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    • 73. 发明授权
    • Process for the production of decorative coatings on substrates
    • 在基材上生产装饰涂料的方法
    • US07273530B2
    • 2007-09-25
    • US10818278
    • 2004-04-05
    • Carmen FlosbachPeter FresePhu Qui NguyenMartin Wulf
    • Carmen FlosbachPeter FresePhu Qui NguyenMartin Wulf
    • B29C65/04B32B37/00
    • B29C37/0025B29C35/0805B29C2035/0827B44C1/16
    • The invention relates to a process for the production of decorative coatings, comprising the following steps: A) providing a substrate to be coated and a backing film coated on one side with an uncured or only partially cured coating of a coating composition curable by means of high-energy radiation, B) forming zones on the backing film which are opaque to high-energy radiation and correspond to the negative image of a desired pattern or decoration, C) applying the coated side of the backing film having the uncured or only partially cured coating of a coating composition curable by means of high-energy radiation with the coated side thereof onto a substrate surface, D) curing the coating applied by the backing film by irradiation with high-energy radiation through the backing film, E) removing the backing film from the coating which remains on the substrate, and F) removing the un-irradiated and thus uncured parts of the coating remaining on the substrate to obtain the desired pattern or decoration.
    • 本发明涉及一种用于生产装饰涂料的方法,包括以下步骤:A)提供待涂覆的基材和在一侧涂覆有未固化或仅部分固化的涂料组合物的背衬薄膜,涂料组合物可通过 高能量辐射,B)在背衬膜上形成对高能辐射不透明并对应于所需图案或装饰的负像的区域,C)将具有未固化或仅部分的背衬膜的涂覆面 通过高能量辐射可固化的涂层组合物的固化涂层,其涂覆侧在基材表面上,D)通过用高能辐射通过背衬膜照射来固化由背衬膜施加的涂层,E) 从保留在基材上的涂层获得背衬膜,以及F)去除残留在基材上的未涂覆的未涂覆的涂层部分以获得所需的图案 或装饰。
    • 77. 发明申请
    • PROCESS FOR THE PRODUCTION OF POLYURETHANE DI(METH)ACRYLATES
    • 聚氨酯二(甲基)丙烯酸酯的生产方法
    • US20060079659A1
    • 2006-04-13
    • US10963907
    • 2004-10-13
    • Carmen FlosbachStefanie Matten
    • Carmen FlosbachStefanie Matten
    • C08G18/00
    • C08G18/8175C08G18/3206C08G18/3212C08G18/672C08G18/73C08G2150/20C09D175/16
    • A process for the production of polyurethane di(meth)acrylates in which a diisocyanate component, a diol component and hydroxy-C2-C4-alkyl(meth)acrylate in the molar ratio x:(x-1):2 are reacted without solvent and without subsequent purification operations, wherein x means any desired value from 2 to 5, wherein 50 to 80 mol % of the diisocyanate component is formed by 1,6-hexane diisocyanate, and 20 to 50 mol % by one or two diisocyanates, each forming at least 10 mol % of the diisocyanate component and being selected from the group consisting of toluylene diisocyanate, diphenylmethane diisocyanate, dicyclohexylmethane diisocyanate, isophorone diisocyanate, trimethylhexane diisocyanate, cyclohexane diisocyanate, cyclohexanedimethylene diisocyanate and tetramethylenexylylene diisocyanate, wherein the mol % of the respective diisocyanates add up to 100 mol %, wherein the diol component comprises no more than four different diols, and 20 to 100 mol % of the diol component is formed by at least one linear aliphatic alpha,omega-C2-C12-diol, and 0 to 80 mol % by at least one (cyclo)aliphatic diol that is different from linear aliphatic alpha,omega-C2-C12-diols, wherein each diol of the diol component forms at least 10 mol % within the diol component, and wherein the mol % of the respective diols add up to 100 mol %.
    • 制备其中二异氰酸酯组分,二醇组分和摩尔比x:(x-1):2的(甲基)丙烯酸羟基-C 2 -C 4烷基酯在无溶剂下反应的聚氨酯二(甲基)丙烯酸酯的方法 并且不进行随后的纯化操作,其中x表示2至5的任何所需值,其中二异氰酸酯组分的50至80mol%由1,6-己二异氰酸酯和20至50mol%的1或2个二异氰酸酯形成, 形成至少10mol%的二异氰酸酯组分,并且选自甲苯二异氰酸酯,二苯基甲烷二异氰酸酯,二环己基甲烷二异氰酸酯,异佛尔酮二异氰酸酯,三甲基己烷二异氰酸酯,环己烷二异氰酸酯,环己烷二亚甲基二异氰酸酯和四亚甲基二亚甲基二异氰酸酯,其中相应的二异氰酸酯 添加至100摩尔%,其中二醇组分包含不超过四个不同的二醇,并且二醇组分的20至100摩尔%通过在 至少一种直链脂族α,ω-C2-C12-二醇,和至少一种不同于直链脂族α,ω-C2-C12-二醇的(环)脂族二醇,0至80mol%,其中 二醇成分在二醇成分内形成至少10摩尔%,其中相应二醇的摩尔%加至100摩尔%。
    • 78. 发明申请
    • Coating compositions and process for the production of multilayer coatings
    • 涂料组合物和生产多层涂料的方法
    • US20060069202A1
    • 2006-03-30
    • US10953311
    • 2004-09-29
    • Wiebke BeckerVolker DuecoffreCarmen FlosbachBirgit Kleuser
    • Wiebke BeckerVolker DuecoffreCarmen FlosbachBirgit Kleuser
    • C08L75/00
    • C09D175/04C08G18/4063C08G2270/00
    • An aqueous coating composition, comprising A) at least one water-dilutable hydroxy-functional binder and B) at least one polyisocyanate crosslinking agent with free isocyanate groups, wherein component A) comprises A1) 40-95 wt. % of at least one water-dilutable hydroxy-functional (meth)acrylic copolymer with a hydroxyl value of 60-250 mg of KOH/g and an acid value of 5-50 mg of KOH/g, which is obtained by free-radical copolymerization performed in a non-aqueous phase, wherein the ratio of primary hydroxyl groups to secondary hydroxyl groups in the (meth)acrylate copolymer A1) is 1:0.1 to 1:1.2 and at least 80% of the secondary hydroxyl groups result from reaction products of a monoepoxy ester and an unsaturated acid-functional monomer, and A2) 5-60 wt. % of at least one water-dilutable polyester oligomer, wherein the total of the weight percentages of component A1) and A2) add up to 100 wt. % and wherein the free-radical polymerization for the production of component A1) is performed at least in part in the presence of component A2) and/or wherein component A2) is added during polymerization or after completion of polymerization.
    • 一种水性涂料组合物,其包含A)至少一种水可稀释的羟基官能粘合剂和B)至少一种具有游离异氰酸酯基团的多异氰酸酯交联剂,其中组分A)包括A1)40-95wt。 %的羟基值为60-250mg KOH / g和酸值为5-50mg KOH / g的水可稀释的羟基官能(甲基)丙烯酸共聚物的%,它是通过自由基 在非水相中进行共聚,其中(甲基)丙烯酸酯共聚物A1)中伯羟基与仲羟基的比例为1:0.1至1:1.2,并且至少80%的仲羟基由反应产生 单环酯和不饱和酸官能单体的产物,和A2)5-60wt。 %的至少一种水可稀释的聚酯低聚物,其中组分A1)和A2)的总重量百分比加到100wt。 %,并且其中用于生产组分A1)的自由基聚合至少部分地在组分A2)和/或其中组分A2)的存在下进行,或者聚合期间或聚合完成后加入。