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    • 76. 发明授权
    • Radiation-sensitive planographic printing plate
    • 辐射敏感平版印刷版
    • US06340554B1
    • 2002-01-22
    • US09596051
    • 2000-06-16
    • Koichi KawamuraKazuo MaemotoSumiaki YamasakiTadahiro SororiHiroshi TashiroKiyotaka Fukino
    • Koichi KawamuraKazuo MaemotoSumiaki YamasakiTadahiro SororiHiroshi TashiroKiyotaka Fukino
    • G03F7004
    • B41M5/368B41C1/1041
    • An object of the present invention is to provide excellent in terms of durability wherein development with water, or direct production of the plate from digital data through infrared laser recording in particular such that a special process is not necessary, is possible, by forming on a support a photosensitive layer containing a reaction product of a compound having in a molecule thereof a functional group X and a functional group Y and a compound represented by a formula (1) stated below, or alternatively, containing a polymerization product of a compound having the functional group X and a compound represented by the formula (1) stated below. Further by incorporating water-insoluble particles in this photosensitive layer, many voids are formed in the photosensitive layer, further improving sensitivity and discrimination. The functional group X is a group selected from among a sulfonic acid ester group, a disulfone group, a sulfonimide group, and an alkoxyalkyl ester group and the functional group Y is a group selected from among —OH, —NH2, —COOH, —NH—CO—R3, and —Si(OR4)3 [wherein R3 and R4 each represents an alkyl group or an aryl group]. (R1)n—X—(OR2)4−n  (1) (1) is (R1)n—X—(OR2)4−n wherein R1 and R2 each represents an alkyl group or an aryl group; X represents Si, Al, Ti, or Zr; and n represents an integer from 0 to 2.
    • 本发明的目的在于提供优异的耐久性,其特征在于,利用水的显影,或通过红外激光记录从数字数据直接制造板,使得不需要特殊的处理,可以通过在 支持含有分子中具有官能团X和官能团Y的化合物和由下式(1)表示的化合物的反应产物的感光层,或者包含具有下式的化合物的聚合产物: 官能团X和下述式(1)表示的化合物。 此外,通过在该感光层中引入水不溶性颗粒,在感光层中形成许多空隙,进一步提高了敏感性和鉴别性。 官能团X是选自磺酸酯基,二砜基,磺酰亚胺基和烷氧基烷基酯基的基团,官能团Y是选自-OH,-NH 2,-COOH, - NH-CO-R3和-Si(OR4)3 [其中R3和R4各自表示烷基或芳基](1)为(R1)nX-(OR2)4-n,其中R1和R2各自表示 烷基或芳基; X表示Si,Al,Ti或Zr; n表示0〜2的整数。