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    • 72. 发明授权
    • Fused silica glass crucible
    • 熔融石英玻璃坩埚
    • US5730800A
    • 1998-03-24
    • US768282
    • 1996-12-17
    • Wataru SatoMasahiro SakuradaOhta TomohikoKatsuhiko Kemmochi
    • Wataru SatoMasahiro SakuradaOhta TomohikoKatsuhiko Kemmochi
    • C03C3/06C30B15/00C30B15/10C30B35/00
    • C30B29/06C03C3/06C30B15/10C30B35/002C03C2201/30C03C2201/32
    • An improved method is proposed for the preparation of a semiconductor silicon single crystal of N-type by the Czochralski process, which is free from the problem of occurrence of delayed OSFs as defects in the single crystal even after prolonged storage at room temperature based on the discovery that presence of a certain amount of aluminum in the melt of silicon contained in a fused silica glass crucible acts to suppress occurrence of delayed OSFs as a type of defects in the single crystal while copper as an impurity acts adversely in this regard. With a known fact that an about 30 .mu.m thick inner surface layer of the crucible is melted down into the silicon melt during the single crystal pulling-up process, namely, the invention proposes use of a crucible of which the inner surface layer of 30 .mu.m thickness contains aluminum in an average concentration of 40 to 500 ppm by weight while the content of copper is as low as possible not to exceed 0.5 ppb by weight. Alternatively, when the fused silica glass crucible is deficient in the content of aluminum, an amount of aluminum is introduced as a dopant into the melt of silicon in the crucible to supplement the content of aluminum in order to be sufficient to suppress delayed OSFs.
    • 提出了一种通过Czochralski工艺制备N型半导体硅单晶的改进方法,其即使在室温下长时间储存​​之后也不会出现延迟OSF作为单晶的缺陷的问题,基于 发现在熔融石英玻璃坩埚中含有的硅熔体中存在一定量的铝作为抑制作为单晶中的缺陷的延迟OSF的发生,而作为杂质的铜在这方面起不利影响。 在已知的事实中,在单晶提拉过程中坩埚的内表面层约30μm的内表面层熔化成硅熔体,即本发明提出使用内表面层为30的坩埚 平均浓度为40〜500ppm的铝,而铜的含量尽可能低,不超过0.5ppb(重量)。 或者,当熔融石英玻璃坩埚的铝含量不足时,将铝的量作为掺杂剂引入到坩埚中的硅熔体中,以补充铝的含量,以足以抑制延迟的OSF。
    • 73. 发明授权
    • Vessel made from pyrolytic boron nitride
    • 由热解氮化硼制成的容器
    • US5674317A
    • 1997-10-07
    • US584806
    • 1996-01-11
    • Noboru KimuraKenji Itou
    • Noboru KimuraKenji Itou
    • C04B35/583C30B15/10C30B35/00C30B29/38
    • C04B35/583C30B15/10C30B35/002Y10S117/90Y10T117/1032
    • Proposed is a novel vessel such as crucibles made from PBN (pyrolytic boron nitride), which is highly resistant against exfoliation of the surface layer and suitable for use, for example, as a container of the melt in the Czochralski single crystal growing of III-V Group compound semiconductor single crystals with an improvement in the serviceable life. The PBN-made vessel of the invention is characterized by specific values of several parameters including density, which should be in the range from 1.90 to 2.05 g/cm.sup.3, intensity ratio of the X-ray diffraction peaks representing the degree of orientation, heat conductivity coefficient and the like. The above mentioned advantageous serviceable life of the vessel can be obtained only when these parameter values are satisfied.
    • 提出了一种新型容器,例如由PBN(热解氮化硼)制成的坩埚,其耐表面层的剥离具有高度抗性,并且适用于例如在Czochralski单晶生长中的熔体的容器, V组化合物半导体单晶,使用寿命有所提高。 本发明的PBN制造的容器的特征在于几个参数的具体值,包括密度,其值应在1.90至2.05g / cm 3的范围内,表示取向度,导热性的X射线衍射峰的强度比 系数等。 只有满足这些参数值,才能获得上述有利的使用寿命。
    • 74. 发明授权
    • Method for the preparation of silicon single crystal
    • 硅单晶的制备方法
    • US5609682A
    • 1997-03-11
    • US498894
    • 1995-07-06
    • Wataru SatoMasahiro SakuradaOhta TomohikoKatsuhiko Kemmochi
    • Wataru SatoMasahiro SakuradaOhta TomohikoKatsuhiko Kemmochi
    • C03C3/06C30B15/00C30B15/10C30B35/00
    • C30B29/06C03C3/06C30B15/10C30B35/002C03C2201/30C03C2201/32
    • An improved method is proposed for the preparation of a semiconductor silicon single crystal of N-type by the Czochralski process, which is free from the problem of occurrence of delayed OSFs as defects in the single crystal even after prolonged storage at room temperature based on the discovery that presence of a certain amount of aluminum in the melt of silicon contained in a fused silica glass crucible acts to suppress occurrence of delayed OSFs as a type of defects in the single crystal while copper as an impurity acts adversely in this regard. With a known fact that an about 30 .mu.m thick inner surface layer of the crucible is melted down into the silicon melt during the single crystal pulling-up process, namely, the invention proposes use of a crucible of which the inner surface layer of 30 .mu.m thickness contains aluminum in an average concentration of 40 to 500 ppm by weight while the content of copper is as low as possible not to exceed 0.5 ppb by weight. Alternatively, when the fused silica glass crucible is deficient in the content of aluminum, an amount of aluminum is introduced as a dopant into the melt of silicon in the crucible to supplement the content of aluminum in order to be sufficient to suppress delayed OSFs.
    • 提出了一种通过Czochralski工艺制备N型半导体硅单晶的改进方法,其即使在室温下长时间储存​​之后也不会出现延迟OSF作为单晶的缺陷的问题,基于 发现在熔融石英玻璃坩埚中含有的硅熔体中存在一定量的铝作为抑制作为单晶中的缺陷的延迟OSF的发生,而作为杂质的铜在这方面起不利影响。 在已知的事实中,在单晶提拉过程中坩埚的内表面层约30μm的内表面层熔化成硅熔体,即本发明提出使用内表面层为30的坩埚 平均浓度为40〜500ppm的铝,而铜的含量尽可能低,不超过0.5ppb(重量)。 或者,当熔融石英玻璃坩埚的铝含量不足时,将铝的量作为掺杂剂引入到坩埚中的硅熔体中,以补充铝的含量,以足以抑制延迟的OSF。
    • 75. 发明授权
    • Method of making composite material crucible for use in a device for
making single crystals
    • 制造复合材料的方法可用于制造单晶的器件
    • US5132145A
    • 1992-07-21
    • US474460
    • 1990-02-02
    • Dominique Valentian
    • Dominique Valentian
    • C30B11/00C30B35/00
    • C30B11/002C30B35/002Y10T428/30
    • A composite material crucible for a device for making single crystals having a single layer integrally-formed cylindrical wall made of composite materials in order to simultaneously provide mechanical strength and matching of its thermal conductivity to the thermal conductivity of a molten sample. The wall has an inner lining intimately and integrally bonded thereto for providing the functions of sealing and physical and chemical compatibility with the sample, without contamination thereof. A method for manufacturing the cylindrical crucible comprising selecting a composite material wall composition including fibers made of carbon or silicon carbide, and a matrix made of carbon or silicon carbide, making from the composite material a single layer integrally-formed cylindrical wall, and depositing on the cylindrical wall an optimized material to form an inner coating which is intimately and integrally bonded to the cylindrical wall.
    • 一种用于制造单晶的装置的复合材料坩埚,其具有由复合材料制成的单层整体形成的圆柱形壁,以便同时提供其热导率与熔融样品的热导率的机械强度和匹配。 该壁具有紧密且一体地结合在其上的内衬,以提供与样品的密封和物理和化学相容性的功能,而不会污染它们。 一种制造圆柱形坩埚的方法,包括选择由碳或碳化硅制成的纤维的复合材料壁组合物和由碳或碳化硅制成的基体,由复合材料制成单层整体形成的圆柱形壁,并沉积在 圆柱形壁是优化的材料,以形成密封并整体地结合到圆柱形壁上的内涂层。
    • 77. 发明授权
    • Cristobalite reinforcement of high silica glass
    • 方石英加强高硅石玻璃
    • US5053359A
    • 1991-10-01
    • US523982
    • 1990-05-16
    • Ted A. LoxleyHarold L. Wheaton
    • Ted A. LoxleyHarold L. Wheaton
    • C03B32/02C03C10/00C03C10/14C30B15/10C30B35/00
    • C30B15/10C03B32/02C03C10/0009C30B35/002
    • A high-density silica glass article with excellent thermal shock characteristics is formed from a high purity vitreous silica containing an aluminum compound as a crystallization aid and having a dense concentration of cristobalite muclei. The aluminum compound is aluminum oxide, aluminum hydroxide, an aluminum salt, or other aluminum-oxide precursor.A refractory silica glass crucible made according to the invention has remarkable advantages in a Czochralski crystal-growing process. The entire crucible can be crystallized during the initial melt down in the Cz furnace to provide a cristobalite inner surface which effectively resists attack by the molten silicon to minimize contamination problems during crystal growing.Another embodiment of the invention relates to a unique drawn silica glass with good flexural strength having fibrous oriented veins of cristobalite embedded in a matrix of vitreous silica and having remarkable resistance to deformation at temperatures of 1500.degree. C. and higher as are encountered in certain ferrous casting and investment casting processes.
    • 具有优异的热冲击特性的高密度二氧化硅玻璃制品由含有铝化合物作为结晶助剂并具有密集浓度的方英石核的高纯度二氧化硅二氧化硅形成。 铝化合物是氧化铝,氢氧化铝,铝盐或其它氧化铝前体。 根据本发明制造的耐火二氧化硅玻璃坩埚在切克拉斯基晶体生长过程中具有显着的优点。 整个坩埚可以在Cz炉初始熔化过程中结晶,以提供方英石内表面,有效抵抗熔融硅的侵蚀,从而最大限度地减少晶体生长过程中的污染问题。 本发明的另一个实施方案涉及具有良好弯曲强度的独特的拉制二氧化硅玻璃,其具有嵌入玻璃状二氧化硅基质中的方英石的纤维定向静脉,并且在1500℃和更高的温度下具有显着的抗变形,如在某些亚铁中遇到的 铸造和熔模铸造工艺。