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    • 73. 发明申请
    • Novel Steam Reformer Based Hydrogen Plant Scheme for Enhanced Carbon Dioxide Recovery
    • 新型蒸汽重整器基于增强二氧化碳回收的氢气方案
    • US20100037521A1
    • 2010-02-18
    • US12267641
    • 2008-11-10
    • Tarun D. VakilUlrich Wolf
    • Tarun D. VakilUlrich Wolf
    • C01B3/32
    • C01B3/382C01B3/384C01B3/48C01B3/52C01B3/56C01B2203/0233C01B2203/0283C01B2203/0288C01B2203/0405C01B2203/0415C01B2203/043C01B2203/0475C01B2203/141C01B2203/146C01B2203/147Y02C10/04Y02P20/129Y02P30/30
    • A novel steam reformer unit design, a novel hydrogen PSA unit design, a novel hydrogen/nitrogen enrichment unit design, and novel processing scheme application are presented. The result of these innovations results in re-allocating most of the total hydrogen plant CO2 emissions load to high pressure syngas stream exiting the water gas shift reactor while minimizing the CO2 emissions load from the reformer furnace flue gas. As compared to the conventional 60/40 split of total CO2 emissions in syngas/flue gas streams for steam reformer based conventional hydrogen plant designs, the present invention results in 85/15 or better CO2 split. This will permit about 85% or better of the total CO2 emissions load to be captured from the syngas stream, using the conventional, well proven and cost effective amine scrubbing technology. Such 85% or better CO2 capture is much greater than the 55% to 60% maximum possible using conventional steam reformer based hydrogen plant technology. As CO2 recovery from high pressure syngas stream is much easier and cost effective as compared to that from low pressure reformer furnace flue gases, a major cost benefit for equivalent CO2 recovery results with the present invention.
    • 提出了一种新型的蒸汽重整单元设计,新型氢PSA单元设计,新型氢/氮浓缩单元设计和新型加工方案应用。 这些创新的结果导致将氢气厂二氧化碳总排放量的大部分重新分配到离开水煤气变换反应器的高压合成气流中,同时最小化来自重整炉炉烟气的二氧化碳排放负荷。 与常规氢气设计设计中用于基于蒸汽重整器的合成气/烟气流中总二氧化碳排放量的常规60/40分解相比,本发明导致85/15或更好的二氧化碳分离。 这将允许从合成气流中捕获的总二氧化碳排放负荷约85%或更好,使用常规的,经过验证的和具有成本效益的胺洗涤技术。 使用常规的基于蒸汽重整器的氢气技术,这种85%或更好的二氧化碳捕获量远大于最大可能的55%至60%。 由于与来自低压重整炉烟道气相比,来自高压合成气流的二氧化碳回收更容易和成本有效,所以本发明的等效二氧化碳回收的主要成本优势。
    • 74. 发明授权
    • Method for the production of organic carbonates
    • 生产有机碳酸酯的方法
    • US07598410B2
    • 2009-10-06
    • US10571479
    • 2004-07-16
    • Henning BucholdJürgen EberhardtUlrich WagnerHans-Jörg Wölk
    • Henning BucholdJürgen EberhardtUlrich WagnerHans-Jörg Wölk
    • C07C69/96
    • C07C68/06C07C68/00C07C69/96
    • The invention relates to a method for the production of monomer organic carbonates from a mixture of organic carbonates and carbamates which are obtained by reacting urea, substituted urea, a salt or ester of carbamide acid or one of the N-substituted derivatives thereof with a polyalkylene glycol, polyester-polyol or a polyether-polyol of general formula (I), wherein R represents a linear or branched alkylene group having 2-12 carbon atoms and n represents a number between 2 and 20, or with a completely or partially hydrolysed polyvinyl alcohol of general formula (II), wherein R′ represents an alkyl group, an aryl group or an acyl group having 1-12 carbon atoms, p and q represent a number between 120, or with mixtures of said compounds in the presence of a catalyst facilitating the separation of ammonia and the ammonia becomes free or the amine is removed from the reaction mixture by means of a strip gas, whereby said mixture is reacted with an alcohol or a phenol whereby monomer carbonates are formed and polymer polyalcohols of formulae (I) or (II) are reformed.
    • 本发明涉及一种由有机碳酸酯和氨基甲酸酯的混合物制备单体有机碳酸酯的方法,其通过使脲,取代的脲,脲酰胺酸的盐或酯或其N-取代的衍生物之一与聚亚烷基 乙二醇,聚酯多元醇或通式(I)的聚醚多元醇,其中R表示具有2-12个碳原子的直链或支链亚烷基,n表示2至20的数,或具有完全或部分水解的聚乙烯 通式(II)的醇,其中R'表示烷基,芳基或具有1-12个碳原子的酰基,p和q表示120之间的数,或与所述化合物在存在下的 促进氨分离的催化剂变得游离,或者通过带状气体从反应混合物中除去胺,由此使所述混合物与醇或酚反应,由此使单体碳 形成式(I)或式(I)或(II)的聚合物多元醇)。
    • 76. 发明授权
    • Process and plant for the production of lower-molecular olefins
    • 用于生产低分子量烯烃的方法和装置
    • US09573863B2
    • 2017-02-21
    • US14006908
    • 2012-02-07
    • Gerhard BirkeHermann Bach
    • Gerhard BirkeHermann Bach
    • C07C1/20C07C2/86C07C4/06
    • C07C2/864C07C1/20C07C4/06C07C2529/40Y02P20/582Y02P30/42C07C11/04C07C11/06
    • In the production of low-molecular olefins, in particular of ethylene and propylene, an educt stream (O) containing at least one oxygenate and an educt stream (C) containing at least one C4+olefin are simultaneously converted in at least one identical reactor on an identical catalyst to obtain a product mixture (P) comprising low-molecular olefins and gasoline hydrocarbons. The ratio (V) of oxygenates in the educt stream (O) to C4+ olefins in the educt stream (C) here is 0.05 to 0.5 and is calculated according to the following formula: V = ∑ j ⁢ k oxygenate - j * n oxygenate - j ∑ i ⁢ k olefin - i * n olefin - i + ∑ j ⁢ k oxygenate - j * n oxygenate - j with: koxygenate-j: carbon number of the oxygenate j noxygenate-j: molar flow rate of the oxygenate j kolefin-i: carbon number of the olefin i nolefin-i: molar flow rate of the olefin i.
    • 在生产低分子量烯烃,特别是乙烯和丙烯的过程中,在至少一个相同的反应器中同时转化含有至少一种含氧化合物的流出物流(O)和含至少一种C4 +烯烃的流出物流(C) 相同的催化剂以获得包含低分子烯烃和汽油烃的产物混合物(P)。 在这里,流出物流(C)中的流出物(O)中的含氧化合物与C 4 +烯烃的比例(V)为0.05至0.5,并且根据以下公式计算:V =Σj?k氧化合物 - j * n含氧化合物 含氧化合物-j:含氧化合物j:含氧化合物的碳数j无氧素-j:含氧化合物j的摩尔流量 α-烯烃-I:烯烃的烯烃数量ilele-i:烯烃的摩尔流量i
    • 79. 发明申请
    • PROCESS AND PLANT FOR THE PRODUCTION OF LOW-MOLECULAR OLEFINS
    • 用于生产低分子油脂的方法和设备
    • US20140018593A1
    • 2014-01-16
    • US14006908
    • 2012-02-07
    • LURGI GMBH
    • Gerhard BirkeHermann Bach
    • C07C2/86
    • C07C2/864C07C1/20C07C4/06C07C2529/40Y02P20/582Y02P30/42C07C11/04C07C11/06
    • In the production of low-molecular olefins, in particular of ethylene and propylene, an educt stream (O) containing at least one oxygenate and an educt stream (C) containing at least one C4+ olefin are simultaneously converted in at least one identical reactor on an identical catalyst to obtain a product mixture (P) comprising low-molecular olefins and gasoline hydrocarbons. The ratio (V) of oxygenates in the educt stream (O) to C4+ olefins in the educt stream (C) here is 0.05 to 0.5 and is calculated according to the following formula: V = ∑ j  k oxygenate - j * n oxygenate - j ∑ i  k olefin - i * n olefin - i + ∑ j  k oxygenate - j * n oxygenate - j with: koxygenate-j: carbon number of the oxygenate j noxygenate-j: molar flow rate of the oxygenate j kolefin-i: carbon number of the olefin i nolefin-i: molar flow rate of the olefin i
    • 在生产低分子量烯烃,特别是乙烯和丙烯的过程中,在至少一个相同的反应器中同时转化含有至少一种含氧化合物的流出物流(O)和含至少一种C4 +烯烃的流出物流(C) 相同的催化剂以获得包含低分子烯烃和汽油烃的产物混合物(P)。 在这里,流出物流(C)中的流出物(O)中的含氧化合物与C 4 +烯烃的比例(V)为0.05至0.5,并且根据以下公式计算:V =Σj?k氧化合物 - j * n含氧化合物 含氧化合物-j:含氧化合物j:含氧化合物的碳数j无氧素-j:含氧化合物j的摩尔流量 α-烯烃-I:烯烃的烯烃数量ilele-i:烯烃的摩尔流量i