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71. 发明授权

US4943667A Preparation of phenylethanols 失效
标题翻译：苯乙醇的制备
公开(公告)号：US4943667A
公开(公告)日：1990-07-24
申请号：US296766
申请日：1989-01-13
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
IPC分类号： B01J27/18 , B01J29/04 , B01J29/85 , C07B61/00 , C07C27/00 , C07C29/10 , C07C29/132 , C07C29/56 , C07C33/20 , C07C33/22 , C07C67/00
CPC分类号： C07C29/132 , Y02P20/582
摘要： Phenylethanols of the formula ##STR1## where R is hydrogen, alkyl of from 1 to 4 carbon atoms, alkoxy of from 1 to 4 carbon atoms, fluorine, trifluoromethyl or trifluoromethoxy, are prepared by reacting epoxides of the formula ##STR2## where R is as defined above, in the presence of hydrogen over zeolites and/or phosphates, doped with hydrogenating metal as catalysts, preferably over zeolites of the pentasil type.
摘要翻译：通过使下式的环氧化物反应，其中R为氢，1-4个碳原子的烷基，1至4个碳原子的烷氧基，氟，三氟甲基或三氟甲氧基的苯基乙醇，其中R为在氢气存在下，在沸石和/或磷酸盐上，掺杂有氢化金属作为催化剂，优选在pentasil型沸石上。

72. 发明授权

US4929765A Preparation of phenylacetaldehydes 失效
标题翻译：苯乙醛的制备
公开(公告)号：US4929765A
公开(公告)日：1990-05-29
申请号：US274930
申请日：1988-11-22
申请人： Hubert Smuda , Wolfgang Hoelderich , Norbert Goetz , Hans-Gert Recker
发明人： Hubert Smuda , Wolfgang Hoelderich , Norbert Goetz , Hans-Gert Recker
IPC分类号： C07C45/51 , C07C45/52 , C07C45/54 , C07C45/58
CPC分类号： C07C45/52 , C07C45/512 , C07C45/513 , C07C45/54 , C07C45/58 , Y02P20/582
摘要： Phenylacetaldehydes of the general formula I ##STR1## where R.sup.1 to R.sup.5 are each independently of the others hydrogen, alkyl, alkoxy, halogen, haloalkyl, haloalkoxy or haloalkylthio, by catalytic rearrangement in the presence of a zeolite, are prepared by reacting an epoxy of the formula II or a phenylglycol of the formula III ##STR2## where Y and Z can be identical to or different from each other and are each hydroxyl, alkoxy, aryloxy or acyloxy, in the gas phase over a borosilicate zeolite catalyst at from 70.degree. to 200.degree. C. under reduced pressure.
摘要翻译：通过在沸石存在下通过催化重排，其中R 1至R 5各自独立地为氢，烷基，烷氧基，卤素，卤代烷基，卤代烷氧基或卤代烷硫基的通式I（I）的苯基乙醛通过使式II的环氧基或式III的苯基二醇其中Y和Z可以彼此相同或不同，并且各自为羟基，烷氧基，芳氧基或酰氧基，其中气相在硼硅酸盐沸石催化剂上在70〜200℃下减压。

73. 发明授权

US4925991A Preparation of dien-1-ols, 9-hydroxydodec-10-enyl 1-tert-butyl ether and use thereof as an intermediate for synthesizing 8,10-dodecadienol 失效
标题翻译：二烯-1-醇，9-羟基十二碳-10-烯基1-叔丁基醚的制备及其作为合成8,10-十二二烯醇的中间体的用途
公开(公告)号：US4925991A
公开(公告)日：1990-05-15
申请号：US235478
申请日：1988-08-24
申请人： Wolfgang Mackenroth , Wolfgang Hoelderich , Rainer Becker , Walter Seufert
发明人： Wolfgang Mackenroth , Wolfgang Hoelderich , Rainer Becker , Walter Seufert
IPC分类号： B01J27/02 , B01J27/16 , B01J27/18 , B01J27/182 , B01J29/85 , C07B61/00 , C07C27/00 , C07C29/10 , C07C29/60 , C07C33/02 , C07C41/00 , C07C43/178 , C07C67/00
CPC分类号： C07C43/178 , C07C29/10 , C07C29/60 , C07B2200/09 , Y02P20/55
摘要： Dien-1-ols of the general formula I ##STR1## where the radicals R.sup.1 to R.sup.7 are identical to or different from one another and each is hydrogen or straight-chain or branched alkyl or 1-12 carbon atoms and n is 1-14, are prepared by dehydrating a hydroxylalkenyl tert-butyl ether of the formula II ##STR2## in the presence of an acidic catalyst at elevated tempertures and essentially at the same time splitting off the tert-butyl protective group, as is 9-hydroxydodec-10-enyl 1-tert-butyl ether which is useful as an intermediate for synthesizing 8,10-dodecadienol.
摘要翻译：其中基团R 1至R 7彼此相同或不同的通式I（I）的二烯-1-醇，各自为氢或直链或支链烷基或1-12个碳原子，n为 1-14，通过在酸性催化剂的存在下在升高的温度下脱水式II II的羟基烯基叔丁基醚，并且基本上同时分离出叔丁基保护基，如是9-羟基十二碳-10-烯基1-叔丁基醚，其可用作合成8,10-十二二烯醇的中间体。

74. 发明授权

US4924000A Preparation of acylated imidazoles 失效
标题翻译：酰化咪唑的制备
公开(公告)号：US4924000A
公开(公告)日：1990-05-08
申请号：US321110
申请日：1989-03-09
申请人： Michael Hesse , Wolfgang Hoelderich , Toni Dockner , Hermann Koehler
发明人： Michael Hesse , Wolfgang Hoelderich , Toni Dockner , Hermann Koehler
IPC分类号： B01J21/00 , B01J21/04 , B01J21/06 , B01J21/08 , B01J23/20 , B01J27/18 , B01J29/04 , C07B61/00 , C07D233/54 , C07D233/64
CPC分类号： C07D233/64
摘要： Acylated imidazoles of the formula ##STR1## where R.sup.1 and R.sup.3 are each H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, R.sup.4 is H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, and R.sup.5 is alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl, alkylaryl or carboxyl, are prepared by reacting imidazoles of the formula ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, at least one of the radicals R.sup.1, R.sup.2 and R.sup.3 being hydrogen, and R.sup.4 is H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, with widely used acylating agents of the formula ##STR3## where R.sup.5 is as defined above and Y is halide, alkoxy, acyloxy or hydroxyl, in the presence of acidic metal oxides and/or phosphates, preferably in the gas phase.
摘要翻译：其中R 1和R 3各自为H，具有1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，R 4为H，1至12的烷基，碳原子，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，R5是1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基，烷基芳基或羧基，使式（Ia）的咪唑与R1，R2和R3各自为1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，基团R1，R2和 R3为氢，R4为H，1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，以及广泛使用的通式为“IMAGE”的酰化剂，其中R5如上定义在酸性金属氧化物和/或磷酸盐的存在下，优选在气相中，Y是卤化物，烷氧基，酰氧基或羟基。

75. 发明授权

US4904812A Preparation of unsaturated nitriles 失效
标题翻译：不饱和腈的制备
公开(公告)号：US4904812A
公开(公告)日：1990-02-27
申请号：US281915
申请日：1988-12-07
申请人： Wolfgang Hoelderich , Matthias Schwarzmann
发明人： Wolfgang Hoelderich , Matthias Schwarzmann
IPC分类号： B01J29/06 , B01J29/00 , B01J29/08 , B01J29/86 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/07 , C07C255/12
CPC分类号： C07C253/22
摘要： Unsaturated nitriles are prepared from lactones and NH.sub.3 by a process in which the reaction of the lactone with NH.sub.3 is carried out in the presence of a zeolite as a catalyst.A particularly suitable starting material is caprolactone and particularly suitable catalysts are zeolites of the pentasil type, for example aluminosilicate zeolites.
摘要翻译：通过内酯与NH 3的反应在作为催化剂的沸石存在下进行的方法由内酯和NH 3制备不饱和腈。特别合适的起始原料是己内酯，特别合适的催化剂是pentasil类型的沸石，例如铝硅酸盐沸石。

76. 发明授权

US4866210A Preparation of ketones 失效
标题翻译：酮的制备
公开(公告)号：US4866210A
公开(公告)日：1989-09-12
申请号：US144372
申请日：1988-01-15
申请人： Wolfgang Hoelderich , Leopold Hupfer , Kurt Schneider
发明人： Wolfgang Hoelderich , Leopold Hupfer , Kurt Schneider
IPC分类号： C07C45/65 , C07C45/67
CPC分类号： C07C45/65 , C07C45/673 , C07C45/676 , Y02P20/582
摘要： Ketones of the formula ##STR1## where R.sup.1 to R.sup.3 are each hydrogen and R.sup.1 to R.sup.4 are each alkyl of 1 to 12 carbon atoms, cycloalkyl of 4 to 8 carbon atoms, aryl, aralkyl or alkylaryl, which each in turn may be substituted, or R.sup.1 and R.sup.2 and R.sup.3 together with the carbon atoms to which they are bonded form a cycloalkane, are prepared by reacting ketones of the formula ##STR2## where one of R.sup.1, R.sup.2, R.sup.3 and R.sup.5 is hydroxyl, alkoxy or carboxyl while the remaining R.sup.1 to R.sup.4 have the abovementioned meanings, with hydrogen in the presence of acid catalysts supporting one or more hydrogenation components, zeolites of the pentasil type being particularly suitable.
摘要翻译：其中R 1至R 3各自为氢且R 1至R 4各自为具有1至12个碳原子的烷基，4至8个碳原子的环烷基，芳基，芳烷基或烷基芳基的式“IMAGE”的酮，其各自依次可被取代，或者R 1和R 2和R 3与它们所键合的碳原子一起形成环烷烃，是通过使下式的酮反应制备的：其中R1，R2，R3和R5之一是羟基，烷氧基或羧基，而其余的 R1至R4具有上述含义，在负载一种或多种氢化组分的酸催化剂存在下用氢气，pentasil型沸石是特别合适的。

77. 发明授权

US4845269A Preparation of 3-pentenoates from 2-pentenoates 失效
标题翻译：由2-戊烯酸酯制备3-戊烯酸酯
公开(公告)号：US4845269A
公开(公告)日：1989-07-04
申请号：US125560
申请日：1987-11-25
申请人： Rolf Fischer , Wolfgang Hoelderich , Manfred Sauerwald
发明人： Rolf Fischer , Wolfgang Hoelderich , Manfred Sauerwald
IPC分类号： B01J27/16 , B01J23/02 , B01J27/00 , B01J27/18 , B01J29/00 , B01J29/08 , B01J29/70 , C07B61/00 , C07C67/333 , C07C69/52 , C07C69/533
CPC分类号： C07C67/327 , B01J29/084 , B01J29/40 , B01J29/86 , C07C319/18 , C07C67/31 , C07D295/15 , B01J2229/186 , B01J2229/20 , B01J2229/42
摘要： 3-pentenoates are prepared from 2-pentenoates by a process in which(a) a 2-pentenoate of the formula ##STR1## where R.sup.1 is alkyl of 1 to 12 carbon atoms, cycloalkyl of 5 to 8 carbon atoms, aralkyl of 7 to 10 carbon atoms or aryl of 6 to 10 carbon atoms, is reacted with a compound of the formula IIR.sup.2 -X-H IIwhere R.sup.2 has the meanings given for R.sup.1 and X is an oxygen or sulfur atom, or with a compound of the formula III ##STR2## where R.sup.3 is hydrogen or R.sup.3 and R.sup.4 are each alkyl of 1 to 12 carbon atoms, cycloakkyl of 5 to 8 carbon atoms, aralkyl of 7 to 10 carbon atoms or aryl of 6 to 10 carbon atoms, and R.sup.3 and R.sup.4 together with the nitrogen atom on which they are substituents may form a 5-membered to 7-membered ring which may additionally contain a nitrogen or oxygen atom as a hetero atom, at from 20.degree. to 300.degree. C., in the presence or absence of a basic catalyst, to give a compound of the formula IV ##STR3## where Y is --XR.sup.2 or ##STR4## in which X, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meanings, and(b) the compound of the formula IV is cleaved in the liquid or gas phase in the presence of an acidic catalyst at from 150.degree. to 450.degree. C. to give a mixture of 3- and 2-pentenoates, and the 3-pentenoate is isolated.
摘要翻译：通过以下方法由2-戊烯酸酯制备3-戊烯酸酯，其中（a）式Ⅰ的2-戊烯酸酯，其中R 1为1至12个碳原子的烷基，5至8个碳原子的环烷基，7个芳烷基至10个碳原子或6至10个碳原子的芳基与式II R2-XH II化合物反应，其中R2具有对R 1给定的含义，X是氧或硫原子，或与式 III，其中R 3是氢或R 3和R 4各自为1至12个碳原子的烷基，5至8个碳原子的环烷基，7至10个碳原子的芳烷基或6至10个碳原子的芳基， R4与它们是取代基的氮原子一起可以形成5元至7元环，其可以在20℃至300℃下另外含有作为杂原子的氮原子或氧原子，不存在碱性催化剂，得到其中Y是-XR2或其中X，R1，R2，R3和R4具有上述m的式IV的化合物IV （b）在150℃至450℃的酸性催化剂存在下，式IV化合物在液相或气相中裂解，得到3-和2-戊烯酸酯的混合物，并且 3-戊烯酸酯是分离的。

78. 发明授权

US4788326A Preparation of 4-pentenoates 失效
标题翻译： 4-戊烯酸酯的制备
公开(公告)号：US4788326A
公开(公告)日：1988-11-29
申请号：US870121
申请日：1986-06-03
申请人： Wolfgang Hoelderich , Wolfgang Richter , Hubert Lendle , Klaus-Dieter Malsch
发明人： Wolfgang Hoelderich , Wolfgang Richter , Hubert Lendle , Klaus-Dieter Malsch
IPC分类号： C07C69/533 , B01J29/00 , C07B61/00 , C07C67/333 , C07C69/52
CPC分类号： C07C67/333 , Y02P20/582
摘要： 4-Pentenoates are prepared by isomerization by a process in which isomeric pentenoates are treated with a zeolite of the pentasil type at from 50.degree. to 300.degree. C., and the 4-pentenoate is distilled off from the reaction mixture.
摘要翻译： 4-戊烯酸酯通过异构化制备，其中异构戊烯酸酯在50-300℃下用pentasil型沸石处理，并从反应混合物中蒸出4-戊烯酸酯。

79. 发明授权

US4777322A Obtaining but-2-enes from C.sub.4 -hydrocarbon mixtures which contain but-1-ene and may or may not contain but-2-enes 失效
标题翻译：从含有1-丁烯的C4-烃混合物中获得丁-2-烯，并且可以含有或不含有2-烯的
公开(公告)号：US4777322A
公开(公告)日：1988-10-11
申请号：US759234
申请日：1985-07-26
申请人： Wolfgang Hoelderich , Alfred Lindner , Wolf D. Mross , Max Strohmeyer , Klaus Volkamer
发明人： Wolfgang Hoelderich , Alfred Lindner , Wolf D. Mross , Max Strohmeyer , Klaus Volkamer
IPC分类号： C07C1/00 , C07C5/25 , C07C7/04 , C07C11/08 , C07C67/00 , C07C5/23
CPC分类号： C07C11/08 , C07C5/2518 , C07C5/2537 , C07C5/2556 , C07C7/04
摘要： But-2-enes are obtained from C.sub.4 -hydrocarbon mixtures which contain but-1-ene and may or may not contain but-2-enes by catalytic isomerization of the but-1-ene to but-2-enes in an isomerization zone at elevated temperatures by a process in which the isomerization is carried out in combination with a distillative separation zone, the said hydrocarbon mixture being fed to the isomerization zone and/or distillative separation zone, the isomerization mixture obtained from the isomerization zone is passed into the distillative separation zone, a but-1-ene-containing fraction is removed above the lower third of the distillative separation zone and passed into the isomerization zone, and the but-2-enes or a fraction containing these are or is removed in the lower third of the distillative separation zone.
摘要翻译：丁-2-烯通过含有丁-1-烯的C 4烃混合物获得，并且可以通过在异构化区中丁-1-烯与丁-2-烯的催化异构化而含有或不含有2-烯在升高的温度下，通过与蒸馏分离区组合进行异构化的方法，将所述烃混合物进料到异构化区和/或蒸馏分离区，将从异构化区获得的异构化混合物送入蒸馏分离区，含有1-丁烯的馏分在蒸馏分离区的三分之一以下被除去并进入异构化区，并且将2-烯烃或其中含有的馏分在下部三分之一的蒸馏分离区。

80. 发明授权

US4743702A Preparation of aliphatic dinitriles 失效
标题翻译：脂肪族二腈的制备
公开(公告)号：US4743702A
公开(公告)日：1988-05-10
申请号：US839161
申请日：1986-03-13
申请人： Wolfgang Hoelderich , Hubert Lendle , Peter Magnussen , Hans Leitner , Jost H. Manegold , Wolfgang Leitenberger
发明人： Wolfgang Hoelderich , Hubert Lendle , Peter Magnussen , Hans Leitner , Jost H. Manegold , Wolfgang Leitenberger
IPC分类号： C07B61/00 , B01J27/00 , B01J29/04 , C07C67/00 , C07C253/00 , C07C253/22 , C07C255/04 , C07C120/08
CPC分类号： C07C253/22
摘要： Aliphatic dinitriles are prepared by reacting aliphatic dicarboxylic acids with ammonia in excess at from 200.degree. to 500.degree. C. in the presence of zeolites as catalysts.
摘要翻译：在沸石作为催化剂存在下，在200-500℃下使脂族二羧酸与氨过量反应制备脂族二腈。

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