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    • 71. 发明授权
    • Photo ion spectrometer
    • 光离子光谱仪
    • US4889987A
    • 1989-12-26
    • US14332
    • 1987-02-13
    • Dieter M. GruenCharles E. YoungMichael J. Pellin
    • Dieter M. GruenCharles E. YoungMichael J. Pellin
    • H01J49/02H01J49/06H01J49/14H01J49/16H01J49/28
    • H01J49/161H01J49/022H01J49/061H01J49/142H01J49/282H01J49/484
    • A charged particle spectrometer for performing ultrasensitive quantitative analysis of selected atomic components removed from a sample. Significant improvements in performing energy and angular refocusing spectroscopy are accomplished by means of a two dimensional structure for generating predetermined electromagnetic field boundary conditions. Both resonance and non-resonance ionization of selected neutral atomic components allow accumulation of increased chemical information. A multiplexed operation between a SIMS mode and a neutral atomic component ionization mode with EARTOF analysis enables comparison of chemical information from secondary ions and neutral atomic components removed from the sample. An electronic system is described for switching high level signals, such as SIMS signals, directly to a transient recorder and through a charge amplifier to the transient recorder for a low level signal pulse counting mode, such as for a neutral atomic component ionization mode.
    • 一种带电粒子光谱仪,用于对从样品中除去的选定的原子成分进行超敏感定量分析。 通过用于产生预定电磁场边界条件的二维结构来实现执行能量和角度重新聚焦光谱的显着改进。 所选择的中性原子组分的共振和非共振电离都允许累积增加的化学信息。 通过EARTOF分析,SIMS模式和中性原子成分离子化模式之间的多路复用操作能够比较从样品中除去的二次离子和中性原子成分的化学信息。 描述了一种电子系统,用于将高电平信号(例如SIMS信号)直接切换到瞬态记录器,并通过电荷放大器切换到瞬态记录器,用于低电平信号脉冲计数模式,例如用于中性原子分量电离模式。
    • 75. 发明申请
    • ION SOURCE AND METHOD FOR GENERATING ELEMENTAL IONS FROM AEROSOL PARTICLES
    • US20180294149A1
    • 2018-10-11
    • US15857897
    • 2017-12-29
    • TOFWERK AG
    • Urs ROHNER
    • H01J49/04H01J49/14
    • H01J49/0445H01J27/24H01J49/14H01J49/161
    • The invention relates to an ion source (50) for generating elemental ions and/or ionised metal oxides from aerosol particles, comprising: a reduced pressure chamber (61) having an inside; an inlet (56) and a flow restricting device (60) for inserting the aerosol particles in a dispersion comprising the aerosol particles dispersed in a gas, in particular in air, into the inside of the reduced pressure chamber (61), the inlet (60) fluidly coupling an outside of the reduced pressure chamber (61) via the flow restricting device (60) with the inside of the reduced pressure chamber (60); a laser (62) for inducing in a plasma region (63) in the inside of the reduced pressure chamber (61) a plasma in the dispersion for atomising and ionising the aerosol particles to elemental ions and/or ionised metal oxides; wherein the reduced pressure chamber (61) is adapted for achieving and maintaining in the inside of the reduced pressure chamber (61) a pressure in a range from 0.01 mbar to 100 mbar. The invention further relates to a method for generating elemental ions and/or ionised metal oxides from aerosol particles, comprising the steps of inserting aerosol particles in a dispersion comprising the aerosol particles dispersed in a gas, in particular in air, through an inlet (56) via a flow restricting device (60) into an inside of a reduced pressure chamber (61), while maintaining in the inside of the reduced pressure chamber (61) a pressure in a range from 0.01 mbar to 100 mbar, preferably from 0.1 mbar to 100 mbar or from 1 mbar to 100 mbar, particular preferably from 0.1 mbar to 50 mbar or from 1 mbar to 50 mbar, most preferably from 0.1 mbar to 40 mbar or from 1 mbar to 40 mbar; and inducing with a laser (62) in a plasma region (63) in the inside of the reduced pressure chamber (61) a plasma in the dispersion for atomising and ionising the aerosol particles to elemental ions and/or ionised metal oxides, wherein the laser (62) is adapted for inducing in the plasma region (63) in the inside of the reduced pressure chamber (61) the plasma in the gas of the dispersion for atomising and ionising the aerosol particles to elemental ions.