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71. 发明授权

US4221720A Thio-bis alkyl lactone acids and esters thereof 失效
标题翻译：硫代双烷基内酯酸及其酯
公开(公告)号：US4221720A
公开(公告)日：1980-09-09
申请号：US967289
申请日：1978-12-07
申请人： Stanley J. Brois , Antonio Gutierrez
发明人： Stanley J. Brois , Antonio Gutierrez
IPC分类号： C07D413/06 , C07D307/32 , C07D307/33 , C07D307/60 , C07D309/30 , C07D413/14 , C10L1/233 , C10L1/24 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/22 , C10M135/32 , C10N30/04 , C10N30/12 , C10N40/04 , F02B3/06 , C07D307/10 , C07D309/20
CPC分类号： C07D307/33 , C07D307/32 , C07D307/60 , C07D309/30 , C10L1/233 , C10L1/2493 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/32 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2209/084 , C10M2209/086 , C10M2209/112 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2223/041 , C10M2223/045 , C10M2223/047 , C10M2229/02 , C10M2229/05 , C10N2210/03 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2270/02 , F02B3/06
摘要： Lactone oxazoline reaction products of hydrocarbon substituted lactone carboxylic acids, for example, polybutyl lactone carboxylic acid, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-(hydroxymethyl)aminomethane (THAM), and their derivatives are useful aditives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-rust agents for gasoline.
摘要翻译：烃取代的内酯羧酸（例如聚丁内酯羧酸）与2,2-二取代-2-氨基-1-链烷醇如三 - （羟甲基）氨基甲烷（THAM）及其衍生物的内酯恶唑啉反应产物是含油组合物，如用于润滑油的污泥分散剂，或汽油用防锈剂等有用的助剂。

72. 发明授权

US4195976A Additive useful in oleaginous compositions 失效
标题翻译：含油组合物中有用的添加剂
公开(公告)号：US4195976A
公开(公告)日：1980-04-01
申请号：US907948
申请日：1978-05-22
申请人： Jack Ryer , James Zielinski , Harold N. Miller , Stanley J. Brois
发明人： Jack Ryer , James Zielinski , Harold N. Miller , Stanley J. Brois
IPC分类号： C07D263/12 , C07D263/14 , C07F5/04 , C07F9/653 , C08F8/32 , C08G63/685 , C10L1/22 , C10L1/233 , C10L1/238 , C10L1/26 , C10L1/30
CPC分类号： C10M1/08 , C07D263/12 , C07D263/14 , C07F5/04 , C07F9/653 , C08F8/32 , C08G63/685 , C10L1/221 , C10L1/233 , C10L1/238 , C10L1/2691 , C10L1/303 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/023 , C10M2207/024 , C10M2207/027 , C10M2207/028 , C10M2207/121 , C10M2207/122 , C10M2207/282 , C10M2207/32 , C10M2207/34 , C10M2209/084 , C10M2209/086 , C10M2209/109 , C10M2209/112 , C10M2211/02 , C10M2215/04 , C10M2215/042 , C10M2215/065 , C10M2215/086 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/042 , C10M2217/043 , C10M2217/046 , C10M2217/06 , C10M2219/044 , C10M2219/046 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/00 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/045 , C10M2223/06 , C10M2223/061 , C10M2223/065 , C10M2223/08 , C10M2223/12 , C10M2225/04 , C10M2225/041 , C10M2227/00 , C10M2227/061 , C10M2229/02 , C10M2229/05 , C10N2210/02 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/102 , C10N2240/103 , C10N2250/10 , C10N2270/02
摘要： Oil soluble oxazoline reaction products of hydrocarbon substituted dicarboxylic acid, ester, or anhydride, for example polyisobutenylsuccinic anhydride, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-hydroxymethylaminomethane (THAM), are useful additives in oleaginous compositions, such as sludge dispersants for lubricating oil or gasoline.
摘要翻译：烃取代的二羧酸，酯或酸酐（例如聚异丁烯基琥珀酸酐）与2,2-二取代-2-氨基-1-链烷醇如三羟甲基氨基甲烷（THAM）的油溶性恶唑啉反应产物是含油的有用的添加剂组合物，例如用于润滑油或汽油的污泥分散剂。

73. 发明授权

US4176073A Molybdenum complexes of lactone oxazoline dispersants as friction reducing antiwear additives for lubricating oils 失效
标题翻译：内酯恶唑啉分散剂的钼络合物作为润滑油的减摩抗磨添加剂
公开(公告)号：US4176073A
公开(公告)日：1979-11-27
申请号：US943206
申请日：1978-09-18
申请人： Jack Ryer , Esther D. Winans , Stanley J. Brois , Antonio Gutierre
发明人： Jack Ryer , Esther D. Winans , Stanley J. Brois , Antonio Gutierre
IPC分类号： C10M163/00 , C07F11/00 , C10M159/18 , C10N10/04 , C10N10/12 , C10N30/04 , C10N30/06 , C10N30/12 , C10N40/25 , C10N60/14 , C10M1/54 , C10L1/30 , C10M1/48
CPC分类号： C10M159/18 , C07F11/005 , C10M2203/06 , C10M2205/00 , C10M2205/026 , C10M2205/06 , C10M2205/22 , C10M2207/026 , C10M2207/027 , C10M2207/028 , C10M2207/144 , C10M2207/146 , C10M2207/16 , C10M2207/262 , C10M2207/287 , C10M2207/288 , C10M2207/289 , C10M2209/084 , C10M2215/04 , C10M2215/08 , C10M2215/082 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/022 , C10M2217/023 , C10M2217/028 , C10M2217/046 , C10M2217/06 , C10M2219/022 , C10M2219/024 , C10M2219/044 , C10M2219/046 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/108 , C10M2223/045 , C10M2223/047 , C10M2223/12 , C10M2223/121 , C10M2225/04 , C10M2225/041 , C10M2227/061 , C10N2210/02 , C10N2210/06
摘要： A molybdenum complex of a lactone oxazoline dispersant, preferably an oil-soluble lactone oxazoline obtained as a reaction product of hydrocarbyl substituted lactone carboxylic acids, for example, polybutyl lactone carboxylic acid, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-(hydroxymethyl) aminomethane (THAM), and their derivatives are useful additives in lubricating oils since both the sludge dispersant and antifriction properties of said oil are enhanced.
摘要翻译：内酯恶唑啉分散剂的钼络合物，优选作为烃基取代的内酯羧酸（例如聚丁内酯羧酸）与2,2-二取代-2-氨基-1-链烷醇的反应产物获得的油溶性内酯恶唑啉，如三（羟甲基）氨基甲烷（THAM），它们的衍生物是润滑油中有用的添加剂，因为所述油的污泥分散剂和抗摩擦性均得到增强。

74. 发明授权

US4174322A Thiobis(oxazolines) 失效
标题翻译：硫堇（恶唑啉）
公开(公告)号：US4174322A
公开(公告)日：1979-11-13
申请号：US817217
申请日：1977-07-20
申请人： Stanley J. Brois , Antonio Gutierrez
发明人： Stanley J. Brois , Antonio Gutierrez
IPC分类号： C07D307/32 , C07D307/33 , C07D307/60 , C07D309/30 , C10L1/233 , C10L1/24 , C10M133/48 , C10M133/58 , C10M135/32 , F02B3/06 , C07D263/08
CPC分类号： C07D307/33 , C07D307/32 , C07D307/60 , C07D309/30 , C10L1/233 , C10L1/2493 , C10M133/48 , C10M133/58 , C10M135/32 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2209/084 , C10M2209/086 , C10M2209/112 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2223/041 , C10M2223/045 , C10M2223/047 , C10M2229/02 , C10M2229/05 , C10N2210/03 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2270/02 , F02B3/06
摘要： Lactone oxazoline reaction products of hydrocarbon substituted lactone carboxylic acids, for example, polybutyl lactone carboxylic acid, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-(hydroxymethyl)aminomethane (THAM), and their derivatives are useful additives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-rust agents for gasoline.
摘要翻译：烃取代的内酯羧酸（例如聚丁内酯羧酸）与2,2-二取代-2-氨基-1-链烷醇如三 - （羟甲基）氨基甲烷（THAM）及其衍生物的内酯恶唑啉反应产物是含油组合物中有用的添加剂，如润滑油污泥分散剂，或汽油防锈剂。

75. 发明授权

US4100187A Olefin-thionophosphine sulfide reaction products, their derivatives and use thereof as oil and fuel additives 失效
标题翻译：烯烃 - 硫代磷化氢反应产物，其衍生物和作为油和燃料添加剂的用途
公开(公告)号：US4100187A
公开(公告)日：1978-07-11
申请号：US622073
申请日：1975-10-14
申请人： Stanley J. Brois
发明人： Stanley J. Brois
IPC分类号： C07F9/32 , C07F9/38 , C07F9/40 , C07F9/6578 , C08F8/34 , C08F8/40 , C10L1/26 , C10M137/14 , C10M159/12 , C10M169/00 , C07F9/04
CPC分类号： C10M159/123 , C07F9/6578 , C08F8/40 , C10L1/2691 , C10M1/08 , C10M137/14 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108 , C10M2205/026 , C10M2207/282 , C10M2207/32 , C10M2207/34 , C10M2209/084 , C10M2209/086 , C10M2209/103 , C10M2209/104 , C10M2209/109 , C10M2209/111 , C10M2211/02 , C10M2215/065 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/045 , C10M2223/047 , C10M2223/06 , C10M2223/061 , C10M2223/063 , C10M2223/065 , C10M2223/12 , C10M2225/00 , C10M2225/02 , C10M2225/04 , C10M2225/041 , C10M2229/02 , C10M2229/05 , C10N2210/02 , C10N2270/02
摘要： Adducts are formed in a process which involves the reaction of an olefin, including olefin polymers, with a dimeric thionophosphine sulfide. Further derivatives may be formed by reacting the resulting olefin-thionophosphine sulfide adduct products with amines, e.g., alkylene polyamines, aziridines, phosphines or metal salts, e.g., zinc salts. Or, alkylene polyamine- or aziridine- treated olefin-thionophosphine sulfide reaction products may be further reacted with metal salts, e.g., zinc acetate. A representative material can be prepared by reacting polyisobutylene with an arylthionophosphine sulfide, and then further reacting the resulting cyclic bis(phosphinodithioic acid) anhydride product with an alkylene polyamine or aziridine, which in turn, may be further modified by reaction with zinc acetate.The oil soluble olefin-thionophosphine sulfide products, as well as its oil soluble derivatives outlined above, may be used as additives for lubricating oil, and petroleum fuels, e.g., gasoline or fuel oil.
摘要翻译：在包括烯烃聚合物的烯烃与二聚硫代膦硫化物反应的方法中形成加合物。另外的衍生物可以通过使所得到的烯烃 - 硫代膦硫化物加合产物与胺例如亚烷基多胺，氮丙啶，膦或金属盐例如锌盐反应形成。或者，亚烷基多胺或氮丙啶处理的烯烃 - 硫代膦化物反应产物可以与金属盐例如乙酸锌进一步反应。代表性材料可以通过使聚异丁烯与芳基硫羰基硫化膦反应制备，然后使所得的环状双（膦酸二硫酸）酸酐产物与亚烷基多胺或氮丙啶进一步反应，其又可以通过与乙酸锌反应进一步改性。

76. 发明授权

US4069023A Carboxylate esters of 1-aza-3,7-dioxabicyclo[3.3.0] oct-5-yl methyl alcohols, their preparation and use as additives for oleaginous compositions 失效
标题翻译： 1-氮杂-3,7-二氧杂双环{8 3.3.0 {9 {0辛-5-基甲醇，其制备和用作油性组合物的添加剂的羧酸酯
公开(公告)号：US4069023A
公开(公告)日：1978-01-17
申请号：US752873
申请日：1976-12-20
申请人： Stanley J. Brois , Jack Ryer , Esther Winans
发明人： Stanley J. Brois , Jack Ryer , Esther Winans
IPC分类号： C10M133/48 , C07D491/22 , C07D498/04 , C08F8/00 , C10L1/22 , C10L10/08 , C10M133/00 , C10N30/04 , C10N30/06 , C10N30/12 , C10N40/25
CPC分类号： C07D491/22 , C07D498/04 , C08F8/30 , C10L1/221 , C10L10/04 , C10L10/08 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2207/282 , C10M2207/32 , C10M2207/34 , C10M2209/084 , C10M2209/086 , C10M2209/103 , C10M2209/112 , C10M2211/02 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/04 , C10M2223/042 , C10M2223/045 , C10M2223/12 , C10M2225/04 , C10M2229/02 , C10M2229/05 , C10N2210/02 , C10N2240/08 , C10N2270/02
摘要： Ester derivatives of 1-aza-3,7-dioxabicyclo [3.3.0] oct-5-yl methyl alcohols which are the reaction products of organic acid materials, preferably long chain dicarboxylic anhydrides such as octadecenyl and polyisobutenylsuccinic anhydrides and aldehyde/tris [hydroxy-methyl] aminomethane (THAM) adducts or mixtures are oleaginous compositions which feature activity in gasoline as rust inhibitors and carburetor detergents; in automatic transmission fluids as friction modifiers and rust inhibitors; and, in automotive, industrial and lubricating oils as sludge dispersants, rust-inhibitors, friction modifiers and copper alloy corrosion inhibitors, the particular use depending on the molecular weight of the ester.
摘要翻译：作为有机酸材料的反应产物的1-氮杂-3,7-二氧杂二环[3.3.0]辛-5-基甲醇的酯衍生物，优选长链二羧酸酐如十八碳烯基和聚异丁烯基琥珀酸酐和醛/三[ 羟基甲基]氨基甲烷（THAM）加合物或混合物是含油组合物，其特征在于作为防锈剂和化油器洗涤剂的汽油中的活性; 在自动变速器油中作为摩擦改进剂和防锈剂; 并且在作为污泥分散剂，防锈剂，摩擦改进剂和铜合金腐蚀抑制剂的汽车，工业和润滑油中，具体用途取决于酯的分子量。

77. 发明授权

US4017406A Carboxylate half esters of 1-aza-3,7-dioxabicyclo[3.3.0] oct-5-yl methyl alcohols, their preparation and use as additives for oleaginous compositions 失效
标题翻译： 1-氮杂-3,7-二氧杂双环{8 3.3.0 {9 {0辛-5-基甲醇，其制备和用作油性组合物的添加剂的羧酸酯半酯
公开(公告)号：US4017406A
公开(公告)日：1977-04-12
申请号：US573545
申请日：1975-05-01
申请人： Stanley J. Brois , Jack Ryer , Esther Winans
发明人： Stanley J. Brois , Jack Ryer , Esther Winans
IPC分类号： C10M133/48 , C07D491/22 , C07D498/04 , C08F8/00 , C10L1/22 , C10L10/08 , C10M133/00 , C10N30/04 , C10N30/06 , C10N30/12 , C10N40/25 , C10M1/32
CPC分类号： C07D491/22 , C07D498/04 , C08F8/30 , C10L1/221 , C10L10/04 , C10L10/08 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2207/282 , C10M2207/32 , C10M2207/34 , C10M2209/084 , C10M2209/086 , C10M2209/103 , C10M2209/112 , C10M2211/02 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/04 , C10M2223/042 , C10M2223/045 , C10M2223/12 , C10M2225/04 , C10M2229/02 , C10M2229/05 , C10N2210/02 , C10N2240/08 , C10N2270/02
摘要： Ester derivatives of 1-aza-3,7-dioxabicyclo [3.3.0] oct-5-yl methyl alcohols which are the reaction products of organic acid materials, preferably long chain dicarboxylic anhydrides such as octadecenyl and polyisobutenylsuccinic anhydrides and aldehyde/tris [hydroxy-methyl] aminomethane (THAM) adducts or mixtures are oleaginous compositions which feature activity in gasoline as rust inhibitors and carburetor detergents; in automatic transmission fluids as friction modifiers and rust inhibitors; and, in automotive, industrial and lubricating oils as sludge dispersants, rust-inhibitors, friction modifiers and copper alloy corrosion inhibitors, the particular use depending on the molecular weight of the ester.
摘要翻译：作为有机酸材料的反应产物的1-氮杂-3,7-二氧杂二环[3.3.0]辛-5-基甲醇的酯衍生物，优选长链二羧酸酐如十八碳烯基和聚异丁烯基琥珀酸酐和醛/三[ 羟基甲基]氨基甲烷（THAM）加合物或混合物是含油组合物，其特征在于作为防锈剂和化油器洗涤剂的汽油中的活性; 在自动变速器油中作为摩擦改进剂和防锈剂; 并且在作为污泥分散剂，防锈剂，摩擦改进剂和铜合金腐蚀抑制剂的汽车，工业和润滑油中，具体用途取决于酯的分子量。

78. 发明授权

US06730747B1 Carbonyl containing compounds 失效
标题翻译：含羰基化合物
公开(公告)号：US06730747B1
公开(公告)日：2004-05-04
申请号：US09476924
申请日：2000-01-04
申请人： Stanley J. Brois
发明人： Stanley J. Brois
IPC分类号： C08F800
CPC分类号： C08F8/28 , C08F8/00 , C08F10/00
摘要： In accordance with the present invention, there is provided a novel composition of matter having the formula: wherein Ra, Rb, Rc, Rd and Re are independently selected from the group consisting of H, alkyl groups and substituted alkyl groups having about 1 to 106 carbon atoms, alkenyl groups and substituted alkenyl groups having about 3 to 106 carbon atoms, wherein the substituents on the alkyl and/or alkenyl groups are selected from the group consisting of alkoxy, halogen, CN, OH, HO(CH2CH2O)x (X=1-10), acyl, acyloxy and aryl substituents.
摘要翻译：根据本发明，提供了具有下式的物质的新组合物：其中Ra，Rb，Rc，Rd和Re独立地选自H，烷基和具有约1-10个碳原子的取代的烷基具有约3至10 6个碳原子的烯基和取代的烯基，其中烷基和/或烯基上的取代基选自烷氧基，卤素，CN，OH，HO （CH 2 CH 2 O）x（X = 1-10），酰基，酰氧基和芳基取代基。

79. 发明授权

US06569820B2 Manufacture of lubricant additives 有权
标题翻译：制造润滑油添加剂
公开(公告)号：US06569820B2
公开(公告)日：2003-05-27
申请号：US09816053
申请日：2001-03-23
申请人： Jonathan M. McConnachie , Ian A. W. Bell , Edward I. Stiefel , Stanley J. Brois , Ernestine W. Hill , Alisdair J. Brown
发明人： Jonathan M. McConnachie , Ian A. W. Bell , Edward I. Stiefel , Stanley J. Brois , Ernestine W. Hill , Alisdair J. Brown
IPC分类号： C10M13900
CPC分类号： C10M159/18 , C07F11/005 , C10M135/18 , C10M2219/068 , C10M2227/09 , C10N2210/06 , C10N2240/08 , C10N2270/02
摘要： Oil-soluble or oil-dispersible trinuclear molybdenum-sulfur compounds are made by reacting, in a polar medium, a reactant molybdenum compound containing an anion that possesses a trinuclear molybdenum core, and a dithiocarbamate that is produced in situ.
摘要翻译：通过在极性介质中使含有具有三核钼核的阴离子的反应物钼化合物和原位产生的二硫代氨基甲酸酯反应制备油溶性或油分散性三核钼硫化合物。

80. 发明授权

US5849193A Surface active metal chelated nutrients for bioremediation of hydrocarbon contaminated soils and water 失效
公开(公告)号：US5849193A
公开(公告)日：1998-12-15
申请号：US678841
申请日：1996-07-12
申请人： Ramesh Varadaraj , Stanley J. Brois , Jan Bock , Cornelius Hendrick Brons
发明人： Ramesh Varadaraj , Stanley J. Brois , Jan Bock , Cornelius Hendrick Brons
IPC分类号： B09C1/10 , C02F1/68 , C11D3/32 , C12N1/38 , C02F3/00
CPC分类号： C02F1/682 , B09C1/10 , C11D3/32 , C12N1/38 , Y10S210/925 , Y10S516/02 , Y10S516/07
摘要： The present invention provides for enhanced bioremediation of hydrocarbon contaminated soils and waters by treating soil or water with a composition comprising of a metal chelated macrocyclic amido amines or mixtures thereof represented by the structural formula: ##STR1## where R is selected from linear or branched alkanes with 8 to 22 carbons, linear or branched alkenes with 4 to 22 carbon atoms; T.sub.1, T.sub.2 and T.sub.3 are independently selected from ethylene, trimethylene, CH.sub.2 CH.sub.2 (NHCH.sub.2 CH.sub.2).sub.x where x is an integer from 1 to 10; MaQb is a metal compound wherein M is a cation selected from cations of Fe, Co, Ni, Cu, Zn, and Mn; and, Q is an anion selected from nitrate, phosphate anions; and a and b are integers from 1 to 3 necessary to satisfy the valence requirements of M and Q. a phosphorous source, and a diluent.

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