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    • 73. 发明授权
    • Polyoelfin films having increased gas permeability and method for making
    • 具有增加的透气性和制备方法的多孔菲林膜
    • US5958319A
    • 1999-09-28
    • US686042
    • 1996-07-24
    • Patrick Brant
    • Patrick Brant
    • C08J5/18C08L23/08B29C35/02
    • C08J5/18C08J2323/16C08L23/0815C08L2314/06
    • Films, made of polyethylenes, and articles made therefrom exhibit, for a given density, improved oxygen transmission. The polyethylenes are produced in a metallocene-catalyzed production process. The films may be made by a cast film process, and may be made under conditions that raise the birefringence and the oxygen transmission rate of the film, such as increasing strain rate decreasing melt temperature, increasing quench rates, or may be post-extrusion treated, for instance annealed or cold drawn. Combinations of both extrusion techniques and post-extrusion techniques may also be used. Polyethylenes utilized for making such films typically have a Composition Distribution Breadth Index above 50%, a M.sub.w /M.sub.n below 3, and a M.sub.z /M.sub.w below 2. The permeability of the films so made will be 50% or more above the permeability of films based on similar resins based on previously used film formation techniques.
    • 由聚乙烯制成的薄膜以及由此制成的制品对于给定的密度显示出改进的氧气透过性。 聚乙烯在金属茂催化的生产过程中制备。 膜可以通过流延膜制备,并且可以在提高膜的双折射和氧气透过速率的条件下制备,例如增加应变速率降低熔融温度,提高淬火速率,或者可以是后挤出处理 ,例如退火或冷拉。 也可以使用挤出技术和挤出后技术的组合。 用于制造这种膜的聚乙烯通常具有高于50%的组分分布宽度指数,Mw / Mn低于3,Mz / Mw低于2。所制成的膜的渗透性将比膜的渗透率高50%或更高 基于基于先前使用的成膜技术的类似树脂。
    • 76. 发明授权
    • Tackified polyethylene layers in stretch/cling films
    • 拉伸/粘贴膜中的增强聚乙烯层
    • US5114763A
    • 1992-05-19
    • US635194
    • 1990-12-28
    • Patrick BrantPaul M. German
    • Patrick BrantPaul M. German
    • B65D75/00
    • B65D75/006Y10T428/1328Y10T428/31855Y10T428/31913
    • A thermoplastic film is provided which is especially suited for use in stretch/cling applications such as, for example, the bundling, packaging and unitizing of foods and other goods. The film comprises a cling layer comprising a polyethylene, preferably low density polyethylene (LLDPE) and a compatible tackifier. The LLDPE has a density of from about 0.87 to about 0.92 g/cc, a melt index of from about 1 to about 30 dg/min and a ratio of weight average molecular weight to number average molecular weight (M.sub.w /M.sub.n) less than about 6. The blend has a glass transition temperature of about 0.degree. C. or less. The film may be a one-sided cling film having a polyolefin slip layer opposite the cling layer.
    • 提供了一种热塑性薄膜,其特别适用于拉伸/粘贴应用,例如食品和其他物品的捆扎,包装和组合。 该薄膜包括一个包含聚乙烯,优选低密度聚乙烯(LLDPE)和相容的增粘剂的粘结层。 LLDPE的密度为约0.87至约0.92g / cc,熔体指数为约1至约30dg / min,重均分子量与数均分子量(Mw / Mn)之比小于约 该共混物的玻璃化转变温度为约0℃或更低。 该膜可以是具有与粘附层相对的聚烯烃滑移层的单面粘贴膜。