinds.
摘要翻译：含有缩合的N，N-二（羟基烷基） - 卤代苯并咪唑酮的线性热塑性聚酯是阻燃或防火的，可用于制造各种成型制品。

76. 发明授权

USB521126I5 失效
公开(公告)号：USB521126I5
公开(公告)日：1976-02-10
申请号：US52112674
申请日：1974-11-05
IPC分类号： C07D235/26 , C08G63/00 , C08G63/18 , C08G63/68 , C08G63/685 , D01F6/84
CPC分类号： C08G63/6856 , Y10S260/24

77. 发明授权

USB521125I5 失效
公开(公告)号：USB521125I5
公开(公告)日：1976-02-10
申请号：US52112574
申请日：1974-11-05
IPC分类号： C08G63/00 , C08G63/685 , C08G63/80 , D01F6/84
CPC分类号： C08G63/6856 , C08G63/80 , Y10S260/24

78. 发明授权

US3835099A Phosphorous acid and ester catalyzed formation of aminediol modified polyesters 失效
标题翻译：磷酸酯和酯催化形成氨基改性聚酯
公开(公告)号：US3835099A
公开(公告)日：1974-09-10
申请号：US37671573
申请日：1973-07-05
申请人： TOYO BOSEKI
发明人： MUNAKATA H , WATANABE K , ARIMATSU Y , TANAKA M
IPC分类号： C08L67/00 , C08G63/00 , C08G63/682 , C08G63/685 , C08G63/78 , C09J167/00 , D01F6/84 , D06P3/52 , C08G17/013
CPC分类号： C08G63/6856 , D06P3/521
摘要： IN WHICH R1 AND R2 ARE EACH AS DEFINED ABOVE AND P AND Q ARE EACH ZERO OR A POSITIVE INTEGER NOT MORE THAN 10, AN IMPROVED PROCESS WHICH IS CHARACTERIZED IN THAT THE REACTION IS CARRIED OUT IN THE PRESENCE OF AT LEAST ONE OF PHOSPHOROUS ACID COMPOUNDS AND HYPOPHOSPHOROUS ACID, WHEREBY (1) THE RATE OF POLYMERIZATION IS ELEVATED, (2) THE SUBLIMATION OF THE STARTING CARBOXYLIC ACID IS PREVENTED, (3) THE MOLECULAR WEIGHT OF THE POLYESTER IS INCREASED AND (4) THE POLYESTER OBTAINED IS COLORLESS AND TRANSPARENT.

-CH2-N(-R1)-R2

WHEREIN R1 AND R2 ARE EACH A LOWER ALKYL GROUP OR, WHEN TAKEN TOGETHER, THEY REPRESENT A LOWER ALKYLENE GROUP, R3 IS A LOWER ALKYL GROUP OR A GROUP OF THE FORMULA:

CH2-O)Q-H

H-(O-CH2-CH2)P-O-CH2-C(-R3)(-CH2-N(-R1)-R2)-CH2-O-(CH2-

IN THE PRODUCTION OF A POLYESTER IMPROVED IN DYEABILITY WITH ACID DYES BY THE REACTION BETWEEN A CARBOXYLIC ACID AND A GLYCOL OF WHICH THE WHOLE OR PART IS THE ONE REPRESENTED BY THE FORMULA:

79. 发明公开

US20240360598A1 Thermoplastic Copolyester Elastomer-Based Yarn 审中-公开
公开(公告)号：US20240360598A1
公开(公告)日：2024-10-31
申请号：US18647086
申请日：2024-04-26
申请人： Celanese Polymers Holding, Inc.
发明人： Carmen A. Covelli , Greg C. Oldham , James A. Lombardo , Katrina Kratz
IPC分类号： D02G3/02 , D01D5/088 , D01F6/84 , D01F11/08 , D02G3/32
CPC分类号： D02G3/02 , D01D5/088 , D01F6/84 , D01F11/08 , D02G3/32 , D10B2331/04 , D10B2401/063
摘要： A thermoplastic copolyester elastomer-based yarn and a method of making a thermoplastic copolyester elastomer-based yarn are disclosed. The yarn comprises a filament that is formed from a thermoplastic copolyester elastomer composition comprising a thermoplastic copolyester elastomer containing hard segments and soft segments. The thermoplastic copolyester elastomer exhibits a flexural modulus of about 300 MPa or less as determined in accordance with ISO 178:2019 at a temperature of about 23° C. and a melting temperature of from about 100° C. to about 230° C. as determined in accordance with ISO 11357-3:2018. The yarn has a linear density of from about 1 to about 2000 denier per filament and exhibits an elongation at break of about 300% or more as determined in accordance with ASTM D2653-07(2018) at a temperature of about 23° C.

80. 发明公开

US20240263358A1 TEXTILE ELEMENTARY MONOFILAMENT CONSISTING OF A POLYESTER 审中-公开
公开(公告)号：US20240263358A1
公开(公告)日：2024-08-08
申请号：US18560979
申请日：2022-05-09
申请人： COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN , Centre National De La Recherche Scientifique (CNRS) , INSTITUT NATIONAL DES SCIENCES APPLIQUÉES DE LYON , Université Claude Bernard Lyon 1 , Université Jean Monnet
发明人： MARC SUTTER , CHRISTOPHE LE CLERC , MÉLISSA POLONI , MARION COLELLA , JULIEN BERNARD , ALAIN ROUSSEAU
IPC分类号： D01F6/84 , C08G63/672 , C08G63/78 , D01D5/08
CPC分类号： D01F6/84 , C08G63/672 , C08G63/78 , D01D5/08 , D10B2331/04 , D10B2401/063
摘要： The invention relates to a textile elementary monofilament consisting of a polyester, said textile elementary monofilament having a melting point Tm of greater than or equal to 240° C., a tenacity of greater than or equal to 2.5 cN/tex and an elongation at break of greater than or equal to 10%, and also to a process for producing such a monofilament.

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