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    • 73. 发明授权
    • Dental adhesive composition
    • 牙科粘合剂组成
    • US08546463B2
    • 2013-10-01
    • US12386022
    • 2009-04-13
    • Joachim E. KleeUwe Lehmann
    • Joachim E. KleeUwe Lehmann
    • A61K6/083A61C5/00
    • C07F9/12A61K6/0023C07F9/091C07F9/093C08F216/125C08F220/58C08F222/385C08F230/02C08L43/02C08L33/00
    • Dental composition comprising an aqueous mixture containing (i) a polymerizable acidic phosphoric acid ester monomer of the following formula (A): wherein a is an integer of from 1 to 10; R1 represents a hydrogen atom or a moiety of the following formula (Y) wherein X independently represent an oxygen atom, a sulfur atom, or a group NR, wherein R may be a hydrogen atom, a C1-6 alkyl group or an acyl group; L represents an (a+b)-valent organic residue containing 1 to 20 carbon atoms and optionally including ether, thioether or amino groups or further acidic groups, whereby the carbon atoms comprise at least a+b carbon atoms selected from primary and secondary aliphatic carbon atoms, secondary alicyclic carbon atoms, and aromatic carbon atoms, each of said a+b carbon atoms linking a phosphate or 2-(oxaallyl) derivative group; b is an integer of from 1 to 10; R2 which may be the same or different, independently may be hydrogen, an allyl group or a moiety R1 wherein b is 1; provided that at least one of R1 and R2 is not hydrogen; (ii) one or more polymerizable N-substituted alkyl acrylic or acrylic acid amide monomers; (iii) an organic water-miscible solvent and/or water; (iv) a polymerization initiator; (v) an inhibitor and/or a stabilizer; (vi) optionally an organic or inorganic acid; and (vii) optionally a filler and/or a fluoride releasing compound.
    • 1.一种牙科用组合物,其含有含有(i)下述通式(A)的可聚合酸性磷酸酯单体的水性混合物:其中a为1〜10的整数, R1表示氢原子或下式(Y)的部分,其中X独立地表示氧原子,硫原子或基团NR,其中R可以是氢原子,C1-6烷基或酰基 ; L表示含有1至20个碳原子的(a + b)价有机残基,并且任选地包括醚,硫醚或氨基或其它酸性基团,其中碳原子包含至少一个选自伯和仲脂族 碳原子,仲脂环碳原子和芳族碳原子,所述a + b个碳原子各自连接磷酸酯或2-(氧杂烯丙基)衍生物基团; b为1〜10的整数, R 2可以相同或不同,独立地可以是氢,烯丙基或部分R1,其中b是1; 条件是R 1和R 2中的至少一个不是氢; (ii)一种或多种可聚合的N-取代的烷基丙烯酸或丙烯酸酰胺单体; (iii)有机水混溶性溶剂和/或水; (iv)聚合引发剂; (v)抑制剂和/或稳定剂; (vi)任选的有机或无机酸; 和(vii)任选的填料和/或氟化物释放化合物。
    • 74. 发明授权
    • Antifouling composition, process for its production and article treated therewith
    • 防污组合物,其生产方法和用其处理的物品
    • US08507580B2
    • 2013-08-13
    • US12913900
    • 2010-10-28
    • Hiroyuki HaraShuichiro SugimotoTakao Hirono
    • Hiroyuki HaraShuichiro SugimotoTakao Hirono
    • C08L27/12C08K5/05
    • D06M15/277C08F214/06C08F220/22C08F220/58C08F222/14C08F2220/1891
    • To provide a process for efficiently producing a fluorine type antifouling composition employing a short chain Rf group, which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has a good soil release property (SR property).A process for producing an antifouling composition, which comprises a step of subjecting monomer components (Z) comprising from 30 to 80 mass % of a monomer (a) having a polyfluoroalkyl group in which the number of carbon atoms to which fluorine atoms are bonded is from 4 to 6, and from 20 to 70 mass % of a monomer (b) having no polyfluoroalkyl group and having a hydrophilic group, to solution polymerization in a volatile organic solvent having a boiling point of at most 100° C. in the presence of a surfactant (c) comprising an ethylene oxide adduct of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to form a fluorocopolymer (A), and a step of volatilizing the volatile organic solvent after the solution polymerization and adding an aqueous medium to form an aqueous dispersion.
    • 为了提供一种能够有效地制造使用短链Rf基的氟型防污组合物的方法,其可以基本上不含挥发性有机溶剂的水性分散体的形式制备并且具有良好的去污性能(SR性能)。 一种防污组合物的制造方法,其特征在于,包括含有30〜80质量%的具有与氟原子键合的碳原子数的多氟烷基的单体(a)的单体成分(Z)的工序是 4〜6质量%,20〜70质量%的不具有多氟烷基且具有亲水性基团的单体(b)在沸点为100℃以下的挥发性有机溶剂中进行溶液聚合, 包含2,4,7,9-四甲基-5-癸炔-4,7-二醇的环氧乙烷加合物以形成含氟共聚物(A)的表面活性剂(c),以及在溶液之后使挥发性有机溶剂挥发的步骤 聚合并加入水性介质以形成水分散体。
    • 80. 发明申请
    • RELOADABLE FINISHES FOR TEXTILES AND FORMULATIONS FOR LOADING SUCH FINISHES
    • 用于装载这种表面的纺织品和配方的可靠的表面处理
    • US20130102943A1
    • 2013-04-25
    • US13394539
    • 2010-08-25
    • Theo GauppRoland LottenbachHans-Jürgen HübnerSabine Dabzer
    • Uwe HolzdörferTheo GauppRoland LottenbachHans-Jürgen Hübner
    • A61K9/107D06M15/29A61F13/00
    • A61K9/107A61F13/00C08F220/28C08F2220/281C08F2220/286D06M13/46D06M15/263D06M15/27D06M15/29D06M23/00Y10T442/20C08F2220/1858C08F220/58C08F2220/585C08F2220/346
    • A polymer compound according to the invention comprises an acrylic acid copolymer composed of acrylic acid derivatives and/or methacrylic acid derivatives, containing: a) at least one acrylic acid derivative and/or methacrylic acid derivative substituted with a sulfonic acid group; b) at least one hydrophilically substituted acrylic acid derivative and/or methacrylic acid derivative; c) at least one lipophilically substituted acrylic acid derivative and/or methacrylic acid derivative; and d) at least one acrylic acid derivative and/or methacrylic acid derivative which acts as a crosslinking agent. In the method according to the invention for loading textile products with a low-molecular compound, a) a textile product is provided with a finishing layer whose accessible surface has a negative charge; and b) the textile product is brought together with an emulsion or active substance solution, for example by immersing the textile product in the emulsion/solution, or by spraying the emulsion/solution on the textile product. At least one low-molecular compound is contained in the dispersed phase of the emulsion, and the surface of the particles of the dispersed phase has a positive charge.
    • 根据本发明的高分子化合物包含由丙烯酸衍生物和/或甲基丙烯酸衍生物组成的丙烯酸共聚物,其包含:a)至少一种被磺酸基取代的丙烯酸衍生物和/或甲基丙烯酸衍生物; b)至少一种亲水取代的丙烯酸衍生物和/或甲基丙烯酸衍生物; c)至少一种亲油取代的丙烯酸衍生物和/或甲基丙烯酸衍生物; 和d)作为交联剂的至少一种丙烯酸衍生物和/或甲基丙烯酸衍生物。 在根据本发明的用于用低分子化合物装载纺织品的方法中,a)纺织产品具有可接触表面具有负电荷的整理层; 和b)将纺织产品与乳液或活性物质溶液接合,例如通过将纺织产品浸入乳液/溶液中,或通过将乳液/溶液喷洒在纺织品上。 在乳液的分散相中含有至少一种低分子化合物,分散相颗粒的表面具有正电荷。