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    • 75. 发明授权
    • Vanadium scavenging compositions
    • 钒清除组合物
    • US4920087A
    • 1990-04-24
    • US165696
    • 1988-03-09
    • Richard F. Wormsbecher
    • Richard F. Wormsbecher
    • B01J29/08C10G11/02C10G11/04C10G11/05
    • B01J29/084C10G11/02C10G11/04C10G11/05
    • Catalytic cracking catalysts which contain a basic alkaline earth metal component in amounts greater than 5 percent by weight (expressed as the oxides) are used to crack hydrocarbon feedstocks that contain substantial quantities of metals such as vanadium, nickel, copper and iron. In a particularly preferred embodiment natural or synthetic particulate magnesium oxide (MgO) containing composites such as dolomite or a formed particulate coprecipitated magnesia-silica cogel (MgO.SiO.sub.2) having a substantial intra-particle pore volume in pores ranging from about 200-10,000 .ANG. in diameter and an average pore diameter greater than about 400 .ANG. in the 200-10,000 .ANG. diameter range is mixed with a zeolite containing fluid cracking catalyst (FCC) either as an integral component of the catalyst particle or as a separate additive.
    • 使用含有大于5重量%(表示为氧化物)的碱性碱土金属组分的催化裂化催化剂用于裂解含有大量金属如钒,镍,铜和铁的烃原料。 在特别优选的实施方案中,包含复合材料如天然或合成的颗粒状氧化镁(MgO),例如白云石或形成颗粒的共沉淀氧化镁 - 硅石共凝胶(MgO.SiO 2),其孔隙范围为约200-10,000安培 直径和在200-10,000安格姆斯直径范围内大于约400安培姆的平均孔径与含沸石的流化裂解催化剂(FCC)混合,作为催化剂颗粒的组成成分或作为单独的添加剂。
    • 76. 发明授权
    • Unclouded metals passivation additive
    • 无云金属钝化添加剂
    • US4919840A
    • 1990-04-24
    • US311487
    • 1989-02-16
    • Ernest B. Boston
    • Ernest B. Boston
    • C10G11/02
    • C10G11/02
    • Unclouded solutions of antimony hydrocarbylthiolate suitable for metals passivation are produced utilizing an amine. In one embodiment of the invention the amine is included with the antimony oxide and hydroxyhydrocarbylthiol reactants to produce the passivating agent. In another embodiment of the invention, the metals passivation additive is produced by combining antimony oxide with a hydroxyhydrocarbylthiol to produce a reaction mixture which is thereafter contacted with an amine. The resulting product is useful for the passivation of metals deposited on cracking catalysts.
    • 使用胺制备适用于金属钝化的烃基硫醇锑的无云解决方案。 在本发明的一个实施方案中,胺与氧化锑和羟基烃基硫醇反应物一起包括以产生钝化剂。 在本发明的另一个实施方案中,金属钝化添加剂通过将氧化锑与羟基烃基硫醇组合以产生反应混合物而生产,其后与胺接触。 所得产物可用于沉积在裂化催化剂上的金属的钝化。
    • 78. 发明授权
    • Unclouded metals passivation additive
    • 无云金属钝化添加剂
    • US4830730A
    • 1989-05-16
    • US151356
    • 1988-02-02
    • Ernest B. Boston
    • Ernest B. Boston
    • C10G11/02
    • C10G11/02Y10S502/521
    • Unclouded solutions of antimony hydrocarbylthiolate suitable for metals passivation are produced utilizing an amine. In one embodiment of the invention the amine is included with the antimony oxide and hydroxyhydrocarbylthio reactants to produce the passivating agent. In another embodiment of the invention, the metals passivation additive is produced by combining antimony oxide with a hydroxhydrocarbylthiol to produce a reaction mixture which is thereafter contacted with an amine. The resulting product is useful for the passivation of metals deposited on cracking catalysts.
    • 使用胺制备适用于金属钝化的烃基硫醇锑的无云解决方案。 在本发明的一个实施方案中,胺与氧化锑和羟基烃基硫代反应物一起包括以产生钝化剂。 在本发明的另一个实施方案中,金属钝化添加剂通过将氧化锑与羟基烃基硫醇组合以产生反应混合物而生产,此后与胺接触。 所得产物可用于沉积在裂化催化剂上的金属的钝化。
    • 79. 发明授权
    • Passivation of metal contaminated cracking catalysts
    • 金属污染裂化催化剂的钝化
    • US4793914A
    • 1988-12-27
    • US120576
    • 1987-11-13
    • Brent J. BertusDarrell W. Walker
    • Brent J. BertusDarrell W. Walker
    • B01J33/00C10G11/02C10G11/00
    • B01J33/00C10G11/02
    • A novel cracking catalyst, a method of preparing same and an improved hydrocarbon cracking process are provided wherein adverse effects of metals such as nickel, vanadium, iron, copper and cobalt in the cracking catalyst are precluded or mitigated by contacting the cracking catalyst with an antimony treating agent comprising at least one of elemental antimony and compounds thereof and a lithium treating agent comprising at least one of elemental lithium and compounds thereof whereby there is added to said catalyst a modifying amount of each antimony treating agent and lithium treating agent with the weight ratio of antimonmy to lithium being such as to provide passivation of contaminating metals greater than the sum of the passivation effect of each of antimony treating agent and lithium treating agent individually.
    • 提供了一种新的裂化催化剂,其制备方法和改进的烃裂解方法,其中通过使裂化催化剂与锑接触来排除或减轻裂化催化剂中镍,钒,铁,铜和钴等金属的不利影响 包括元素锑及其化合物中的至少一种的处理剂和包含元素锂及其化合物中的至少一种的锂处理剂,由此向所述催化剂中加入每种锑处理剂和锂处理剂的改性量,其重量比 例如提供比锑处理剂和锂处理剂各自钝化效果的总和大的污染金属的钝化。
    • 80. 发明授权
    • Process for thermal cracking of heavy oil
    • 重油热裂解工艺
    • US4772378A
    • 1988-09-20
    • US63766
    • 1987-06-23
    • Terukatsu MiyauchiYoneichi IkedaTatsuji Kikuchi
    • Terukatsu MiyauchiYoneichi IkedaTatsuji Kikuchi
    • B01J38/22C10G9/32C10G11/02C10G47/30
    • C10G47/30
    • Disclosed is a process for the thermal cracking of heavy oils, which comprises a thermal cracking step of contacting a heavy oil with a fine powder of a porous material fluidized by a fluidizing gas to mainly obtain a light oil and a regenerating step of gasifying and removing coke adhering to the fine powder taken out from the thermal cracking step while fluidizing the fine powder by a molecular oxygen-containing gas and a steam-containing gas, the fine powder being circulated between the two steps, wherein fine spherical particles having a pore volume of 0.2 to 1.5 cm.sup.3 /g, a specific surface area of 5 to 1500 m.sup.2 /g, an average pore size of 10 to 10,000 .ANG. and a weight average size of 0.025 to 0.25 mm, in which these properties are stably maintained at the temperature adopted for the thermal cracking, are used as the fine powder, and a hydrogen gas is made present at the thermal cracking step, the partial pressure of hydrogen is maintained at about 0.5 to about 5 Kg/cm.sup.2 and the total pressure at said step is maintained at about 1 to about 10 Kg/cm.sup.2 -G.
    • 本发明公开了一种重油热裂化方法,其特征在于,包括将重油与流化气体流化的多孔质材料的细粉接触以主要获得轻油的热裂解步骤和气化除去的再生步骤 焦炭附着在从热裂解步骤取出的细粉末中,同时通过含分子氧的气体和含蒸气的气体使微细粉末流化,细粉末在两个步骤之间循环,其中细孔体积 的比例为0.2〜1.5cm 3 / g,比表面积为5〜1500m 2 / g,平均孔径为10〜10,000,重均粒径为0.025〜0.25mm,其特性稳定地保持在温度 用于热裂解,用作细粉末,并且在热裂解步骤中存在氢气,氢的分压保持在约0.5至约5Kg / cm 2,并且 所述步骤的压力保持在约1至约10Kg / cm 2 -G。