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    • 77. 发明授权
    • Method of inhibiting corrosion using cations
    • 使用阳离子抑制腐蚀的方法
    • US4474607A
    • 1984-10-02
    • US474208
    • 1983-03-10
    • Brian P. F. GoldieJohn J. McCarroll
    • Brian P. F. GoldieJohn J. McCarroll
    • C09C1/00C09C1/24C09C1/30C09C1/42C09C3/00C09C3/06C09D5/08C09D17/00C23F11/00C23F11/18C04B9/02
    • C09C1/00C09C1/24C09C1/3045C09C1/42C09C3/06C09D5/084C23F11/18C01P2004/61C01P2004/84C01P2006/12C01P2006/80
    • A corrosion inhibitor comprises particles of an inorganic oxide having cations of yttrium or cations of one or more metals of the lanthanide group chemically bound to the particles by ion-exchange. The cations are released by ion-exchange with other cations and not by the water solubility of the corrosion inhibitor.The corrosion inhibiting particles may be prepared by contacting particles of the inorganic oxide with an aqueous solution containing the required cations. Alternatively, the particles of the inorganic oxide may be contacted with an aqueous solution of an alkali metal so that alkali metal ions are exchanged onto the surface of the oxide and then contacting the alkali metal exchanged oxide with a solution of the required cations so that the required cations replace the alkali metal cations.The corrosion inhibiting particles may be incorporated into protective coatings e.g. paints based on epoxy resins, alkyd resins, vinyl resins or chlorinated rubbers in amounts up to 80% wt. based on the dry film weight of the coating.
    • 腐蚀抑制剂包括具有钇阳离子的无机氧化物颗粒或通过离子交换与颗粒化学结合的镧系元素的一种或多种金属的阳离子。 阳离子通过与其他阳离子离子交换而不是通过腐蚀抑制剂的水溶性释放。 腐蚀抑制颗粒可以通过使无机氧化物的颗粒与含有所需阳离子的水溶液接触来制备。 或者,无机氧化物的颗粒可以与碱金属的水溶液接触,使得碱金属离子交换到氧化物的表面上,然后使碱金属交换的氧化物与所需阳离子的溶液接触,使得 所需阳离子取代碱金属阳离子。 腐蚀抑制颗粒可以结合到保护涂层中,例如 基于环氧树脂,醇酸树脂,乙烯基树脂或氯化橡胶的涂料,其量高达80重量%。 基于涂膜的干膜重量。
    • 79. 发明授权
    • Stabilized surface modified fillers
    • 稳定表面改性填料
    • US4420341A
    • 1983-12-13
    • US365673
    • 1982-04-05
    • Thomas H. Ferrigno
    • Thomas H. Ferrigno
    • C08K9/04C09C3/08C09C1/42
    • C09C3/08C08K9/04C01P2004/61C01P2004/80C01P2006/10C01P2006/12C01P2006/19C01P2006/80
    • Several organic acid reactive comminuted minerals, which are generally used as fillers for plastics, rubber, etc., are treated with unsaturated organic acids, alone or in admixture with saturated acids, antioxidants and, alternatively, liquid agents. The surfied (surface modified) fillers thus obtained have excellent wetting and dispersion in both polar and non-polar media as exemplified by their superior packing fractions. Unsaturated acids, alone or in admixture with saturated acids, do not yield fillers stable to the effects of oxidation, both in preparation and use. It has been discovered that very low concentrations of antioxidants stabilize the surfied filler against oxidation and resulting instability. Liquid agents also have been discovered to add a new dimension to the art by cooperating with the acid surfiers (surface modifiers) to modify the interface between the filler and matrix to a greater extent than by previously available techniques. These surfied fillers are thus valuable adjuncts in formulating plastics and related compositions.
    • 通常用作塑料,橡胶等填料的几种有机酸反应性粉碎矿物,单独使用不饱和有机酸,或与饱和酸,抗氧化剂和液体剂混合处理。 如此获得的表面改性(表面改性)填料在极性和非极性介质中具有优异的润湿和分散性,例如其优异的填充分数。 不饱和酸单独或与饱和酸混合,在制备和使用中都不会产生对氧化作用有稳定的填料。 已经发现,非常低浓度的抗氧化剂使冲洗的填料稳定,防止氧化并导致不稳定性。 也已经发现液体试剂通过与酸洗涤剂(表面改性剂)配合来增加本领域的新​​尺寸,以通过以前可获得的技术更大程度地修饰填料和基质之间的界面。 因此,这些表面填料是配制塑料和相关组合物的有益辅助材料。