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    • 73. 发明申请
    • Method of and apparatus for producing sub-critical water decomposition products
    • 生产亚临界水分解产物的方法和设备
    • US20070160524A1
    • 2007-07-12
    • US10589331
    • 2005-02-14
    • Hiroyuki Yoshida
    • Hiroyuki Yoshida
    • C01B5/00
    • C02F11/08A62D2203/10B01J3/008B09B3/00Y02E50/30
    • [Problems] A method of and an apparatus for continuous sub-critical water decomposition treatment for material to be processed containing solid matter are provided, which are capable of controlling decomposition reaction of the material to be processed and suitable for large-scale operations. The method and the apparatus are also capable of minimizing equipment costs and selectively producing desired useful substances at high yield rates. [Means to Solve the Problems] Material to be processed is grinded in advance into particles, which are mixed with water to prepare slurry. The slurry is sent to a compressing means (1) through a pipe and is compressed. Next, the compressed slurry is sent to a heating means 2 and heated, and is brought into a sub-critical state. The slurry in a sub-critical condition is introduced through an inlet (8) into a bottom part of a reactor (3). In the reactor (3) a fixed bed, a fluidized bed, and a sub-critical water dissolution part are formed in that order from the bottom. One(s) of outlets (101) to 106 provided at top and side portions of the reactor 3 is/are selected so that the sub-critical water dissolution part is taken out therethrough, whereby the residence time of the sub-critical water is adjusted and thus the reaction time of sub-critical water decomposition of the material to be processed is adjusted.
    • [问题]提供了含有固体物质的待处理材料的连续亚临界水分解处理的方法和装置,其能够控制待处理材料的分解反应并适合于大规模操作。 该方法和装置还能够最小化设备成本并以高产率选择性地生产所需的有用物质。 [解决问题的方法]将待处理的材料预先研磨成与水混合以制备浆料的颗粒。 将浆料通过管道送到压缩装置(1)并被压缩。 接下来,将压缩的浆料送到加热装置2并加热并进入亚临界状态。 处于亚临界状态的浆料通过入口(8)引入反应器(3)的底部。 在反应器(3)中,从底部依次形成固定床,流化床和亚临界水溶解部分。 选择设置在反应器3的顶部和侧部的一个或多个出口(101)至106,使得亚临界水溶解部分被从其中取出,由此亚临界水的停留时间为 进行调整,调整待处理材料的亚临界水分解反应时间。
    • 76. 发明申请
    • Method for starting up a system for treating waste by hydrothermal oxidation
    • 通过水热氧化启动废物处理系统的方法
    • US20040238460A1
    • 2004-12-02
    • US10483058
    • 2004-06-30
    • Francois CansellManuel Bottreau
    • C02F001/68
    • C02F1/72C02F11/08C02F2303/16Y02E20/12
    • The invention relates to a method for starting up a system for oxidating organic bodies. Said system comprises a tubular body (10) wherein an aqueous body is injected into the inlet (12) thereof at a pressure P1, said tubular body (10) having a first zone (16) extending the inlet (12) thereof, a second zone (18) into which an oxidating compound can be injected into the output (14) thereof. The inventive method comprises the following steps: a first amount of thermal energy Q1 is provided in the first zone (16), said amount of thermal energy being able to raise the temperature of the liquid flowing through said tubular body (10) from an initial temperature to a higher temperature T1; and a determined amount of a combustible mixture which can react at said intermediate temperature T1 in order to provide an amount of thermal energy Q2 bringing the temperature of said liquid to a reaction temperature is injected.
    • 本发明涉及一种启动用于氧化有机物体的系统的方法。 所述系统包括管状体(10),其中水分体以压力P1注入其入口(12),所述管状体(10)具有延伸入口(12)的第一区域(16),第二区域 区域(18),其中可以将氧化化合物注入其中的输出(14)中。 本发明的方法包括以下步骤:在第一区域(16)中设置第一量的热能Q1,所述热能量能够将流过所述管状体(10)的液体的温度从初始 温度到更高的温度T1; 以及确定量的可在所述中间温度T1反应的可燃混合物,以便提供使所述液体的温度达到反应温度的一定量的热能Q2。
    • 77. 发明申请
    • Method for removing metal from wastewater
    • 从废水中去除金属的方法
    • US20040217062A1
    • 2004-11-04
    • US10854254
    • 2004-05-27
    • Shuhei YadaKenji TakasakiYasushi OgawaYoshiro Suzuki
    • C02F001/52
    • C02F9/00C02F1/005C02F1/12C02F1/38C02F1/44C02F1/52C02F1/56C02F1/66C02F1/72C02F1/74C02F11/08C02F2101/20C02F2103/36C02F2301/08Y10S210/912
    • An object of the present invention is to provide a method for efficiently removing a metal from wastewater formed by subjecting the liquid waste to wet combustion treatment or wet oxidation treatment, said liquid waste resulting from an acrylic acid production process. Provided is a method for removing a metal from wastewater formed by subjecting at least a part of liquid waste to wet combustion treatment or wet oxidation treatment, said liquid waste resulting from an acrylic acid production process involving the steps of forming acrylic acid through catalytic vapor phase oxidation of at least one of propane, propylene, and acrolein, and purifying the acrylic acid through distillation, wherein the method comprises the steps of: (a) removing a solid content from the wastewater; (b) removing carbonate ions and carbonate salts from the treated liquid obtained by the step (a); and (c) removing a metal from the treated liquid from the step (b).
    • 本发明的目的是提供一种从废水进行湿式燃烧处理或湿式氧化处理所形成的废水中有效地除去金属的方法,所述废液由丙烯酸生产过程产生。 提供一种从废水中除去金属的方法,所述废水通过使至少一部分废液进行湿式燃烧处理或湿式氧化处理而形成,所述废液是由丙烯酸生产方法产生的,包括通过催化气相形成丙烯酸的步骤 丙烷,丙烯和丙烯醛中的至少一种的氧化,并通过蒸馏纯化丙烯酸,其中所述方法包括以下步骤:(a)从废水中除去固体含量; (b)从由步骤(a)获得的处理液中除去碳酸根离子和碳酸盐; 和(c)从步骤(b)从经处理的液体中除去金属。
    • 80. 发明申请
    • Hydrothermal treatment system and method
    • 水热处理系统及方法
    • US20030057164A1
    • 2003-03-27
    • US10282854
    • 2002-10-29
    • William Tracy Wofford IIIJames Walton GriffithRichard Wayne HumphriesJustin Wade Lawrence
    • C02F001/72
    • C02F11/08B01J3/008B01J19/26B01J2219/00006C02F1/38C02F1/72C02F1/727
    • In addition to the contactor and reactor arrangement (10, 83), a hydrothermal treatment system (60) includes an effluent stream splitting arrangement (86) for receiving hydrothermal reaction effluent and splitting this effluent to produce two separate effluent streams. These separated effluent streams are used to heat at least a water stream and first reactant material stream before these streams are injected into the contactor and reactor arrangement (10, 83). A first split effluent heat exchange arrangement (81) places one split effluent stream in a heat exchange relationship with the water input to the contactor and reactor arrangement (10, 83). A second split effluent heat exchange arrangement (79, 80) places the other split effluent stream in a heat exchange relationship with both the first reactant material and the water input to the contactor and reactor arrangement (10, 83).
    • 除了接触器和反应器装置(10,83)之外,水热处理系统(60)包括用于接收水热反应流出物并将该流出物分离以产生两个单独的流出物流的流出物流分流装置(86)。 这些分离的流出物流用于在将这些流注入到接触器和反应器装置(10,83)中之前加热至少一个水流和第一反应物料流。 第一分流流出物热交换装置(81)将一个分流流出物流与输入到接触器和反应器装置(10,83)的水进行热交换关系。 第二分流流出物热交换装置(79,80)将另一分离流出物流与第一反应物料和输入到接触器和反应器装置(10,83)的水进行热交换关系。