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71. 发明授权

US4483918A Color photographic light-sensitive material 失效
标题翻译：彩色摄影感光材料
公开(公告)号：US4483918A
公开(公告)日：1984-11-20
申请号：US449803
申请日：1982-12-14
申请人： Nobuo Sakai , Yoshimasa Aotani , Yoshiharu Yabuki , Nobuo Furutachi
发明人： Nobuo Sakai , Yoshimasa Aotani , Yoshiharu Yabuki , Nobuo Furutachi
IPC分类号： G03C7/26 , G03C7/30 , G03C7/392 , G03C7/40
CPC分类号： G03C7/3012 , G03C7/39208
摘要： A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material having at least one layer containing at least one kind of 5-pyrazolone type 2-equivalent magenta coupler represented by the following general formula (Ia): ##STR1## wherein W represents phenyl substituted with at least one halogen, alkyl, alkoxy, alkoxycarbonyl or cyano; Y represents acylamino or anilino; and Z represents aryloxy, alkoxy, heterocyclic oxy, alkylthio, arylthio, heterocyclic thio, acylthio, acylamino, sulfonamido, alkoxycarbonylamino, aryloxycarbonylamino or nitrogen containing heterocyclic ring which is bonded to the active position of the pyrazolone ring through the nitrogen atom, and at least one kind of compound represented by the following general formula (II): ##STR2## wherein R.sub.1 represents substituted or unsubstituted alkyl, aralkyl, cycloalkyl or alkenyl; R.sub.2 represents hydrogen or a substituent same as defined for R.sub.1 ; Ar represents unsubstituted phenyl, phenyl, or naphthyl substituted with at least one member selected from the group consisting of halogen, carboxy and substituted or unsubstituted alkyl, aralkyl, alkenyl, cycloalkyl, alkylthio, phenyl, aryloxy, acylamino, carbamoyl, sulfonamido and sulfamoyl, and when two or more substituents are present on the phenyl group or the naphthyl group, these may be the same or different; and R.sub.1 and R.sub.2 may be bonded to each other to form a ring or each of R.sub.1 and R.sub.2 may be bonded to the ring represented by Ar to form a ring.
摘要翻译：一种卤化银彩色照相感光材料，其包含在其上涂覆有至少一个卤化银乳剂层的载体，所述彩色照相感光材料具有至少一层含有至少一种5-吡唑啉酮2-型当量品红成色剂由下列通式（Ia）表示：其中W表示被至少一个卤素，烷基，烷氧基，烷氧基羰基或氰基取代的苯基; Y表示酰氨基或苯胺基; Z表示通过氮原子键合到吡唑啉酮环的活性位置的芳氧基，烷氧基，杂环氧基，烷硫基，芳硫基，杂环硫基，酰硫基，酰氨基，亚磺酰氨基，烷氧基羰基氨基，芳氧基羰基氨基或含氮杂环，一种由以下通式（II）表示的化合物：其中R 1表示取代或未取代的烷基，芳烷基，环烷基或烯基; R2代表氢或与R1定义相同的取代基; Ar表示未取代的苯基，苯基或被选自卤素，羧基和取代或未取代的烷基，芳烷基，烯基，环烷基，烷硫基，苯基，芳氧基，酰氨基，氨基甲酰基，亚磺酰氨基和氨磺酰基中的至少一个的取代基，当苯基或萘基上存在两个以上取代基时，它们可以相同或不同; 并且R 1和R 2可以彼此键合形成环，R 1和R 2中的每一个可以键合到由Ar表示的环上以形成环。

72. 发明授权

US4407936A Process and material for forming color photographic image 失效
标题翻译：用于形成彩色摄影图像的工艺和材料
公开(公告)号：US4407936A
公开(公告)日：1983-10-04
申请号：US243159
申请日：1981-03-12
申请人： Seiji Ichijima , Toshiyuki Watanabe , Nobuo Furutachi , Nobuo Seto
发明人： Seiji Ichijima , Toshiyuki Watanabe , Nobuo Furutachi , Nobuo Seto
IPC分类号： G03C7/38 , C07D231/52 , C09B26/02 , G03C7/384 , G03C1/40
CPC分类号： G03C7/384 , C07D231/52
摘要： A color photographic light-sensitive material is described, said material comprising a support having coated thereon at least one silver halide emulsion layer containing a 5-pyrazolone magenta coupler represented by formula (I) ##EQU1## wherein R represents an acylamino group, an anilino group or a ureido group; Ar.sup.1 represents a phenyl group which may be substituted with one or more halogen groups, alkyl groups, or alkoxy groups; Ar.sup.2 represents a phenyl group or a naphthyl group, each of which may be substituted with one or more halogen groups, hydroxy groups, carboxy groups, cyano groups, alkyl groups, acylamino groups, carbamoyl groups, ureido groups, sulfonamido groups, diacylamino groups, sulfamoyl groups, alkoxycarbonyl groups, phenyl groups, arysulfonyl groups or alkoxy groups; X represents oxygen, sulfur, or a methylene group; and Y represents a straight chain or branched chain alkylene group having from 1 to 6 carbon atoms, or an alkylene group containing an ether bond.
摘要翻译：描述了一种彩色摄影感光材料，所述材料包括其上涂覆有至少一个含有式（I）表示的5-吡唑啉酮品红成色剂的卤化银乳剂层的载体，其中R表示酰氨基，苯胺基或脲基; Ar 1表示可被一个或多个卤素基团，烷基或烷氧基取代的苯基; Ar 2表示可以被一个或多个卤素基团取代的苯基或萘基，羟基，羧基，氰基，烷基，酰氨基，氨基甲酰基，脲基，亚磺酰氨基，二酰基氨基，氨磺酰基，烷氧基羰基，苯基，芳磺酰基或烷氧基; X表示氧，硫或亚甲基; Y表示具有1〜6个碳原子的直链或支链亚烷基或含有醚键的亚烷基。

73. 发明授权

US4351897A Color photographic light-sensitive material 失效
公开(公告)号：US4351897A
公开(公告)日：1982-09-28
申请号：US291886
申请日：1981-08-11
申请人： Kozo Aoki , Nobuo Seto , Yoshiharu Yabuki , Masakazu Morigaki , Nobuo Furutachi , Kotaro Nakamura
发明人： Kozo Aoki , Nobuo Seto , Yoshiharu Yabuki , Masakazu Morigaki , Nobuo Furutachi , Kotaro Nakamura
IPC分类号： G03C7/38 , C07D231/52 , C09B26/02 , G03C7/384 , G03C1/40
CPC分类号： C07D231/52 , G03C7/384
摘要： A silver halide color photographic light-sensitive material is described comprising a support having thereon a photographic layer containing at least one coupler represented by formula (I) or (II) ##STR1## wherein Ar represents a phenyl group substituted with at least one substituent selected from a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; X represents a halogen atom or an alkoxy group; R.sub.1 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acylamino group, a sulfonamido group, a sulfamoyl group, a carbamoyl group, a diacylamino group, an alkoxycarbonyl group, an alkoxysulfonyl group, an aryloxysulfonyl group, an alkanesulfonyl group, an arylsulfonyl group, an alkylthio group, an arylthio group, an alkyloxycarbonylamino group, an alkylureido group, an acyl group, a nitro group, a carboxy group, or a trifluoromethyl group; R.sub.2 represents a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; R.sub.3 represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; at least one of R.sub.2 and R.sub.3 represents an alkoxy group; m.sub.1 and m.sub.2 each represents an integer from 1 to 4; R.sub.4 represents an alkyl group or an aryl group; R.sub.5 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or an aryl group; n represents an integer from 1 to 6; and when m.sub.1, m.sub.2 and n each is 2 or more, each R.sub.1, R.sub.3 and R.sub.5 may be the same or different.The color photographic light-sensitive material containing a 2-equivalent magenta color image-forming coupler as described above has various advantages, for example, in that the dye formation efficiency in the color development step is high, the photographic properties are not influenced by variations in the pH of the color development bath, and the color images formed are fast to heat or light.

74. 发明授权

US4346165A Process for improving light fastness of color images 失效
标题翻译：提高彩色图像耐光性的方法
公开(公告)号：US4346165A
公开(公告)日：1982-08-24
申请号：US223665
申请日：1981-01-19
申请人： Satoru Sawada , Shigeru Oono , Nobuo Seto , Yoshiaki Suzuki , Kotaro Nakamura , Nobuo Furutachi
发明人： Satoru Sawada , Shigeru Oono , Nobuo Seto , Yoshiaki Suzuki , Kotaro Nakamura , Nobuo Furutachi
IPC分类号： G03C7/26 , G03C1/815 , G03C7/38 , G03C7/392 , G03C7/00
CPC分类号： G03C7/39296
摘要： A process for improving the light fastness of a magenta color image which comprises introducing a specific complex and a specific discoloration prevention aid into a layer bearing the magenta color image.
摘要翻译：一种用于提高品红色图像的耐光性的方法，其包括将特定复合物和特定变色防止助剂引入到承载品红色图像的层中。

75. 发明授权

US4332886A Color photographic light-sensitive material including an organic spirobis compound color coupler 失效
标题翻译：彩色照相感光材料，包括有机螺二色复合颜色成色剂
公开(公告)号：US4332886A
公开(公告)日：1982-06-01
申请号：US195166
申请日：1980-10-08
申请人： Kozo Aoki , Tetsuro Kojima , Nobuo Furutachi , Satoru Sawada
发明人： Kozo Aoki , Tetsuro Kojima , Nobuo Furutachi , Satoru Sawada
IPC分类号： G03C7/26 , C07D317/44 , C07D317/46 , C07D317/50 , C07D317/54 , C07D317/62 , C07D317/64 , C07D319/18 , C07D319/22 , C07D321/10 , C07D493/04 , C07D493/06 , C07D493/08 , C07D493/22 , G03C1/06 , G03C7/392 , G03C1/10
CPC分类号： C07D493/04 , C07D317/44 , C07D317/46 , C07D317/50 , C07D317/54 , C07D317/62 , C07D317/64 , C07D319/18 , C07D319/22 , C07D321/10 , C07D493/06 , G03C7/39268
摘要： A color photographic light-sensitive material containing, in a photographic layer, a coupler and at least one compound represented by the formula (I), or at least one bis-compound (inclusive spirobis-compound) thereof, ##STR1## wherein Z represents an alkylene group having from 1 to 3 carbon atoms which can be substituted with one or more of hydrogen, a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a.dbd.S group or a.dbd.O group; and R.sub.1, R.sub.2, R.sub.3, and R.sub.4 each represents hydrogen, a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an acyl group, an acylamino group, a sulfonamido group, a diacylamino group, a carboxy group, a sulfo group, or a hydroxy group, or R.sub.1 and R.sub.2 and R.sub.3 together form a group represented by ##STR2## (wherein Z has the same meaning as Z in formula (I)) or a 5-membered or 6-membered hydrocarbon ring or hetero-cyclic ring is described.The compounds represented by formula (I) are effective in preventing the fading of dye images formed upon color development of the color photographic light-sensitive material and the occurrence of yellow stain in non-image areas due to the action of light, humidity or heat.
摘要翻译：在照相层中含有由式（I）表示的至少一种化合物或其至少一种双 - 化合物（包括它们的双螺旋体化合物）的彩色照相感光材料，其中Z表示可以被一个或多个氢，卤素原子，烷基，芳基，烷氧基，芳氧基，a = S基团取代的具有1至3个碳原子的亚烷基， = O组; R 1，R 2，R 3和R 4各自表示氢，卤素原子，烷基，芳基，烷氧基，芳氧基，烷硫基，酰基，酰氨基，亚磺酰氨基，二酰基氨基，羧基，磺基或羟基，或R 1和R 2和R 3一起形成由下式表示的基团（其中Z具有与式（I）中的Z相同的含义）或5- 6元或6元烃环或杂环。由式（I）表示的化合物可有效地防止由于光，湿或热的作用引起的在彩色照相感光材料的显色中形成的染料图像的褪色和非图像区域中的黄染色的发生。

76. 发明授权

US4264723A Silver halide color photographic materials 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US4264723A
公开(公告)日：1981-04-28
申请号：US91663
申请日：1979-11-05
申请人： Seiji Ichijima , Nobuo Seto , Toshiyuki Watanabe , Nobuo Furutachi
发明人： Seiji Ichijima , Nobuo Seto , Toshiyuki Watanabe , Nobuo Furutachi
IPC分类号： G03C7/38 , C07D231/52 , C09B26/02 , G03C7/384 , G03C1/40
CPC分类号： C07D231/52 , G03C7/384
摘要： Silver halide color photographic sensitive materials which comprise photographic layers containing at least one of the couplers represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an anilino group, an acylamino group or a ureido group, R.sub.2 represents an alkyl group, an aralkyl group or an alkenyl group, X.sub.1, X.sub.2 and X.sub.3 each represents a hydrogen atom, an alkyl group, a halogen atom, an alkoxy group, an aryloxy group, an acylamino group, a carbamoyl group, a sulfamoyl group, a sulfonyl group, a cyano group or an alkoxycarbonyl group and X.sub.1, X.sub.2 and X.sub.3 may be the same or different, are disclosed.
摘要翻译：卤化银彩色照相感光材料，其包含含有由以下通式（I）表示的至少一种成色剂的照相层：其中R 1表示苯胺基，酰氨基或脲基，R 2表示烷基，芳烷基或烯基，X1，X2和X3各自表示氢原子，烷基，卤素原子，烷氧基，芳氧基，酰氨基，氨基甲酰基，氨磺酰基，磺酰基，氰基或烷氧基羰基，X 1，X 2和X 3可以相同或不同。

77. 发明授权

US4220470A Silver halide material containing photographic magenta coupler 失效
标题翻译：含有摄影品红色成色剂的卤化银材料
公开(公告)号：US4220470A
公开(公告)日：1980-09-02
申请号：US881318
申请日：1978-02-27
申请人： Nobuo Furutachi , Kotaro Nakamura , Atsuaki Arai , Minoru Yamada , Keisuke Shiba
发明人： Nobuo Furutachi , Kotaro Nakamura , Atsuaki Arai , Minoru Yamada , Keisuke Shiba
IPC分类号： G03C7/38 , C09B26/02 , G03C7/305 , G03C7/384 , G03C7/00 , G03C1/40
CPC分类号： G03C7/30529 , G03C7/384
摘要： A photographic two-equivalent magenta coupler represented by the following general formula (I): ##STR1## wherein (A) represents a residue of a magenta color image-forming coupler in which one of the hydrogen atoms in the coupling position is eliminated; Q represents an oxygen atom or NH group; and B represents the non-metallic atoms necessary to form a 5-membered or a 6-membered ring containing the nitrogen atom and the ##STR2## group. Color photographic light-sensitive materials containing the two-equivalent magenta coupler are also described.
摘要翻译：由下列通式（I）表示的照相双等效品红成色剂：其中（A）表示连接位置的氢原子之一为品红色成像剂的残基，淘汰 Q表示氧原子或NH基团; B表示形成含有氮原子和基团的5元或6元环所必需的非金属原子。还描述了含有两当量品红色成色剂的彩色照相感光材料。

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