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71. 发明授权

USB449837I5 失效
公开(公告)号：USB449837I5
公开(公告)日：1976-03-02
申请号：US44983774
申请日：1974-03-11
IPC分类号： B01J27/24 , B01J31/02 , B01J31/14 , B01J37/22
CPC分类号： B01J37/22 , B01J27/24 , B01J31/0231 , B01J31/0252 , B01J31/143 , B01J2231/323

72. 发明授权

US3848053A Alkyl aluminum disposal method 失效
标题翻译： ALKYL铝处理方法
公开(公告)号：US3848053A
公开(公告)日：1974-11-12
申请号：US38272673
申请日：1973-07-26
申请人： ETHYL CORP
发明人： GOVERNALE L
IPC分类号： B01J31/40 , C01F7/16 , C01F7/36 , C01F7/04
CPC分类号： B01J31/143 , B01J27/10 , B01J31/0252 , B01J31/26 , B01J31/4015 , B01J2231/12 , C01F7/164 , C01F7/36 , Y02P20/584
摘要： 1. A METHOD OF RECOVERING ALUMINUM FROM A COMPOSITION CONTAINING AN ALKYL ALUMINUM COMPOUND, SAID METHOD COMPRISING REACTING SAID COMPOSITION WITH AN ANILINE TO FORM AN ALUMINUM ANILIDE, HYDROLYZING SAID ALUMINUM ANILIDE WITH AQUEOUS BASE, AND REACTING THE HYDROLYZED PRODUCT WITH AN ALKALINE EARTH METAL BASE TO PRECIPITATE AN ALKALINE EARTH METAL ALUMINATE IN A RECOVERABLE FORM.

73. 发明授权

US3124621A Isomerization of cyclooctadiene 失效
公开(公告)号：US3124621A
公开(公告)日：1964-03-10
申请号：US3124621D
IPC分类号： B01J31/02 , C07C5/25
CPC分类号： B01J31/0252 , B01J31/0237 , B01J2231/52 , C07C5/2562 , C07C13/263

74. 发明授权

US09050587B2 Catalyst composition and process for preparing linear alpha-olefins 有权
标题翻译：制备线性α-烯烃的催化剂组合物和方法
公开(公告)号：US09050587B2
公开(公告)日：2015-06-09
申请号：US12734982
申请日：2008-11-11
申请人： Vugar Aliyev , Fuad Mosa , Mohammed Al-Hazmi
发明人： Vugar Aliyev , Fuad Mosa , Mohammed Al-Hazmi
IPC分类号： B01J31/02 , C07C2/02 , B01J31/04 , B01J31/14 , B01J31/22 , B01J31/38 , C07C2/30 , C07C2/32 , B01J27/135
CPC分类号： B01J31/04 , B01J27/135 , B01J31/0212 , B01J31/0252 , B01J31/143 , B01J31/2208 , B01J31/38 , B01J2231/20 , B01J2531/31 , B01J2531/48 , C07C2/30 , C07C2/32 , C07C2531/14 , C07C2531/22 , C07C11/02
摘要： The present invention relates to a catalyst composition for the oligomerization of ethylene, comprising a transition metal compound of the general formula MXm(OR′)4-m or MXm(OOCR′)4-m, wherein R′ is an alkyl, alkenyl, aryl, aralkyl or cycloalkyl group, X is chlorine or bromine and m is from 0 to 4 and a reaction product of an organoaluminium compound and a cyclic amide, as well as to a process for preparing linear alpha-olefins utilizing this catalyst composition.
摘要翻译：本发明涉及用于乙烯低聚的催化剂组合物，其包含通式为MXm（OR'）4-m或MXm（OOCR'）4-m的过渡金属化合物，其中R'为烷基，链烯基，芳基，芳烷基或环烷基，X为氯或溴，m为0至4，有机铝化合物与环状酰胺的反应产物，以及利用该催化剂组合物制备线型α-烯烃的方法。

75. 发明授权

US08840856B2 Method for producing imidic acid salt 有权
标题翻译：生产酰亚胺酸盐的方法
公开(公告)号：US08840856B2
公开(公告)日：2014-09-23
申请号：US13322782
申请日：2010-06-01
申请人： Takayoshi Morinaka , Tsutomu Nanmyo
发明人： Takayoshi Morinaka , Tsutomu Nanmyo
IPC分类号： C01B25/10 , C01B21/097 , C01B21/093 , C01B21/086 , B01J31/02
CPC分类号： C01B21/086 , B01J31/0245 , B01J31/0252 , C01B21/093 , C01B21/0975
摘要： To provide an imide salt represented by the formula wherein, R represents a halosulfonyl group (—SO2X1 where X1 is a halogen such as fluorine, chlorine, bromine and iodine) or dihalophosphoryl group (—POX2X3 where X2 and X3 are the same or different halogens such as fluorine, chlorine, bromine and iodine), and M represents an alkali metal; with high selectivity and high efficiency by using a low-cost starting material. In the production of an imide salt, an alkali metal fluoride, a sulfuryl halide or phosphoryl halide, and ammonia or an ammonium salt are reacted. According to this method, a desired imide salt can be produced with high yield, while greatly suppressing the production of a by-product.
摘要翻译：提供由下式表示的酰亚胺盐：其中，R表示卤代磺酰基（-SO2X1，其中X1是氟，氯，溴和碘等卤素）或二卤代磷酰基（-POX2X3，其中X2和X3是相同或不同的卤素例如氟，氯，溴和碘），M表示碱金属; 通过使用低成本起始材料，具有高选择性和高效率。在制备酰亚胺盐时，使碱金属氟化物，硫酰卤或磷酰卤，以及氨或铵盐反应。根据该方法，可以高产率地制造所需的酰亚胺盐，同时大大抑制副产物的生成。

76. 发明申请

US20130237708A1 Optically Active Cyclic Alcohol Compound And Method For Preparing The Same 有权
标题翻译：光学活性环醇化合物及其制备方法
公开(公告)号：US20130237708A1
公开(公告)日：2013-09-12
申请号：US13747376
申请日：2013-01-22
申请人： Masaki Okamoto , Akira Sakuragi , Yoshikazu Mori , Muneki Kishida , Takanori Higashijima
发明人： Masaki Okamoto , Akira Sakuragi , Yoshikazu Mori , Muneki Kishida , Takanori Higashijima
IPC分类号： C07D215/233 , C07D401/04
CPC分类号： C07D215/233 , B01J31/0252 , B01J31/146 , B01J31/1805 , B01J31/2295 , B01J2231/64 , B01J2231/643 , B01J2531/821 , C07B53/00 , C07D215/22 , C07D401/04 , Y02P20/55
摘要： The present invention relates to a method for preparing an optically active cyclic alcohol compound represented by general formula [I]: [wherein R represents a hydrogen atom or a protecting group for amino group, and * represents an asymmetric carbon atom.] which comprises a step of subjecting a cyclic ketone compound represented by general formula [II]: [wherein R has the same meaning as defined above.] to asymmetric reduction (A) in the presence of an optically active oxazaborolidine compound and a boron hydride compound, or (B) in the presence of an asymmetric transition metal complex obtained from a transition metal compound and an asymmetric ligand and a hydrogen donor, and relates to said compound.
摘要翻译：本发明涉及一种由通式[I]表示的光学活性环状醇化合物的制备方法：[其中R表示氢原子或氨基保护基，*表示不对称碳原子]，其包含在光学活性的恶唑硼烷化合物和硼氢化合物的存在下，将不饱和还原（A）进行不饱和还原（A）的步骤：（其中R具有与上述定义相同的含义） B）在由过渡金属化合物和不对称配体和氢供体获得的不对称过渡金属络合物的存在下，涉及所述化合物。

77. 发明申请

US20120316357A1 Method for Producing Diaryl Carbonate 有权
标题翻译：碳酸二芳基酯的制备方法
公开(公告)号：US20120316357A1
公开(公告)日：2012-12-13
申请号：US13579649
申请日：2011-02-23
申请人： Budianto Nishiyama , Nobuhisa Miyake
发明人： Budianto Nishiyama , Nobuhisa Miyake
IPC分类号： C07C68/06
CPC分类号： B01J31/0214 , B01J31/0252 , B01J2531/42 , B01J2531/46 , C07C68/06 , Y02P20/582 , C07C69/96
摘要： The present invention provides a method for continuously producing a diaryl carbonate stably for a long time with high productivity. The method for producing a diaryl carbonate according to the present invention comprises a step (1) of obtaining an alkylaryl carbonate; a step (2) of obtaining a reaction product from the alkylaryl carbonate; a step (3) of separating the diaryl carbonate and a high boiling component from the reaction product; and a step (4) of recycling the high boiling component into the steps (1) and/or (2), wherein the high boiling component recycled in the step (4) includes a particular compound, and the particular compound satisfies a particular condition.
摘要翻译：本发明提供一种以高生产率长时间稳定连续生产碳酸二芳基酯的方法。根据本发明的制备碳酸二芳基酯的方法包括获得碳酸烷基芳基酯的步骤（1）从碳酸烷基芳基酯获得反应产物的步骤（2）; 从反应产物中分离碳酸二芳酯和高沸点组分的步骤（3）; 以及将高沸点组分再循环到步骤（1）和/或（2）中的步骤（4），其中在步骤（4）中再循环的高沸点组分包括特定的化合物，特定化合物满足特定条件。

78. 发明申请

US20110224431A1 Triazolium Carbene Catalysts and Stereoselective Bond Forming Reactions Thereof 审中-公开
标题翻译：三唑鎓碳烯催化剂和立体选择性键形成反应
公开(公告)号：US20110224431A1
公开(公告)日：2011-09-15
申请号：US13020693
申请日：2011-02-03
申请人： Tomislav Rovis , Harit U. Vora
发明人： Tomislav Rovis , Harit U. Vora
IPC分类号： C07D498/04 , C07D203/06 , C07D303/14 , C07C51/00 , B01J31/18
CPC分类号： B01J31/0271 , B01J31/0231 , B01J31/0252 , B01J31/0284 , B01J31/0285 , B01J2231/64 , B01J2231/645 , C07B41/08 , C07C51/16 , C07D333/24 , C07D498/04
摘要： Provided herein are triazolium carbine catalysts useful for asymmetric hydration, fluorination, and deuteration, and processes for their preparation. Also provided are synthetic reactions in which these catalysts are used, in particular, in stereoselective formation of carbon-chlorine, carbon-hydrogen, carbon-fluorine, and carbon-deuterium bonds.
摘要翻译：本文提供了可用于不对称水合，氟化和氘化的三唑鎓卡宾催化剂及其制备方法。还提供了使用这些催化剂的合成反应，特别是在碳 - 氯，碳 - 氢，碳 - 氟和碳 - 氘键的立体选择性形成中。

79. 发明申请

US20110054130A1 CATALYST COMPOSITION AND PROCESS FOR PREPARING LINEAR ALPHA-OLEFINS 有权
标题翻译：催化剂组合物和制备线性ALPHA-烯烃的方法
公开(公告)号：US20110054130A1
公开(公告)日：2011-03-03
申请号：US12734982
申请日：2008-11-11
申请人： Vugar Aliyev , Fuad Mosa , Mohammed Ali-Hazmi
发明人： Vugar Aliyev , Fuad Mosa , Mohammed Ali-Hazmi
IPC分类号： C08F4/42 , B01J31/14
CPC分类号： B01J31/04 , B01J27/135 , B01J31/0212 , B01J31/0252 , B01J31/143 , B01J31/2208 , B01J31/38 , B01J2231/20 , B01J2531/31 , B01J2531/48 , C07C2/30 , C07C2/32 , C07C2531/14 , C07C2531/22 , C07C11/02
摘要： The present invention relates to a catalyst composition for the oligomerization of ethylene, comprising a transition metal compound of the general formula MXm, (OR′)4-m or MXm(OOCR′)4-m, wherein R′ is an alkyl, alkenyl, aryl, aralkyl or cycloalkyl group, X is chlorine or bromine and m is from 0 to 4 and a reaction product of an organoaluminium compound and a cyclic amide, as well as to a process for preparing linear alpha-olefins utilizing this catalyst composition.
摘要翻译：本发明涉及一种用于乙烯低聚的催化剂组合物，其包含通式MXm，（OR'）4-m或MXm（OOCR'）4-m的过渡金属化合物，其中R'是烷基，烯基芳基，芳烷基或环烷基，X为氯或溴，m为0-4，有机铝化合物与环状酰胺的反应产物，以及利用该催化剂组合物制备线性α-烯烃的方法。

80. 发明授权

US07692046B2 Heterogeneous arylalkyl oxidation promoter 失效
标题翻译：异构芳烷基氧化促进剂
公开(公告)号：US07692046B2
公开(公告)日：2010-04-06
申请号：US11821020
申请日：2007-06-21
申请人： Matthew W. Holtcamp , Renuka N. Ganesh , Tan-Jen Chen , Jihad M. Dakka
发明人： Matthew W. Holtcamp , Renuka N. Ganesh , Tan-Jen Chen , Jihad M. Dakka
IPC分类号： C07C409/00
CPC分类号： B01J23/745 , B01J31/0211 , B01J31/0252 , B01J35/0033 , B01J37/0203 , B01J2231/70 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , C07C409/08
摘要： A promoter can have utility in selective heterogeneous oxidation of arylalkyl hydrocarbons such as, for example, cyclohexyl benzene and/or sec-butyl benzene to form hydroperoxides. The promoter can include the product of contacting a solid support comprising a metal oxide surface and an iron compound. The solid support can include, for example, titanium dioxide and/or an iron oxide such as magnetite and can have magnetic susceptibility. A method for the oxidation of arylalkyl hydrocarbons to form hydroperoxides can include contacting 16 an arylalkyl hydrocarbon with oxygen in the presence of the promoter under catalytic oxidation conditions to form arylalkyl hydroperoxide, which can then be converted to phenol via cleavage 26. The method can include recovery 22 of the promoter from the arylalkyl hydroperoxide and can further include recycling the recovered promoter to the contacting 16. Where the solid support has magnetic susceptibility, the recovery 22 can include magnetic separation of the promoter.
摘要翻译：助催化剂可用于芳基烷基烃例如环己基苯和/或仲丁基苯的选择性异相氧化以形成氢过氧化物。助催化剂可以包括使包含金属氧化物表面和铁化合物的固体载体接触的产物。固体支持体可以包括例如二氧化钛和/或氧化铁如磁铁矿，并且可以具有磁化率。用于氧化芳基烷基烃以形成氢过氧化物的方法可以包括在催化氧化条件下在助催化剂存在下使芳烷基烃与氧接触，形成芳基烷基氢过氧化物，然后可通过裂解将其转化为苯酚。该方法可包括从芳基烷基氢过氧化物中回收22个启动子，并且可以进一步包括将回收的促进剂再循环到接触16.当固体支持物具有磁化率时，回收22可以包括促进剂的磁性分离。

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