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    • 72. 发明授权
    • Catalyst for the polymerization of olefins and process for the
polymerization of olefins
    • 用于烯烃聚合的催化剂和烯烃聚合方法
    • US5498770A
    • 1996-03-12
    • US309885
    • 1994-09-20
    • Motoki HosakaKenji GotoMasahiko Matsuo
    • Motoki HosakaKenji GotoMasahiko Matsuo
    • C08F4/658C07F7/18C08F10/00C08F110/06C08F4/656
    • C08F10/00C07F7/184C08F110/06
    • A catalyst for the polymerization of olefins comprising (A) a solid catalyst component essentially containing magnesium, titanium, an electron donor compound, and a halogen which is prepared by contacting a magnesium compound, a titanium halide compound, and an electron donor compound, (B) an organoaluminum compound, and (C) an organosilicon compound and a process for polymerizing an olefin using the same are disclosed, the organosilicon compound (C) being represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represents an alkyl group having from 1 to 3 carbon atoms; R.sup.3 and R.sup.4, which may be the same or different, each represents an alkyl group having from 1 to 3 carbon atoms, or a halogen atom; and m and n each represents 0 or an integer of 1 or 2. A polyolefin having high stereoregularity and broad molecular weight distribution can be obtained in high yield.
    • 一种用于烯烃聚合的催化剂,包括(A)基本上含有镁,钛,电子给体化合物和卤素的固体催化剂组分,其通过使镁化合物,卤化钛化合物和电子给体化合物接触而制备( B)有机铝化合物和(C)有机硅化合物和使用其的使烯烃聚合的方法,有机硅化合物(C)由式(I)表示:其中R1和R2 其可以相同或不同,各自表示具有1至3个碳原子的烷基; R 3和R 4可以相同或不同,各自表示具有1至3个碳原子的烷基或卤素原子; m和n各自表示0或1或2的整数。可以高产率获得具有高立构规整性和宽分子量分布的聚烯烃。
    • 73. 发明授权
    • Polymer bound metallocenes
    • 聚合物结合金属茂
    • US5492975A
    • 1996-02-20
    • US455382
    • 1995-05-31
    • Bernd PeiferHelmut G. AltM. Bruce WelchSyriac J. Palackal
    • Bernd PeiferHelmut G. AltM. Bruce WelchSyriac J. Palackal
    • C08F4/642C07F17/00C08F4/58C08F4/60C08F4/619C08F4/6192C08F4/646C08F4/656C08F4/657C08F4/685C08F8/00C08F8/42C08F10/00
    • C08F8/42C08F10/00C08F4/61912C08F4/61916C08F4/61922
    • A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
    • 提供由式QM(R)m表示的聚合物结合配体及其制备方法,其中Q是聚苯乙烯,M是Si,C,Ge,Sn,P或N,每个R是至少一个 R是环戊二烯基型化合物,m为2或3,所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应,其中聚苯乙烯用碱金属进行金属化,其中所述有机卤化物由式XM(R )m,其中X是卤化物。 本发明的其它方面包括由式QM(R)mZYn表示的聚合物结合金属茂及其制备方法,其中Z为过渡金属,Y为卤化物,甲基,氢或环戊二烯基型基团, 并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系,其制备方法和使用该催化剂体系的聚合方法。
    • 74. 发明授权
    • Polymer bound ligands
    • 聚合物结合的配体
    • US5492973A
    • 1996-02-20
    • US454764
    • 1995-05-31
    • Bernd PeiferHelmut G. AltM. Bruce WelchSyriac J. Palackal
    • Bernd PeiferHelmut G. AltM. Bruce WelchSyriac J. Palackal
    • C08F4/642C07F17/00C08F4/58C08F4/60C08F4/619C08F4/6192C08F4/646C08F4/656C08F4/657C08F4/685C08F8/00C08F8/42C08F10/00
    • C08F8/42C08F10/00C08F4/61912C08F4/61916C08F4/61922
    • A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
    • 提供由式QM(R)m表示的聚合物结合配体及其制备方法,其中Q是聚苯乙烯,M是Si,C,Ge,Sn,P或N,每个R是至少一个 R是环戊二烯基型化合物,m为2或3,所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应,其中聚苯乙烯用碱金属进行金属化,其中所述有机卤化物由式XM(R )m,其中X是卤化物。 本发明的其它方面包括由式QM(R)mZYn表示的聚合物结合金属茂及其制备方法,其中Z为过渡金属,Y为卤化物,甲基,氢或环戊二烯基型基团, 并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系,其制备方法和使用该催化剂体系的聚合方法。