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71. 发明授权

US4469763A Lithium oxyhalide battery with cathode catalyst 失效
标题翻译：具有阴极催化剂的卤氧化锂电池
公开(公告)号：US4469763A
公开(公告)日：1984-09-04
申请号：US544244
申请日：1983-10-21
申请人： Fraser Walsh , R. Scott Morris
发明人： Fraser Walsh , R. Scott Morris
IPC分类号： H01M4/88 , H01M4/90 , H01M6/14 , H01M6/16
CPC分类号： H01M6/14 , H01M10/4235 , H01M4/134 , H01M4/62
摘要： In a lithium oxyhalide battery having an anode containing lithium, calcium or a combination thereof, a non-aqueous electrolyte containing an oxyhalide such as thionyl chloride, sulfuryl chloride or phosphorous oxychloride and a cathode, the improvement comprising:(a) addition of a tetraaza-[14]-annulene complex to the cathode.
摘要翻译：在具有包含锂，钙或其组合的阳极的卤氧化锂电池中，含有诸如亚硫酰氯，磺酰氯或磷酰氯的卤氧化物的非水电解质和阴极，改进包括：（a）添加四氮杂 - [14] - 芸香烯复合物到阴极。

72. 发明授权

US4463072A Secondary batteries containing room-temperature molten 1,2,3-trialkylimidazolium halide non-aqueous electrolyte 失效
标题翻译：含有室温熔融的1,2,3-三烷基咪唑卤化物非水电解质的二次电池
公开(公告)号：US4463072A
公开(公告)日：1984-07-31
申请号：US556497
申请日：1983-11-30
申请人： Paul R. Gifford , James B. Palmisano , Lawrence W. Shacklette , Ronald R. Chance , James E. Toth
发明人： Paul R. Gifford , James B. Palmisano , Lawrence W. Shacklette , Ronald R. Chance , James E. Toth
IPC分类号： H01M4/36 , H01M4/60 , H01M4/62 , H01M6/14 , H01M10/36
CPC分类号： H01M4/36 , H01M10/36 , H01M4/60 , H01M4/621 , H01M6/14
摘要： Batteries and especially secondary batteries employing an anode comprising aluminum and a molten, non-aqueous electrolyte containing admixtures of aluminum halide and 1,2,3-trialkylimidazolium halides having the formula TimX: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently alkyl groups of 1 to 12 carbons and X is independently halide or mixtures of halides, e.g., chloride and/or bromide are disclosed. The molar ratio of aluminum hereinafter denoted by Al, to trialkylimidalozium, hereinafter denoted by Tim, in the electrolyte, may be varied over a wide range so as to make the molten electrolyte composition acidic and as such the electrolyte is useful in batteries, especially secondary batteries employing aluminum anodes and a variety of cathodes.
摘要翻译：电池，特别是使用包含铝的阳极和含有卤化铝和具有式TimX的1,2,3-三烷基咪唑卤化物的熔融非水电解质的二次电池：其中R1，R2和R3独立地为烷基 1至12个碳，X独立地为卤化物或卤化物的混合物，例如氯化物和/或溴化物。以下由Al表示的铝与三烷基酰亚胺的摩尔比（以下用Tim表示）在电解质中可以在宽范围内变化，以使熔融电解质组合物呈酸性，并且因此电解质可用于电池，特别是二次采用铝阳极和各种阴极的电池。

73. 发明授权

US4463071A Secondary batteries using room-temperature molten non-aqueous electrolytes containing 1,2,3-trialkylimidazolium halides or 1,3-dialkylimidazolium halide 失效
标题翻译：使用含有1,2,3-三烷基咪唑鎓卤化物或1,3-二烷基咪唑鎓卤化物的室温熔融非水电解质的二次电池
公开(公告)号：US4463071A
公开(公告)日：1984-07-31
申请号：US556496
申请日：1983-11-30
申请人： Paul R. Gifford , Lawrence W. Shacklette , James E. Toth , James F. Wolf
发明人： Paul R. Gifford , Lawrence W. Shacklette , James E. Toth , James F. Wolf
IPC分类号： H01M4/36 , H01M4/60 , H01M6/14 , H01M10/36
CPC分类号： H01M6/14 , H01M10/36 , H01M4/36 , H01M4/60
摘要： Batteries and especially secondary batteries employing selected anodes and cathodes such as conjugated backbone polymers and transition metal chalcogenides inserted with alkali metal cations (especially lithium) and molten, non-aqueous electrolyte compositions containing admixture of aluminum halide and at least one of 1,2,3-trialkylimidazolium halide and 1,3-dialkylimidazolium halide having the formulae TimX and DimX, respectively: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are independently alkyl groups of 1 to 12 carbons and X is independently halide, e.g., chloride and bromide and in some instances an alkali metal and/or tetraalkylammonium salt which may also be incorporated into the electrolyte composition are disclosed. The molar ratio of aluminum to trialkylimidazolium or to dialkylimidazolium in the electrolyte, may be varied over a wide range so as to make the molten electrolyte composition basic or neutral and as such the electrolyte is useful in batteries, especially secondary batteries comprising anodes of reduced conjugated backbone polymers or lithiated transition-metal chalcogenides such as Li.sub.x WO.sub.2 and a variety of cathodes such as oxidized conjugated backbone polymers or lithiated transition-metal chalcogenides such as Li.sub.x CoO.sub.2.
摘要翻译：电池，特别是使用插入有碱金属阳离子（特别是锂）的共轭主链聚合物和过渡金属硫族化合物的选定阳极和阴极以及阴极，其包含铝卤化物和至少一种1,2的混合物的熔融的非水电解质组合物， 3-三烷基咪唑鎓卤化物和具有式TimX和DimX的1,3-二烷基咪唑鎓卤化物：其中R 1，R 2，R 3，R 4和R 5独立地为1至12个碳的烷基，X独立地为卤素，例如，氯化物和溴化物，并且在一些情况下，还可以并入电解质组合物中的碱金属和/或四烷基铵盐。电解质中铝与三烷基咪唑或二烷基咪唑的摩尔比可以在很宽的范围内变化，以使熔融电解质组合物成为碱性或中性，因此电解质可用于电池，尤其是包含还原共轭阳极的二次电池骨架聚合物或锂化过渡金属硫族化物如LixWO2和各种阴极如氧化共轭主链聚合物或锂化过渡金属硫族化物如LixCoO2。

74. 发明授权

US4450213A Cell having improved abuse resistance 失效
标题翻译：细胞具有改善的耐药性
公开(公告)号：US4450213A
公开(公告)日：1984-05-22
申请号：US339819
申请日：1982-01-18
申请人： Arabinda N. Dey , Robert W. Holmes
发明人： Arabinda N. Dey , Robert W. Holmes
IPC分类号： H01M4/06 , H01M6/14 , H01M6/16 , H01M4/36
CPC分类号： H01M4/06 , H01M6/14 , Y10T29/49108
摘要： A non-aqueous cell having a lithium anode is made abuse resistant by sandwiching and enclosing a thin substantially perforation-free copper foil or sheet between layers of lithium whereby the copper is isolated from the cell electrolyte.
摘要翻译：具有锂阳极的非水电池通过在锂层之间夹入并包围薄的基本上无穿孔的铜箔或片而被制成具有抗性，由此将铜从电池电解质中分离出来。

75. 发明授权

US4447504A Electrochemical cell with two rate battery stacks 失效
标题翻译：电化学电池与两个电池堆叠
公开(公告)号：US4447504A
公开(公告)日：1984-05-08
申请号：US455090
申请日：1983-01-03
申请人： Franz Goebel
发明人： Franz Goebel
IPC分类号： H01M6/14 , H01M6/46 , H01M12/00 , H01M2/02 , H01M2/08 , H01M4/36
CPC分类号： H01M6/14 , H01M6/46
摘要： A primary electrochemical cell capable of selective operation at one of several possible discharge rates. The electrochemical cell in accordance with the present invention includes a pair of battery stacks positioned one above the other in a housing of the cell in a spaced-apart relationship. One of the battery stacks includes a first plurality of anode structures of first thicknesses and a first plurality of carbon electrode structures of first thicknesses arranged in alternation with the first plurality of anode structures. Similarly, the other battery stack includes a second plurality of anode structures of second thicknesses and a second plurality of carbon electrode structures of second thicknesses arranged in alternation with the second plurality of anode structures. The relative thicknesses of the abovementioned components of the two stacks, together with the number of components in the two stacks, can be controlled so as to achieve different discharge rates and durations of discharge of the cell at the different rates. The battery stacks may be operated during discharge either individually or together to achieve three possible discharge rates for the cell.
摘要翻译：能够以几种可能的放电速率之一选择性操作的主电化学电池。根据本发明的电化学电池包括一对电池堆，它们以间隔开的关系一个在电池的壳体中彼此上下放置。电池堆中的一个包括第一厚度的第一多个阳极结构和与第一多个阳极结构交替布置的第一厚度的第一多个碳电极结构。类似地，另一个电池堆包括第二厚度的第二多个阳极结构和与第二多个阳极结构交替布置的第二厚度的第二多个碳电极结构。可以控制两个堆叠的上述组分的相对厚度以及两个堆叠中的组分的数量，以便以不同的速率实现不同的放电速率和电池的放电持续时间。电池堆可以在放电期间单独地或一起操作以实现电池的三种可能的放电速率。

76. 发明授权

US4426430A Inorganic NbF.sub.5 (TaF.sub.5)-P.sub.2 O.sub.5 electrolytes 失效
标题翻译：无机NbF5（TaF5）-P2O5电解质
公开(公告)号：US4426430A
公开(公告)日：1984-01-17
申请号：US441119
申请日：1982-11-12
申请人： Paul A. Tick
发明人： Paul A. Tick
IPC分类号： H01M6/14 , H01M10/36 , H01M4/36
CPC分类号： H01M6/14 , H01M10/36
摘要： Compositions in the NbF.sub.5 (TaF.sub.5)-P.sub.2 O.sub.5 system which are liquid at room temperature and exhibit relatively high ionic conductivities, useful for example, as electrolytes in batteries or other electrochemical cells, are described.
摘要翻译：描述了NbF5（TaF5）-P2O5系统中在室温下液体并具有较高离子电导率的组合物，例如可用作电池或其它电化学电池中的电解质。

77. 发明授权

US4418127A Battery cell module 失效
标题翻译：电池单元模块
公开(公告)号：US4418127A
公开(公告)日：1983-11-29
申请号：US324348
申请日：1981-11-23
申请人： John S. Shambaugh , Robert G. Yetman , Hyman Zeltzer
发明人： John S. Shambaugh , Robert G. Yetman , Hyman Zeltzer
IPC分类号： H01M2/02 , H01M2/10 , H01M2/12 , H01M6/14 , H01M14/00
CPC分类号： H01M2/1258 , H01M2/0202 , H01M2/10 , H01M2/12 , H01M6/14 , H01M2/1223
摘要： A modular lithium battery having a plurality of cells, having electrical connecting means connecting the cells to output terminals, and venting means for releasing discharge byproducts to a chemical scrubber. Stainless steel cell casings are potted in an aluminum modular case with syntactic foam and epoxy. The wall thickness resulting is about 0.5 inches.
摘要翻译：具有多个电池的模块化锂电池，具有将电池连接到输出端子的电连接装置，以及用于将放电副产品释放到化学洗涤器的排气装置。不锈钢电池外壳采用复合泡沫和环氧树脂封装在铝模块外壳中。所产生的壁厚约为0.5英寸。

78. 发明授权

US4407910A Anode neutralization 失效
标题翻译：阳极中和
公开(公告)号：US4407910A
公开(公告)日：1983-10-04
申请号：US306132
申请日：1981-09-28
申请人： Vincent O. Catanzarite
发明人： Vincent O. Catanzarite
IPC分类号： H01M2/16 , H01M6/14 , H01M6/50 , H01M10/42 , H01M10/34
CPC分类号： H01M2/1613 , H01M6/14 , H01M10/4235 , H01M2200/00 , H01M2200/10 , H01M2300/0014 , H01M2300/002
摘要： An electrochemical cell having an alkali or alkaline metal anode, a cathode or current collector, an electrolyte and an anode neutralizing agent consisting of an inorganic solid positioned contiguous to and in intimate contact with the anode. Said neutralizing agent is nonreactive with all cell components below a predetermined temperature near the melting point of the anode. At or near the melting point of the anode, the agent and anode enter into endothermic or at most mildly exothermic reaction.
摘要翻译：具有碱金属或碱金属阳极的电化学电池，阴极或集电器，电解质和阳极中和剂，其由与阳极邻接且与阳极紧密接触的无机固体组成。所述中和剂与低于阳极熔点附近的预定温度的所有电池组分无反应。在或接近阳极的熔点时，试剂和阳极进入吸热或最温和的放热反应。

79. 发明授权

US4356240A Extremely high rate flat cell 失效
标题翻译：极高的扁平电池
公开(公告)号：US4356240A
公开(公告)日：1982-10-26
申请号：US200819
申请日：1980-10-27
申请人： Arabinda N. Dey , Noble E. Hamilton
发明人： Arabinda N. Dey , Noble E. Hamilton
IPC分类号： H01M6/14 , H01M6/46 , H01M4/36
CPC分类号： H01M6/46 , H01M6/14
摘要： An extremely high rate flat cell and a method of fabrication thereof with the cell comprising successive stacked anode and cathode layers within a cell container comprised of two members with co-fitting external flanges. Each cathode layer embodies a metallic extension or tab therefrom for external terminal connection. The extensions of all the cathode layers are substantially symmetrically positioned between said co-fitting external flanges with said flanges and metallic extensions all being simultaneously welded together and electrically interconnected during cell sealing. The anode layers are electrically connected together, preferably by pressure contacting layers to each other adjacent to a metallic terminal member for said anode. Such a cell having a lithium anode, a carbon cathode and a thionyl chloride electrolyte solvent/cathode depolarizer (3" diameter.times.0.90" height) safely provides a short circuit current in excess of 1500 amperes at a voltage above 1 volt and about 14 ampere hours at a constant current of 100 amperes.
摘要翻译：一种极高速率的扁平电池及其制造方法，电池包括在具有共同外部凸缘的两个构件的电池容器内的连续堆叠的阳极和阴极层。每个阴极层体现了用于外部端子连接的金属延伸件或突片。所有阴极层的延伸部基本上对称地位于所述共同的外部凸缘之间，其中所述凸缘和金属延伸部同时被焊接在一起并在电池密封期间电连接。阳极层电连接在一起，优选地通过相邻的金属端子构件彼此压力接触层。这种具有锂阳极，碳阴极和亚硫酰氯电解质溶剂/阴极去极化器（3“直径高0.85”）的电池在高于1伏特和约1伏特的电压下安全地提供超过1500安培的短路电流在安培恒定电流为安培时为14安培小时。

80. 发明授权

US4352866A Electrochemical cell with improved cathode current collector and method 失效
标题翻译：具有改进的阴极集电器和方法的电化学电池
公开(公告)号：US4352866A
公开(公告)日：1982-10-05
申请号：US116721
申请日：1980-01-30
申请人： Keith A. Klinedinst , Francis G. Murphy
发明人： Keith A. Klinedinst , Francis G. Murphy
IPC分类号： H01M4/86 , H01M6/14
CPC分类号： H01M6/14 , H01M4/86
摘要： Disclosed is a primary electrochemical cell having an improved cathode current collector and a method for making the current collector. The cell comprises an oxidizable active anode material; and electrolytic solution comprising a reducible soluble cathode and an electrolyte solute dissolved therein; and a cathode current collector comprising a layer of finely-divided catalyst for reducing the solvent, bonded to an inert, electrically-conductive substrate. Preferably, a bonding layer, comprising a finely-divided polymer and a minor amount of conductive material, bonds the catalyst layer to the substrate. The bonding and catalyst layers preferably can be formed by sequentially applying respective dispersions thereof to the substrate, drying, and heating to bond the materials. Soluble cathode cells employing cathode current collectors of the type described have exceptionally rapid discharge properties.
摘要翻译：公开了具有改进的阴极集电器和制造集电器的方法的主电化学电池。电池包括可氧化的活性阳极材料; 和包含可还原的可溶性阴极和溶解在其中的电解质溶质的电解液; 以及阴极集电器，其包括用于还原溶剂的细分催化剂层，结合到惰性导电基材上。优选地，包含细碎聚合物和少量导电材料的粘合层将催化剂层粘合到基底上。接合和催化剂层优选可以通过将其各自的分散体依次施加到基材上，干燥和加热以形成粘合材料。使用所述类型的阴极集电器的可溶性阴极电池具有非常快速的放电特性。

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