会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 75. 发明授权
    • Grafting, phase-inversion and cross-linking controlled multi-stage bulk
process for making ABS graft copolymers
    • 接枝,相转化和交联控制多级体积法制备ABS接枝共聚物
    • US5414045A
    • 1995-05-09
    • US165766
    • 1993-12-10
    • Chen-Youn SueRobert KochJohn E. PaceGregory R. Prince
    • Chen-Youn SueRobert KochJohn E. PaceGregory R. Prince
    • C08F2/00B01J19/18C08F2/02C08F279/00C08F279/04C08L25/12C08L55/02C08L51/04
    • B01J19/1862C08L55/02B01J2219/00159B01J2219/00168B01J2219/00184
    • A method is provided for continuous mass polymerization of acrylonitrile-butadiene-styrene type thermoplastics. The method involves charging a liquid feed comprising a vinylidene aromatic monomer, an unsaturated vinyl nitrile monomer and a synthetic butadiene polymer dissolved therein into a grafting reactor to prereact the liquid mass to form grafted rubber continuous phase polymeric product. The product from the grafting reactor is then charged to a phase inversion reactor where free rigid copolymer in monomer is the only continuous phase, and where dispersed particles of grafted rubber with occluded rigid copolymer and monomer are immediately formed from the product of the grafting reactor. The second polymerization product, which is coming out from the phase inversion reactor, is then charged to a finishing reactor wherein the material is further polymerized to form a third polymerization product which then can be devolatilized to provide a final thermoplastic composition. The process of the present invention provides unique capacity and flexibility in controlling and adjusting rubber grafting and rubber particle morphology. Process conditions can be controlled to produce a high gloss or a low gloss resin product.
    • 提供了用于丙烯腈 - 丁二烯 - 苯乙烯型热塑性塑料的连续质量聚合的方法。 该方法包括将包含亚乙烯基芳族单体,不饱和乙烯基腈单体和溶解在其中的合成丁二烯聚合物的液体进料装入接枝反应器中以预先反应液体物质以形成接枝橡胶连续相聚合物。 然后将来自接枝反应器的产物加入到相转化反应器中,其中单体中的游离刚性共聚物是唯一的连续相,并且其中由接枝反应器的产物立即形成具有闭塞刚性共聚物和单体的接枝橡胶的分散颗粒。 然后将从相转化反应器出来的第二聚合产物装入精制反应器中,其中进一步聚合该材料以形成第三聚合产物,然后其可以脱挥发分以提供最终的热塑性组合物。 本发明的方法在控制和调节橡胶接枝和橡胶颗粒形态方面提供了独特的能力和灵活性。 可以控制工艺条件以产生高光泽或低光泽的树脂产品。
    • 76. 发明授权
    • Process for the continuous preparation of encapsulated toner
    • 用于连续制备包封的调色剂的方法
    • US5264315A
    • 1993-11-23
    • US871156
    • 1992-04-20
    • Hock S. TanHadi K. MahabadiJoseph D. Wright
    • Hock S. TanHadi K. MahabadiJoseph D. Wright
    • B01J13/04B01J13/14B01J19/18G03G9/08G03G9/093
    • B01J19/1862G03G9/09392B01J2219/00099
    • A process for the continuous preparation of an encapsulated toner comprised of a core comprised of polymer and pigment encapsulated within a polymer shell, which process comprises continuously separately feeding an oil phase containing core monomers, oil soluble shell monomers and pigment and an aqueous phase containing surfactant into a continuous flowthrough mixing tank; homogenizing the aforementioned two phases to enable small oil droplets with an average diameter of from between about 3 to about 25 microns; overflowing the resulting droplets to at least one continuously stirred tank reactor while simultaneously feeding water soluble shell monomer to said stirred reactor to effect interfacial polymerization thereby causing shell formation; and thereafter allowing the encapsulated droplets to flow into a reactor or reactors and heating the reactor or reactors to effect free radical polymerization of the core monomers, followed by cooling, and isolating the said encapsulated toner.
    • 用于连续制备包封的调色剂的方法包括由包封在聚合物外壳内的聚合物和颜料组成的芯,该方法包括连续分别进料含有核心单体,油溶性壳单体和颜料的油相和含水相的表面活性剂 进入连续流通的混合罐; 均化上述两相以使平均直径为约3至约25微米的小油滴; 将所得液滴溢流到至少一个连续搅拌的罐式反应器中,同时将水溶性壳单体加入到所述搅拌反应器中以进行界面聚合从而导致壳形成; 然后允许包封的液滴流入反应器或反应器并加热反应器或反应器以实现核心单体的自由基聚合,然后冷却,并分离所述包封的调色剂。