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71. 发明授权

US2202994A Process for making alkali metal amides 失效
标题翻译：制备碱金属酰胺的方法
公开(公告)号：US2202994A
公开(公告)日：1940-06-04
申请号：US6767936
申请日：1936-03-07
申请人： DU PONT
发明人： NIEUWLAND JULIUS A
IPC分类号： C01B21/082 , C01B21/092
CPC分类号： C01B21/0926 , C01B21/082

72. 发明授权

US10160036B2 Stabilized lithium metal formations coasted with a shell containing nitrogen, and a method for the production of same 有权
公开(公告)号：US10160036B2
公开(公告)日：2018-12-25
申请号：US14785237
申请日：2014-04-17
申请人： Rockwood Lithium GmbH
发明人： Ulrich Wietelmann , Christoph Hartnig , Ute Emmel , Vera Nickel
IPC分类号： B22F1/00 , C01B21/06 , C01D15/00 , C01B21/092 , H01M4/36 , H01M4/38 , H01M4/62 , B22F1/02 , H01M10/052 , H01M4/134 , H01M4/02
摘要： The invention relates to particulate lithium metal formations having a substantially spherical geometry and a core composed of metallic lithium, which are enclosed with an outer passivating but ionically conductive layer containing nitrogen. The invention further relates to a method for producing lithium metal formations by reacting lithium metal with one or more passivating agent(s) containing nitrogen, selected from the groups N2, NxHy with x=1 or 2 and y=3 or 4, or a compound containing only the elements C, H, and N, and optionally Li, at temperatures in the range between 60 and 300° C., preferably between 100 and 280° C., and particularly preferably above the melting temperature of lithium of 180.5° C., in an inert organic solvent under dispersion conditions or in an atmosphere that contains a gaseous coating agent containing nitrogen.

73. 发明授权

US09771383B2 Modified opioids containing silicon 有权
公开(公告)号：US09771383B2
公开(公告)日：2017-09-26
申请号：US14710777
申请日：2015-05-13
申请人： James Andrew Leskosek
发明人： James Andrew Leskosek
IPC分类号： C07F7/10 , C01B21/092 , A61K31/695 , C07F7/18 , C07F7/21 , C07F7/08
CPC分类号： C07F7/10 , A61K31/695 , C01B21/092 , C07F7/0801 , C07F7/1804 , C07F7/1872 , C07F7/21
摘要： A modified opioid is provided comprising modified morphine molecules, wherein for each morphine molecule, one or more carbon atoms are replaced with silicon atoms. A method is further provided for modifying an opioid comprising morphine molecules, said method comprising the step of replacing one or more carbon atoms with silicon atoms.

74. 发明授权

US07927569B2 Methods for producing gallium and other oxo/hydroxo-bridged metal aquo clusters 有权
标题翻译：镓和其他氧代/羟基桥接金属聚簇的生产方法
公开(公告)号：US07927569B2
公开(公告)日：2011-04-19
申请号：US12541889
申请日：2009-08-14
申请人： Darren W. Johnson , Elisabeth Rather Healey , Jason T. Gatlin , Zachary L. Mensinger
发明人： Darren W. Johnson , Elisabeth Rather Healey , Jason T. Gatlin , Zachary L. Mensinger
IPC分类号： C01F17/00 , C01B21/092
CPC分类号： C01G15/00 , C01F7/66 , C01G1/00 , C01P2002/30 , C01P2002/72 , C01P2002/77
摘要： Metallic clusters can be produced by contacting a metal salt such as a metal nitrate with an organic reducing agent. Metals can be selected from a group consisting of metals exhibiting octahedral coordination, and nitrates of the selected metal or metals are contacted with, for example nitrosobenzene. Binary, tertiary, or other clusters can be produced.
摘要翻译：金属簇可以通过使金属盐如金属硝酸盐与有机还原剂接触来制备。金属可以从由显示八面体配位的金属组成的组中选择，并且所选择的金属或金属的硝酸盐与例如亚硝基苯接触。可以生成二元，三级或其他簇。

75. 发明申请

US20090175775A1 Metal complexes having vitamin b12 as a ligand 失效
标题翻译：具有维生素B12作为配体的金属配合物
公开(公告)号：US20090175775A1
公开(公告)日：2009-07-09
申请号：US10585294
申请日：2005-01-10
申请人： Roger Alberto , Susanne Barbara Kunze , Hector Knight Castro , Stefan Mundwiler
发明人： Roger Alberto , Susanne Barbara Kunze , Hector Knight Castro , Stefan Mundwiler
IPC分类号： C07F15/00 , C07F13/00 , C07F1/08 , C01B21/092
CPC分类号： C07D487/22 , A61K47/551 , A61K51/0453
摘要： The present invention relates to a metal complex of the general formula M(L)n, wherein each L is independently selected and represents a ligand and at least one L is vitamin B12 (cyanocobalamin) or a derivative thereof bound through the nitrogen atom of its cyanide group to M, which is an element selected from the transition metals, thus, forming a M-NC—[Co] moiety with [Co] representing vitamin B12 without cyanide and wherein n is 1, 2, 3, 4, 5 or 6. The complex can be prepared by mixing a precursor molecule with vitamin B12. The metal complexes can be used for radiodiagnostics, chemotherapy and radionuclide therapy.
摘要翻译：本发明涉及一种通式M（L）n的金属络合物，其中每个L独立选择并代表一种配体，至少一种L是维生素B12（氰钴胺）或其衍生物，其结合在其的氮原子上氰化物基团，其是选自过渡金属的元素，因此，形成具有代表不含氰化物的维生素B12的[Co]部分的M-NC- [Co]部分，并且其中n为1,2,3,4,5或复合物可以通过将前体分子与维生素B12混合来制备。金属络合物可用于放射诊断，化疗和放射性核素治疗。

76. 发明授权

US07537747B2 Hydrogen storage mixed gas system method 失效
标题翻译：储氢混合气系统方法
公开(公告)号：US07537747B2
公开(公告)日：2009-05-26
申请号：US10860628
申请日：2004-06-03
申请人： Martin S Meyer , Frederick E Pinkerton , Gregory P Meisner
发明人： Martin S Meyer , Frederick E Pinkerton , Gregory P Meisner
IPC分类号： C01B21/092 , C01B3/04 , C01B6/04 , C01B6/06 , C01B6/24 , C01B6/00 , C01B6/02
CPC分类号： C01B3/065 , C01B21/0923 , Y02E60/362
摘要： A system comprising solid media and a gaseous atmosphere, said solid media having a first condition which is hydrogenated and a second condition which is partially or fully dehydrogenated relative to said first condition, and wherein said gaseous atmosphere comprises nitrogen.
摘要翻译：一种包含固体介质和气体气氛的系统，所述固体介质具有被氢化的第一条件和相对于所述第一条件部分或完全脱氢的第二条件，并且其中所述气态气体包括氮气。

77. 发明申请

US20080237538A1 Process for Preparing Lithium Amide and a Composition Obtainable by Said Process 审中-公开
标题翻译：制备锂酰胺的方法和所述方法可获得的组合物
公开(公告)号：US20080237538A1
公开(公告)日：2008-10-02
申请号：US10590167
申请日：2005-02-14
申请人： Ian V.J. Archer , Noel A. Hamill
发明人： Ian V.J. Archer , Noel A. Hamill
IPC分类号： C01B21/092 , C09K3/00
CPC分类号： C01B21/0926
摘要： There is provided a process for preparing a lithium amide composition in which in a first step lithium metal is brought into contact with ammonia to form lithium bronze and in a second step the lithium bronze is reacted with a 1,3-diene or an arylolefin, such as butadiene, isoprene, piperylene, dimethylbutadiene, hexadiene, styrene, methyl styrene, divinylbenzene, naphthalene or anthracene, in the presence of a solvent wherein the temperature is maintained at or below the boiling point of ammonia. Examples of solvents include pentane, cyclopentane, hexane, heptane, octane, cyclohexane, toluene, xylene, cumene, ethyl benzene, tetraline, diethyl ether, tetrahydrofuran (THF), 2-methyl-THF, tetrahydropyran, diisopropyl ether, dibutyl ether, dioxan, methyl-tert-butyl ether or glycol ether. Lithium amide compositions obtainable by said process show improved activity, particularly in reactions involving enolate formation.
摘要翻译：提供了一种制备氨基锂组合物的方法，其中在第一步中，使锂金属与氨接触形成青铜，第二步是将青铜与1,3-二烯烃或芳烃烯烃反应，例如丁二烯，异戊二烯，戊间二烯，二甲基丁二烯，己二烯，苯乙烯，甲基苯乙烯，二乙烯基苯，萘或蒽在溶剂存在下，其中温度保持在氨或沸点以下。溶剂的实例包括戊烷，环戊烷，己烷，庚烷，辛烷，环己烷，甲苯，二甲苯，枯烯，乙苯，四氢化萘，乙醚，四氢呋喃（THF），2-甲基THF，四氢吡喃，二异丙基醚，二丁醚，二恶烷，甲基叔丁基醚或二醇醚。通过所述方法可获得的酰胺组合物显示改善的活性，特别是在涉及烯醇化物形成的反应中。

78. 发明授权

US07341703B2 Mixed hydrogen generation material 失效
标题翻译：混合氢气生成材料
公开(公告)号：US07341703B2
公开(公告)日：2008-03-11
申请号：US10789899
申请日：2004-02-27
申请人： Frederick E Pinkerton , Martin S Meyer , Gregory P Meisner
发明人： Frederick E Pinkerton , Martin S Meyer , Gregory P Meisner
IPC分类号： C01B21/092 , C01B3/04
CPC分类号： C01B21/092 , C01B3/001 , C01B3/0031 , C01B21/08 , C01B21/0923 , C01P2002/72 , C01P2002/88 , Y02E60/327 , Y02E60/364
摘要： In one aspect, the invention provides a novel quaternary hydrogen storage composition having a hydrogenated state and a dehydrogenated state. Further, the present invention provides methods of storing hydrogen in a hydrogen storage composition, and methods of releasing hydrogen by reacting a nitride composition and a hydride composition.
摘要翻译：一方面，本发明提供具有氢化状态和脱氢状态的新型储氢组合物。此外，本发明提供了将氢存储在储氢组合物中的方法，以及通过使氮化物组合物和氢化物组合物反应释放氢的方法。

79. 发明申请

US20050271581A1 Hydrogen storage mixed gas system method 失效
标题翻译：储氢混合气系统方法
公开(公告)号：US20050271581A1
公开(公告)日：2005-12-08
申请号：US10860628
申请日：2004-06-03
申请人： Martin Meyer , Frederick Pinkerton , Gregory Meisner
发明人： Martin Meyer , Frederick Pinkerton , Gregory Meisner
IPC分类号： C01B3/06 , C01B3/08 , C01B21/092
CPC分类号： C01B3/065 , C01B21/0923 , Y02E60/362
摘要： A system comprising solid media and a gaseous atmosphere, said solid media having a first condition which is hydrogenated and a second condition which is partially or fully dehydrogenated relative to said first condition, and wherein said gaseous atmosphere comprises nitrogen.
摘要翻译：一种包含固体介质和气体气氛的系统，所述固体介质具有被氢化的第一条件和相对于所述第一条件部分或完全脱氢的第二条件，并且其中所述气态气体包括氮气。

80. 发明授权

US06967012B2 Imide/amide hydrogen storage materials and methods 失效
标题翻译：酰亚胺/酰胺储氢材料及方法
公开(公告)号：US06967012B2
公开(公告)日：2005-11-22
申请号：US10603474
申请日：2003-06-25
申请人： Gregory P. Meisner , Frederick E. Pinkerton , Martin S. Meyer , Michael P. Balogh , Matthew D. Kundrat
发明人： Gregory P. Meisner , Frederick E. Pinkerton , Martin S. Meyer , Michael P. Balogh , Matthew D. Kundrat
IPC分类号： C01B3/00 , C01B21/092 , C01B6/02 , C01B6/04 , C01B6/06 , C01B6/24
CPC分类号： C01B3/001 , C01B21/0926 , Y02E60/324 , Y02E60/364
摘要： In one aspect, the invention provides a hydrogen storage composition having a hydrogenated state and a dehydrogenated state. In the hydrogenated state, such composition comprises an amide and a hydride. In a dehydrogenated state, the composition comprises an imide.
摘要翻译：一方面，本发明提供具有氢化状态和脱氢状态的储氢组合物。在氢化状态下，这种组合物包含酰胺和氢化物。在脱氢状态下，组合物包含酰亚胺。

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