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71. 发明授权

US5097085A Process for oligomerizing olefins using phosphorous-containing acid on montmorillonite clay 失效
标题翻译：使用含有含磷酸盐的蒙脱石粘土低聚烯烃的方法
公开(公告)号：US5097085A
公开(公告)日：1992-03-17
申请号：US551969
申请日：1990-07-12
申请人： John R. Sanderson , John F. Knifton
发明人： John R. Sanderson , John F. Knifton
IPC分类号： B01J21/16 , B01J27/16 , C07B61/00 , C07C2/12 , C07C2/18 , C07C9/00 , C07C11/02 , C08F4/06 , C08F4/18 , C08F8/00 , C08F10/14 , C10M105/04 , C10N40/25 , C10N60/02 , C10N70/00
CPC分类号： B01J27/16 , B01J21/16 , C07C2/18 , C07C9/00 , C07C2521/16 , C07C2527/16 , C07C2527/173
摘要： An improved process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks are prepared in good yield by oligomerizing linear olefins using montmorillonite clays which have a phosphorous-containing acid deposited thereon.

72. 发明授权

US5068366A Simultaneous epoxide and carboxylic acid manufacture by co-oxidation in the presence of a cobalt catalyst 失效
标题翻译：在钴催化剂存在下通过共同氧化制备环氧化物和羧酸
公开(公告)号：US5068366A
公开(公告)日：1991-11-26
申请号：US563237
申请日：1990-08-06
申请人： John R. Sanderson , Edward T. Marquis
发明人： John R. Sanderson , Edward T. Marquis
IPC分类号： C07C51/235 , C07C51/25 , C07D301/06
CPC分类号： C07D301/06 , C07C51/235 , C07C51/252
摘要： A process for the preparation of isobutylene oxide and isobutyric acid from isobutylene and isobutyraldehyde, respectively, by a co-oxidation process conducted in the presence of oxygen and a cobalt salt catalyst at a temperature of about 20.degree. to about 180.degree. C. is disclosed.
摘要翻译：公开了通过在约20℃至约180℃的温度下在氧和钴盐催化剂存在下进行的共氧化方法从异丁烯和异丁醛制备异丁烯和异丁酸的方法。。

73. 发明授权

US5059725A One step synthesis of methyl t-butyl ether from t-butanol plus methanol using Group IV oxides treated with sulfates or sulfuric acid 失效
标题翻译：使用用硫酸盐或硫酸处理的IV族氧化物一步合成叔丁醇甲基叔丁基醚
公开(公告)号：US5059725A
公开(公告)日：1991-10-22
申请号：US677192
申请日：1991-03-29
申请人： John F. Knifton , John R. Sanderson
发明人： John F. Knifton , John R. Sanderson
IPC分类号： B01J21/06 , B01J27/053 , C07B61/00 , C07C41/09 , C07C43/04
CPC分类号： C07C41/09
摘要： Disclosed is a method wherein t-butanol is reacted with methanol in one step to provide methyl t-butyl ether at a temperature of about 20.degree. C. to 250.degree. C. and a pressure of about atmospheric to about 1000 psig employing a catalyst consisting of a Group IV oxide on which there has been deposited a sulfur-containing compound from the group consisting of ammonium sulfate or sulfuric acid.
摘要翻译：公开了一种方法，其中叔丁醇与甲醇在一个步骤中反应以在约20℃至250℃的温度和约大气压至约1000psig的压力下提供甲基叔丁基醚，使用催化剂组成的IV族氧化物，其中已经从硫酸铵或硫酸中沉积含硫化合物。

74. 发明授权

US4980514A Ketone derivatives of polyoxypropylene glycols 失效
标题翻译：聚氧丙烯二醇的酮衍生物
公开(公告)号：US4980514A
公开(公告)日：1990-12-25
申请号：US444211
申请日：1989-12-01
申请人： John R. Sanderson , Edward T. Marquis
发明人： John R. Sanderson , Edward T. Marquis
IPC分类号： B01J23/46 , C07B61/00 , C07C45/29 , C07C45/30 , C07C49/175 , C08G65/32
CPC分类号： C07C49/175 , C07C45/29 , C07C45/30
摘要： Diketones useful as intermediates for reaction with carboxylic acids to provide surfactants and for reaction with amine adducts to provide fuel additives are prepared from polyoxyalkylene glycols having a molecular weight of about 200 to about 2,000 and having the formula: ##STR1## wherein R is hydrogen or methyl and wherein n is a positive number having a value of 1 to about 50,The polyoxyalkylene polyol is oxidized in the presence of a halogenated alkane solvent and a ruthenium catalyst with an alkali metal or alkaline earth metal hypochlorite at a temperature of about 10.degree. to about 50.degree. C. and a pressure of about 0 to 1,000 psig. over a period of about 10 to about 20 hours to provide the corresponding diketone having the formula: ##STR2## wherein R and n have the meaning given above.
摘要翻译：可用作与羧酸反应以提供表面活性剂和与胺加合物反应以提供燃料添加剂的中间体的二酮由具有约200至约2,000的分子量的聚氧亚烷基二醇制备，具有下式：其中R 是氢或甲基，其中n为1至约50的正数。聚氧化烯多元醇在卤化烷烃溶剂和钌催化剂存在下，在碱金属或碱土金属次氯酸盐的存在下，在约10℃至约50℃，压力为约0至1,000psig。在约10至约20小时的时间内提供具有下式的相应二酮：其中R和n具有上述含义。

75. 发明授权

US4978799A Production of detergent range alcohols and ketones using porphyrin catalysts 失效
标题翻译：使用卟啉催化剂生产洗涤剂范围的醇和酮
公开(公告)号：US4978799A
公开(公告)日：1990-12-18
申请号：US428812
申请日：1989-10-30
申请人： John R. Sanderson , Edward T. Marquis , Howard F. Payton
发明人： John R. Sanderson , Edward T. Marquis , Howard F. Payton
IPC分类号： C07C29/48 , C07C45/28
CPC分类号： C07C45/28 , C07C29/48
摘要： A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of a transition metal porphyrin catalyst is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide. The transition metal porphyrin catalyst may be transition metal phthalocyanines, transition metalloporphines and the like. The transition metal itself may be iron, manganese, cobalt and mixtures thereof. Suitable ligands include, but are not limited to imidazoles and lithium borate. Other useful additives include alkali metal perchlorates, such as sodium perchlorate, iodosylbenzene and alkali metal superoxides, such as potassium superoxide, and phase transfer catalysts such as tetrabutyl ammonium bromide.
摘要翻译：描述了在过渡金属卟啉催化剂存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。过渡金属卟啉催化剂可以是过渡金属酞菁，过渡金属卟啉等。过渡金属本身可以是铁，锰，钴及其混合物。合适的配体包括但不限于咪唑和硼酸锂。其它有用的添加剂包括碱金属高氯酸盐如高氯酸钠，碘代苯和碱金属超氧化物如超氧化钾，以及相转移催化剂如四丁基溴化铵。

76. 发明授权

US4910349A Catalyst production of tertiary butyl alcohol from tertiary butyl hydroperoxide 失效
标题翻译：催化剂由叔丁基过氧化氢生产叔丁醇
公开(公告)号：US4910349A
公开(公告)日：1990-03-20
申请号：US94173
申请日：1987-09-08
申请人： John R. Sanderson , John F. Knifton , Edward T. Marquis
发明人： John R. Sanderson , John F. Knifton , Edward T. Marquis
IPC分类号： C07C29/132
CPC分类号： C07C29/132
摘要： Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a metal phthalocyanine catalyst promoted with a rhenium compound, such as a phthalocyanine of a metal of Group IB, Group VIIB or Group VIIIB of the Periodic Table (e.g., chloroferric phthalocyanine and rhenium heptoxide-p-dioxane or oxotrichloro-bis-(triphenylphosphine) rhenium V).
摘要翻译：通过叔丁基过氧化氢的催化分解，优选在叔丁醇的溶液中，在用铼化合物，如IB组金属，ⅦB族金属的酞菁等促进的金属酞菁催化剂的存在下，制备叔丁醇，元素周期表VIIIB组（例如，氯代酞菁和铼的叔丁醇钌或氧三氯 - 双 - （三苯基膦）铼V）。

77. 发明授权

US4722919A Synthesis of vanadium/propylene glycol complexes 失效
标题翻译：钒/丙二醇配合物的合成
公开(公告)号：US4722919A
公开(公告)日：1988-02-02
申请号：US916075
申请日：1986-10-06
申请人： Edward T. Marquis , John R. Sanderson
发明人： Edward T. Marquis , John R. Sanderson
IPC分类号： B01J31/22
CPC分类号： B01J31/223 , B01J31/4092 , B01J2231/72 , B01J2531/56
摘要： Complexes made by reacting propylene glycol with a vanadium compound soluble therein at an elevated temperature. Mild stripping of the water subsequent to complex formation is preferred. The ratio of moles of propylene glycol to gram atoms of vanadium in the complex forming reaction ranges from 7:1 to 20:1.
摘要翻译：通过使丙二醇与可溶于其中的钒化合物在升高的温度下反应制得的络合物。复合物形成后水的轻度汽提是优选的。络合物形成反应中丙二醇与钒原子数的摩尔比为7:1至20:1。

78. 发明授权

US4691035A Purification of propylene oxide by treatment with a selected base and inert salt 失效
标题翻译：通过用选择的碱和惰性盐处理来纯化环氧丙烷
公开(公告)号：US4691035A
公开(公告)日：1987-09-01
申请号：US851846
申请日：1986-04-14
申请人： John R. Sanderson , Edward T. Marquis , William A. Smith , Kenneth P. Keating
发明人： John R. Sanderson , Edward T. Marquis , William A. Smith , Kenneth P. Keating
IPC分类号： C07D301/32
CPC分类号： C07D301/32
摘要： Methyl formate is removed from propylene oxide by treatment with a selected base such as sodium hydroxide in water and glycerol. Selected inert salts may be added. The rate of methyl formate hydrolysis by selected bases was increased to commercially acceptable levels by addition of the glycerol. The glycerol and inert salts reduced the amount of residual water in the propylene oxide.
摘要翻译：通过用选择的碱如氢氧化钠在水和甘油中处理，从环氧丙烷中除去甲酸甲酯。可以加入选择的惰性盐。通过加入甘油将选择的碱的甲酸甲酯水解速率提高到商业上可接受的水平。甘油和惰性盐减少环氧丙烷中残留水的量。

79. 发明授权

US4469880A Cycloalkane epoxides produced by air oxidation of cycloalkenes 失效
标题翻译：通过环烯烃的空气氧化产生的环烷烃环氧化物
公开(公告)号：US4469880A
公开(公告)日：1984-09-04
申请号：US422103
申请日：1982-09-23
申请人： John R. Sanderson , Lewis W. Watts, Jr. , Terry L. Renken , Steven H. Vanderpool
发明人： John R. Sanderson , Lewis W. Watts, Jr. , Terry L. Renken , Steven H. Vanderpool
IPC分类号： C07D301/06 , C07D303/04
CPC分类号： C07D303/04 , C07D301/06
摘要： A process for the production of cycloalkane epoxides from cycloalkenes in the presence of a boron-containing catalyst, oxygen and a carboxylate ion source via air oxidation is described. Alkali metal borates, alkali earth metal borates, rare earth borates and transition metal borates are useful catalysts. The boron catalyst may contain many different cations including lithium, sodium, strontium, barium, cerium, zirconium, vanadium, niobium, iron, cobalt, nickel, copper, zinc, and mixtures thereof. The reaction is conducted at a temperature in the range of 50.degree. to 150.degree. C. and a pressure of one atmosphere or greater. Cycloalkane epoxides are useful in the preparation of resins, plasticizers, etc.
摘要翻译：描述了通过空气氧化在含硼催化剂，氧和羧酸根离子源存在下从环烯烃生产环烷烃环氧化物的方法。碱金属硼酸盐，碱土金属硼酸盐，稀土硼酸盐和过渡金属硼酸盐是有用的催化剂。硼催化剂可以包含许多不同的阳离子，包括锂，钠，锶，钡，铈，锆，钒，铌，铁，钴，镍，铜，锌及其混合物。该反应在50℃至150℃的温度和一个或多于一个气压的压力下进行。环烷烃环氧化物可用于制备树脂，增塑剂等

80. 发明授权

US4450290A Alkane acetates produced by oxidative esterification of olefins over transition metal borates in the presence of acetic acid 失效
标题翻译：在乙酸存在下，过渡金属硼酸盐通过烯烃的氧化酯化产生的烷基乙酸酯
公开(公告)号：US4450290A
公开(公告)日：1984-05-22
申请号：US402663
申请日：1982-07-28
申请人： John R. Sanderson , Lewis W. Watts, Jr. , Walter H. Brader, Jr.
发明人： John R. Sanderson , Lewis W. Watts, Jr. , Walter H. Brader, Jr.
IPC分类号： C07C67/05
CPC分类号： C07C67/05
摘要： A process for the production of alkane acetates from olefins in the presence of a transition metal borate catalyst, oxygen and acetic acid alone via oxidative esterification is described. The reaction is conducted at a temperature in the range of 120.degree. to 220.degree. C. and a pressure of 1 atmosphere or greater. Alkane diacetates and hydroxy acetates are produced which may be used as precursors to alkylene oxides, alkylene glycols and other useful compounds.
摘要翻译：描述了通过氧化酯化在过渡金属硼酸盐催化剂，氧气和乙酸存在下由烯烃生产烷基乙酸酯的方法。反应在120-220℃的温度和1个大气压或更大的压力下进行。产生二烷基二烷基酯和羟基乙酸酯，其可用作环氧烷，亚烷基二醇和其它有用化合物的前体。

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