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71. 发明授权

US5401486A Preparation of essentially alkali-free titanium zeolites 失效
标题翻译：碱性无碱钛沸石的制备
公开(公告)号：US5401486A
公开(公告)日：1995-03-28
申请号：US164425
申请日：1993-12-08
申请人： Ulrich Mueller , Wolfgang Hoelderich
发明人： Ulrich Mueller , Wolfgang Hoelderich
IPC分类号： B01J29/89 , C01B37/00 , C07C249/04 , C01B33/34
CPC分类号： B01J29/89 , C01B37/005 , C07C249/04 , Y10S423/22
摘要： A process for preparing essentially alkali-free titanium silicate crystals having a zeolite structure, comprises reacting an SiO.sub.2 -containing mixture of water, a tetraalkylammonium compound, a titanium component and ammonia in the absence of a metal hydroxide or salt under hydrothermal conditions in a molar ratio of ammonia/tetraalkylammonium of from 3:1 to 200:1.
摘要翻译：基本上制备具有沸石结构的无碱钛硅酸盐晶体的方法，包括在水热条件下在不存在金属氢氧化物或盐的情况下使含有SiO 2的水，四烷基铵化合物，钛组分和氨的混合物在摩尔氨/四烷基铵的比例为3：1至200：1。

72. 发明授权

US5128307A Copper-containing catalyst for low temperature shift conversion 失效
标题翻译：含铜催化剂用于低温转化转化
公开(公告)号：US5128307A
公开(公告)日：1992-07-07
申请号：US649299
申请日：1991-01-30
申请人： Herbert Wanjek , Claus Witte , Michael J. Sprague , Matthias Irgang , Wolfgang Hoelderich , Wolf D. Mross
发明人： Herbert Wanjek , Claus Witte , Michael J. Sprague , Matthias Irgang , Wolfgang Hoelderich , Wolf D. Mross
IPC分类号： B01J23/72 , B01J23/80 , B01J35/10 , C01B3/16
CPC分类号： B01J37/031 , B01J23/72 , B01J23/80 , B01J35/1014 , B01J35/1019 , C01B3/16 , Y02P20/52
摘要： Copper-containing catalysts for low temperature shift conversion at from 150.degree. to 300.degree. C. and under from 10 to 40 bar, which additionally contain aluminum and zinc, if necessary in the form of the compounds or oxides and are prepared by coprecipitation, the copper-containing catalysts containing potassium and having a BET surface area adapted to the potassium content, and the potassium content being brought to 0.1-3.0% by weight at a BET surface of from 30 to 160 m.sup.2 /g, are used for the preparation of hydrogen and carbon dioxide from carbon monoxide and water.
摘要翻译：在150〜300℃，10〜40巴下进行低温转化转化的含铜催化剂，如果需要，还含有铝和锌，如果需要，可以以化合物或氧化物的形式，通过共沉淀制备含有钾的具有适合于钾含量的BET表面积的含铜催化剂和在BET表面积为30〜160m 2 / g的钾含量为0.1-3.0重量％用于制备来自一氧化碳和水的氢和二氧化碳。

73. 发明授权

US4960954A Preparation of enol ethers 失效
标题翻译：烯醇醚的制备
公开(公告)号：US4960954A
公开(公告)日：1990-10-02
申请号：US329007
申请日：1989-03-27
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer , Walter Himmele
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer , Walter Himmele
IPC分类号： C07C41/48 , C07C45/49 , C07C47/198 , C07C67/327
CPC分类号： C07C41/48 , C07C45/49 , C07C47/198 , C07C67/327 , Y02P20/582
摘要： Enol ethers of the general formula I ##STR1## are prepared by eliminating the radical R.sup.4 OH from acetals or ketals of the formula II ##STR2## where the substituents R.sup.1 and R.sup.2 are each independently of the other hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.8 -cycloalkenyl, unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted aryl or C.sub.7 -C.sub.16 aralkyl,R.sup.3 is --CR.sup.5 (OR.sup.4).sub.2, --COOR.sup.4 or --COR.sup.4,R.sup.4 is C.sub.1 -C.sub.20 -alkyl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl,R.sup.5 is hydrogen or C.sub.1 -C.sub.8 -alkyl,in a process which comprises performing the reaction in the presence of phosphoric acid and/or phosphates on a carrier material and/or phosphates and/or zeolites as catalysts.
摘要翻译：通式I（I）的烯醇醚通过从式II（II）的缩醛或缩酮中除去基团R 4 OH来制备，其中取代基R 1和R 2各自独立地为氢，C1- C 1 -C 8烷基，C 3 -C 8环烷基，C 3 -C 8 - 环烯基，未取代的或C 1 -C 4烷基取代的芳基或C 7 -C 16芳烷基，R 3是-CR 5（OR 4）2，-COOR 4或-COR 4， - 烷基，C 7 -C 20 - 烷基芳基或C 7 -C 20 - 芳烷基，R 5是氢或C 1 -C 8 - 烷基，其包括在载体材料上的磷酸和/或磷酸盐存在下进行反应和/或磷酸盐和/或沸石作为催化剂。

74. 发明授权

US4950763A Preparation of ketones 失效
标题翻译：酮的制备
公开(公告)号：US4950763A
公开(公告)日：1990-08-21
申请号：US381469
申请日：1989-07-18
申请人： Charles Schommer , Klaus Ebel , Toni Dockner , Matthias Irgang , Wolfgang Hoelderich , Harald Rust
发明人： Charles Schommer , Klaus Ebel , Toni Dockner , Matthias Irgang , Wolfgang Hoelderich , Harald Rust
IPC分类号： B01J21/06 , B01J23/04 , C07B61/00 , C07C45/00 , C07C45/48 , C07C45/74 , C07C49/04 , C07C49/76 , C07C49/792 , C07C67/00 , C07D213/50
CPC分类号： B01J23/04 , C07C45/48 , C07D213/50
摘要： Ketones of the general formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another are each alkyl, cycyloalkyl, arylalkyl, aryl or hetaryl, and one or more of the radicals R.sup.1 and R.sup.2 carry one or more hydrogen atoms on the .alpha.-carbon atom, are prepared by reacting two carboxylic acids of the general formulae (IIa/IIb), R.sup.1 --COOH (IIa) and R.sup.2 --COOH (IIb) or by reacting a carboxylic acid R.sup.1 --COOH (IIa) and a ketone ##STR2## or by reacting a mixture of IIa, IIb and Ib, in the gas phase in the presence of a catalyst, by a process in which a catalyst is used whose active material contains at least 50% by weight of titanium dioxide having a specific surface area greater than 10 m.sup.2 /g.0.
摘要翻译：其中R 1和R 2彼此独立地为烷基，氰基烷基，芳基烷基，芳基或杂芳基的通式（I）的酮，其中R 1和R 2中的一个或多个携带一个或多个氢原子通过使通式（IIa / IIb），R1-COOH（IIa）和R2-COOH（IIb）的两种羧酸反应或通过使羧酸R1-COOH（IIa）和酮（Ib）或IIa，IIb和Ib的混合物在气相中，在催化剂存在下，通过使用活性物质含有至少50重量％的催化剂的方法的比表面积大于10m 2 / g的二氧化钛。

75. 发明授权

US4943667A Preparation of phenylethanols 失效
标题翻译：苯乙醇的制备
公开(公告)号：US4943667A
公开(公告)日：1990-07-24
申请号：US296766
申请日：1989-01-13
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
IPC分类号： B01J27/18 , B01J29/04 , B01J29/85 , C07B61/00 , C07C27/00 , C07C29/10 , C07C29/132 , C07C29/56 , C07C33/20 , C07C33/22 , C07C67/00
CPC分类号： C07C29/132 , Y02P20/582
摘要： Phenylethanols of the formula ##STR1## where R is hydrogen, alkyl of from 1 to 4 carbon atoms, alkoxy of from 1 to 4 carbon atoms, fluorine, trifluoromethyl or trifluoromethoxy, are prepared by reacting epoxides of the formula ##STR2## where R is as defined above, in the presence of hydrogen over zeolites and/or phosphates, doped with hydrogenating metal as catalysts, preferably over zeolites of the pentasil type.
摘要翻译：通过使下式的环氧化物反应，其中R为氢，1-4个碳原子的烷基，1至4个碳原子的烷氧基，氟，三氟甲基或三氟甲氧基的苯基乙醇，其中R为在氢气存在下，在沸石和/或磷酸盐上，掺杂有氢化金属作为催化剂，优选在pentasil型沸石上。

76. 发明授权

US4929765A Preparation of phenylacetaldehydes 失效
标题翻译：苯乙醛的制备
公开(公告)号：US4929765A
公开(公告)日：1990-05-29
申请号：US274930
申请日：1988-11-22
申请人： Hubert Smuda , Wolfgang Hoelderich , Norbert Goetz , Hans-Gert Recker
发明人： Hubert Smuda , Wolfgang Hoelderich , Norbert Goetz , Hans-Gert Recker
IPC分类号： C07C45/51 , C07C45/52 , C07C45/54 , C07C45/58
CPC分类号： C07C45/52 , C07C45/512 , C07C45/513 , C07C45/54 , C07C45/58 , Y02P20/582
摘要： Phenylacetaldehydes of the general formula I ##STR1## where R.sup.1 to R.sup.5 are each independently of the others hydrogen, alkyl, alkoxy, halogen, haloalkyl, haloalkoxy or haloalkylthio, by catalytic rearrangement in the presence of a zeolite, are prepared by reacting an epoxy of the formula II or a phenylglycol of the formula III ##STR2## where Y and Z can be identical to or different from each other and are each hydroxyl, alkoxy, aryloxy or acyloxy, in the gas phase over a borosilicate zeolite catalyst at from 70.degree. to 200.degree. C. under reduced pressure.
摘要翻译：通过在沸石存在下通过催化重排，其中R 1至R 5各自独立地为氢，烷基，烷氧基，卤素，卤代烷基，卤代烷氧基或卤代烷硫基的通式I（I）的苯基乙醛通过使式II的环氧基或式III的苯基二醇其中Y和Z可以彼此相同或不同，并且各自为羟基，烷氧基，芳氧基或酰氧基，其中气相在硼硅酸盐沸石催化剂上在70〜200℃下减压。

77. 发明授权

US4925991A Preparation of dien-1-ols, 9-hydroxydodec-10-enyl 1-tert-butyl ether and use thereof as an intermediate for synthesizing 8,10-dodecadienol 失效
标题翻译：二烯-1-醇，9-羟基十二碳-10-烯基1-叔丁基醚的制备及其作为合成8,10-十二二烯醇的中间体的用途
公开(公告)号：US4925991A
公开(公告)日：1990-05-15
申请号：US235478
申请日：1988-08-24
申请人： Wolfgang Mackenroth , Wolfgang Hoelderich , Rainer Becker , Walter Seufert
发明人： Wolfgang Mackenroth , Wolfgang Hoelderich , Rainer Becker , Walter Seufert
IPC分类号： B01J27/02 , B01J27/16 , B01J27/18 , B01J27/182 , B01J29/85 , C07B61/00 , C07C27/00 , C07C29/10 , C07C29/60 , C07C33/02 , C07C41/00 , C07C43/178 , C07C67/00
CPC分类号： C07C43/178 , C07C29/10 , C07C29/60 , C07B2200/09 , Y02P20/55
摘要： Dien-1-ols of the general formula I ##STR1## where the radicals R.sup.1 to R.sup.7 are identical to or different from one another and each is hydrogen or straight-chain or branched alkyl or 1-12 carbon atoms and n is 1-14, are prepared by dehydrating a hydroxylalkenyl tert-butyl ether of the formula II ##STR2## in the presence of an acidic catalyst at elevated tempertures and essentially at the same time splitting off the tert-butyl protective group, as is 9-hydroxydodec-10-enyl 1-tert-butyl ether which is useful as an intermediate for synthesizing 8,10-dodecadienol.
摘要翻译：其中基团R 1至R 7彼此相同或不同的通式I（I）的二烯-1-醇，各自为氢或直链或支链烷基或1-12个碳原子，n为 1-14，通过在酸性催化剂的存在下在升高的温度下脱水式II II的羟基烯基叔丁基醚，并且基本上同时分离出叔丁基保护基，如是9-羟基十二碳-10-烯基1-叔丁基醚，其可用作合成8,10-十二二烯醇的中间体。

78. 发明授权

US4924000A Preparation of acylated imidazoles 失效
标题翻译：酰化咪唑的制备
公开(公告)号：US4924000A
公开(公告)日：1990-05-08
申请号：US321110
申请日：1989-03-09
申请人： Michael Hesse , Wolfgang Hoelderich , Toni Dockner , Hermann Koehler
发明人： Michael Hesse , Wolfgang Hoelderich , Toni Dockner , Hermann Koehler
IPC分类号： B01J21/00 , B01J21/04 , B01J21/06 , B01J21/08 , B01J23/20 , B01J27/18 , B01J29/04 , C07B61/00 , C07D233/54 , C07D233/64
CPC分类号： C07D233/64
摘要： Acylated imidazoles of the formula ##STR1## where R.sup.1 and R.sup.3 are each H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, R.sup.4 is H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, and R.sup.5 is alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl, alkylaryl or carboxyl, are prepared by reacting imidazoles of the formula ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, at least one of the radicals R.sup.1, R.sup.2 and R.sup.3 being hydrogen, and R.sup.4 is H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, with widely used acylating agents of the formula ##STR3## where R.sup.5 is as defined above and Y is halide, alkoxy, acyloxy or hydroxyl, in the presence of acidic metal oxides and/or phosphates, preferably in the gas phase.
摘要翻译：其中R 1和R 3各自为H，具有1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，R 4为H，1至12的烷基，碳原子，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，R5是1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基，烷基芳基或羧基，使式（Ia）的咪唑与R1，R2和R3各自为1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，基团R1，R2和 R3为氢，R4为H，1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，以及广泛使用的通式为“IMAGE”的酰化剂，其中R5如上定义在酸性金属氧化物和/或磷酸盐的存在下，优选在气相中，Y是卤化物，烷氧基，酰氧基或羟基。

79. 发明授权

US4904812A Preparation of unsaturated nitriles 失效
标题翻译：不饱和腈的制备
公开(公告)号：US4904812A
公开(公告)日：1990-02-27
申请号：US281915
申请日：1988-12-07
申请人： Wolfgang Hoelderich , Matthias Schwarzmann
发明人： Wolfgang Hoelderich , Matthias Schwarzmann
IPC分类号： B01J29/06 , B01J29/00 , B01J29/08 , B01J29/86 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/07 , C07C255/12
CPC分类号： C07C253/22
摘要： Unsaturated nitriles are prepared from lactones and NH.sub.3 by a process in which the reaction of the lactone with NH.sub.3 is carried out in the presence of a zeolite as a catalyst.A particularly suitable starting material is caprolactone and particularly suitable catalysts are zeolites of the pentasil type, for example aluminosilicate zeolites.
摘要翻译：通过内酯与NH 3的反应在作为催化剂的沸石存在下进行的方法由内酯和NH 3制备不饱和腈。特别合适的起始原料是己内酯，特别合适的催化剂是pentasil类型的沸石，例如铝硅酸盐沸石。

80. 发明授权

US4866210A Preparation of ketones 失效
标题翻译：酮的制备
公开(公告)号：US4866210A
公开(公告)日：1989-09-12
申请号：US144372
申请日：1988-01-15
申请人： Wolfgang Hoelderich , Leopold Hupfer , Kurt Schneider
发明人： Wolfgang Hoelderich , Leopold Hupfer , Kurt Schneider
IPC分类号： C07C45/65 , C07C45/67
CPC分类号： C07C45/65 , C07C45/673 , C07C45/676 , Y02P20/582
摘要： Ketones of the formula ##STR1## where R.sup.1 to R.sup.3 are each hydrogen and R.sup.1 to R.sup.4 are each alkyl of 1 to 12 carbon atoms, cycloalkyl of 4 to 8 carbon atoms, aryl, aralkyl or alkylaryl, which each in turn may be substituted, or R.sup.1 and R.sup.2 and R.sup.3 together with the carbon atoms to which they are bonded form a cycloalkane, are prepared by reacting ketones of the formula ##STR2## where one of R.sup.1, R.sup.2, R.sup.3 and R.sup.5 is hydroxyl, alkoxy or carboxyl while the remaining R.sup.1 to R.sup.4 have the abovementioned meanings, with hydrogen in the presence of acid catalysts supporting one or more hydrogenation components, zeolites of the pentasil type being particularly suitable.
摘要翻译：其中R 1至R 3各自为氢且R 1至R 4各自为具有1至12个碳原子的烷基，4至8个碳原子的环烷基，芳基，芳烷基或烷基芳基的式“IMAGE”的酮，其各自依次可被取代，或者R 1和R 2和R 3与它们所键合的碳原子一起形成环烷烃，是通过使下式的酮反应制备的：其中R1，R2，R3和R5之一是羟基，烷氧基或羧基，而其余的 R1至R4具有上述含义，在负载一种或多种氢化组分的酸催化剂存在下用氢气，pentasil型沸石是特别合适的。

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