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71. 发明申请

US20140243568A1 Method for Making a Catalyst Comprising a Phosphorous Modified Zeolite and Use of Said Zeolite 审中-公开
标题翻译：制备包含磷改性沸石的催化剂的方法和所述沸石的用途
公开(公告)号：US20140243568A1
公开(公告)日：2014-08-28
申请号：US14236736
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
IPC分类号： B01J29/85 , C07C4/06 , C07C2/08 , C07C2/86 , C07C1/22
CPC分类号： B01J29/85 , B01J29/40 , B01J29/65 , B01J29/7023 , B01J29/7026 , B01J29/7038 , B01J29/7042 , B01J29/7046 , B01J37/0009 , B01J37/10 , B01J37/28 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C1/24 , C07C2/08 , C07C2/66 , C07C2/864 , C07C4/06 , C07C2521/08 , C07C2527/14 , C07C2529/40 , C07C2529/65 , C10G3/49 , C10G29/205 , C10G29/22 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/08 , C07C15/46 , C07C15/08
摘要： A method to make a phosphorus modified zeolite can include providing a zeolite including at least one ten member ring in the structure steaming the zeolite, mixing the zeolite with one or more binders and shaping additives, and then shaping the mixture. The method can include making a ion-exchange. The shaped mixture can be steamed. Phosphorous can be introduced on the catalyst to introduce at least 0.1 wt % of phosphorus, such as be dry impregnation or chemical vapor deposition. A metal, such as calcium, can be introduced. The catalyst can be washed, calcinated, and then steamed. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatics by alcohols with olefins and/or alcohols.
摘要翻译：制备磷改性沸石的方法可以包括提供在蒸汽沸石的结构中包括至少一个十元环的沸石，将沸石与一种或多种粘合剂和成型添加剂混合，然后使混合物成型。该方法可以包括进行离子交换。成型的混合物可以蒸。可以在催化剂上引入磷以引入至少0.1重量％的磷，例如干浸渍或化学气相沉积。可以引入金属，如钙。催化剂可以洗涤，煅烧，然后蒸。蒸汽浓度（X）可以至少约为2.催化剂可以在高于625℃的温度下蒸煮，例如700-800℃的温度。催化剂可用于醇脱水，烯烃裂解，MTO方法，以及通过醇与烯烃和/或醇烷基化芳族化合物。

72. 发明申请

US20140194662A1 Method for Making a Catalyst Comprising a Phosphorous Modified Zeolite and Use of Said Zeolite 审中-公开
标题翻译：制备包含磷改性沸石的催化剂的方法和所述沸石的用途
公开(公告)号：US20140194662A1
公开(公告)日：2014-07-10
申请号：US14236750
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
IPC分类号： B01J29/85 , C07C2/66 , C07C2/86 , C07C1/24 , C07C4/06
CPC分类号： B01J29/85 , B01J29/40 , B01J29/405 , B01J29/65 , B01J29/655 , B01J29/70 , B01J29/7023 , B01J29/7026 , B01J29/7038 , B01J29/7042 , B01J29/7046 , B01J29/7049 , B01J29/7088 , B01J29/7096 , B01J37/0009 , B01J37/0201 , B01J37/0209 , B01J37/10 , B01J37/28 , B01J2229/186 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C1/24 , C07C2/08 , C07C2/66 , C07C2/864 , C07C4/06 , C07C2521/08 , C07C2527/14 , C07C2529/40 , C07C2529/65 , C10G3/49 , C10G29/205 , C10G29/22 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/08 , C07C15/46 , C07C15/08
摘要： A method to make a phosphorus modified zeolite can include providing a zeolite having at least one ten member ring, making an ion-exchange, steaming the zeolite, and introducing phosphorus on the zeolite. The zeolite can be mixed with one or more binders and shaping additives, and then shaped. A metal can be introduced, and the catalyst can be washed, calcined, and steamed in an equilibration step. The steaming can be at performed at a steam severity (X) of at least about 2. The steaming can be performed at a temperature above 625° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatics by alcohols with olefins and/or alcohols.
摘要翻译：制备磷改性沸石的方法可以包括提供具有至少一个十元环的沸石，进行离子交换，蒸煮沸石，并在沸石上引入磷。沸石可以与一种或多种粘合剂和成型添加剂混合，然后成型。可以引入金属，并且可以在平衡步骤中对催化剂进行洗涤，煅烧和蒸煮。蒸汽可以在至少约2的蒸汽苛刻度（X）下进行。蒸汽可以在高于625℃的温度下进行。催化剂可用于醇脱水，烯烃裂解，MTO方法和烷基化醇与烯烃和/或醇的芳族化合物。

73. 发明申请

US20140148630A1 PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 有权
标题翻译：从ISOBUTANOL制造OLEFINS的过程
公开(公告)号：US20140148630A1
公开(公告)日：2014-05-29
申请号：US13813168
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22
CPC分类号： C07C1/24 , B01J29/40 , B01J2229/42 , C07C1/22 , C07C4/06 , C07C6/04 , C07C2529/40 , C08F10/02 , C10G3/42 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： The present invention relates to a process for the conversion of an alcohol mixture (A) comprising about 20 w % to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 450° C. in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising: ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，任选的水，任选的惰性组分，b）在有效使至少一部分异丁醇和其它醇脱水的条件下，使所述物流与催化剂（A1）在高于450℃的温度下在所述反应器（A）中接触， c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的混合物（A）的醇，各种烃和步骤a）的任选的惰性组分的流出物， d）将步骤c）的所述流出物分馏以产生至少一种乙烯流，丙烯流，基本上由具有4个碳原子或更多的烃组成的级分，水和步骤a）的任选的惰性组分，任选地将乙烯全部回收或在par 在反应器（A）的入口处，任选地在反应器（A）的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分。

74. 发明授权

US08535515B2 Hydrotreating and/or hydrocracking catalyst of hydrocarbons and preparation thereof 有权
标题翻译：烃的加氢处理和/或加氢裂化催化剂及其制备
公开(公告)号：US08535515B2
公开(公告)日：2013-09-17
申请号：US10567564
申请日：2004-08-04
申请人： Thierry Cholley , Jean-Pierre Dath
发明人： Thierry Cholley , Jean-Pierre Dath
IPC分类号： B01J23/882
CPC分类号： B01J31/0254 , B01J23/85 , B01J23/88 , B01J23/882 , B01J37/0203 , B01J37/0236 , B01J37/20 , C10G45/08 , C10G47/12 , C10G2300/70
摘要： The invention relates to a hydroconversion catalyst, which comprises a refractory oxide support, at least one metal selected from group VIII and at least one metal selected from group VIB and which is characterized in that it has at least one organic compound containing at least one oxime group of formula (I)>C═NOR1, in which R1 is selected among hydrogen and alkyl, allyl, aryl, alkylene or cycloaliphatic groups, and combinations thereof, these groups being able to be substituted by at least one electron donor group.
摘要翻译：本发明涉及一种加氢转化催化剂，其包含难熔氧化物载体，至少一种选自VIII族的金属和至少一种选自VIB族的金属，其特征在于其具有至少一种含有至少一个肟的有机化合物式（I）的基团C = NOR1，其中R 1选自氢和烷基，烯丙基，芳基，亚烷基或脂环族基团，及其组合，这些基团能够被至少一个电子给体基团取代。

75. 发明申请

US20130204058A1 COMBINED PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 有权
公开(公告)号：US20130204058A1
公开(公告)日：2013-08-08
申请号：US13813107
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/24 , C07C4/06
CPC分类号： C07C1/24 , B01J21/04 , B01J29/40 , B01J29/65 , C07C4/06 , C07C2521/04 , C07C2529/40 , C07C2529/65 , C07C2529/85 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w % to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) (also called the first reaction zone or low temperature reaction zone) a stream comprising the mixture (A), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) in said reactor (A) at conditions effective to dehydrate: at least a portion of the isobutanol to essentially butenes, at least a portion of other alcohols, if any, to essentially olefins other than butene having the same carbon number as the alcohol precursor, c) recovering from said reactor (A) an effluent comprising: butenes, optionally olefins other than butene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to remove a portion or all the water, unconverted alcohols, optionally the inert component, and optionally the whole or a part of the various hydrocarbons to get a stream (D) comprising essentially olefins and optionally the inert component, e) introducing at least a part of said stream (D) in an OCP reactor (also called the second reaction zone or high temperature zone), f) contacting said stream comprising at least a part of (D), optionally in combination with a stream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins), in said OCP reactor with a catalyst which is selective towards light olefins in the effluent, to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, g) fractionating said effluent of step f) to produce at least an ethylene stream, a propylene stream and a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, optionally recycling ethylene in whole or in part at the inlet of the OCP reactor of step f), or at the inlet of the reactor (A) or at the inlet of both the OCP reactor of step f) and the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the OCP reactor.

76. 发明申请

US20110190561A1 Process for Making Crystalline Metallosilicates 审中-公开
标题翻译：制备结晶金属硅酸盐的方法
公开(公告)号：US20110190561A1
公开(公告)日：2011-08-04
申请号：US12994561
申请日：2009-02-24
申请人： Metin Bulut , Pierre Jacobs , Delphine Minoux , Nikolai Nesternko , Jean-Pierre Dath , Sander Van Donk
发明人： Metin Bulut , Pierre Jacobs , Delphine Minoux , Nikolai Nesternko , Jean-Pierre Dath , Sander Van Donk
IPC分类号： C07C1/20 , C01B39/00 , C01B39/02
CPC分类号： B01J29/40 , B01J2229/62 , C01B37/005 , C01B39/02 , C01B39/04 , C01B39/38 , C01B39/40 , C07C2/864 , C07C2529/70 , C10G29/205 , Y02P20/52 , C07C15/08
摘要： The present invention relates to a process for making a crystalline metallosilicate composition comprising crystallites having an inner part (the core) and an outer part (the outer layer or shell) such that: the ratio Si/metal is higher in the outer part than in the inner part, the crystallites have a continuous distribution of metal and silicon over the crystalline cross-section, said process comprising: a) providing an aqueous medium comprising OH— anions and a metal source, b) providing an aqueous medium comprising an inorganic source of silicon and optionally a templating agent, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to crystallyze the desired metallosilicate, e) recovering the desired metallosilicate, wherein in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is
摘要翻译：本发明涉及一种制备结晶金属硅酸盐组合物的方法，其包含具有内部部分（芯部）和外部部分（外层或外壳）的微晶，使得：外部部分的Si /金属比例高于所述内部部分，所述微晶在结晶截面上具有金属和硅的连续分布，所述方法包括：a）提供包含OH-阴离子和金属源的水性介质，b）提供包含无机源的水性介质的硅和任选的模板剂，c）任选地提供包含任选的二氧化硅有机源的非水性液体培养基，d）在有效地使所需的金属硅酸盐水解的条件下，将培养基a），b）和任选的c））回收所需的金属硅酸盐，其中在混合物a）+ b）+ c）中，在结晶之前，Si org / Si无机物的比例<0.3，有利地<0.2，优选为0，摩尔浓度 tio OH- / SiO 2为至少0.3，有利地为0.3至0.62，优选为0.31至0.61，更优选为0.32至0.61，非常优选为0.33至0.6，混合物a）+ b）+ c），在结晶之前，高于13，优选高于13.1，更优选高于13.2，还更优选高于13.3，最优选高于13.4。

77. 发明申请

US20080194892A1 Hydroprocessing Catalyst, Preparation Method Thereof and Use of Same 有权
标题翻译：加氢催化剂及其制备方法及用途
公开(公告)号：US20080194892A1
公开(公告)日：2008-08-14
申请号：US11795411
申请日：2006-01-19
申请人： Thierry Cholley , Jean-Pierre Dath , Claude Brun , Georges Fremy , Francis Humblot
发明人： Thierry Cholley , Jean-Pierre Dath , Claude Brun , Georges Fremy , Francis Humblot
IPC分类号： B01J31/26 , C07C4/06
CPC分类号： B01J31/0209 , B01J21/04 , B01J23/85 , B01J23/882 , B01J23/94 , B01J37/0203 , B01J37/20 , B01J38/52 , C10G45/04 , C10G45/08
摘要： The invention relates to a hydrocarbon hydroprocessing catalyst comprising a support based on at least one refractory oxide, at least one metal from group VIII and at least one metal from group VIB. The inventive catalyst is characterised in that it also comprises at least one organic compound having formula (I) or (II) in which each R1 represents independently an alkyl group at C1-18, an alkenyl group at C2-18, an aryl group at C6-18, a cycloalkyl group at C3-8, an alkylaryl or arylalkyl group at C7-20, or the two R1 groups together form a divalent group at C2-18, and R2 represents an alkylene group at C1-18, an arylene group at C6-18, a cycloalkylene group at C3-7, or a combination of same. The invention also relates to a method of preparing one such catalyst and to the use thereof for hydroprocessing or hydrocracking.
摘要翻译：本发明涉及一种烃加氢处理催化剂，其包含基于至少一种难熔氧化物的载体，至少一种VIII族金属和至少一种VIB族金属。本发明的催化剂的特征在于其还包含至少一种具有式（I）或（II）的有机化合物，其中每个R 1独立地表示C 1-18上的烷基， C 2〜C 18的链烯基，C 6-18的芳基，C 3〜C 8的环烷基 >，C 7-20的烷基芳基或芳基烷基或两个R 1个基团一起在C 2-18位上形成二价基团，，R 2表示C 1-18亚烷基，C 6-18亚烷基，C 6-18亚环烷基， SUB> 3-7 ，或其组合。本发明还涉及制备一种这样的催化剂的方法及其用于加氢处理或加氢裂化的方法。

78. 发明申请

US20080087577A1 Hydroprocessing Catalyst, Method for the Preparation Thereof and Use of the Same 有权
标题翻译：加氢处理催化剂及其制备方法及其应用
公开(公告)号：US20080087577A1
公开(公告)日：2008-04-17
申请号：US11795519
申请日：2006-01-19
申请人： Thierry Cholley , Jean-Pierre Dath , Claude Brun , Georges Fremy , Francis Humblot
发明人： Thierry Cholley , Jean-Pierre Dath , Claude Brun , Georges Fremy , Francis Humblot
IPC分类号： B01J23/88 , B01J23/94 , B01J37/20 , B01J38/52 , C10G45/08
CPC分类号： C10G47/12 , B01J21/04 , B01J23/85 , B01J23/882 , B01J23/94 , B01J31/0202 , B01J37/0203 , B01J37/20 , B01J38/52 , C10G45/04 , C10G45/08 , C10G47/06 , C10G47/10 , C10G2300/1037 , C10G2300/301 , C10G2300/44 , C10G2300/703
摘要： The invention relates to a hydrocarbon hydroconversion catalyst comprising a carrier based on refractory oxide, a metal of the group VIII, and a metal of the group VIB. Said catalyst is characterised in that it also comprises at least one organic compound selected from the alkene diols of formula (I) wherein R1 represents a C2-10 alkenylene group, preferably C2-4 alkenylene, a C6-18 arylene group, or a C7-18 alkylene-arylene group, and each R2 independently represents a hydrogen atom or a C1-18 alkyl group, a C1-18 alkenyl group, a C6-18 aryl group, a C3-8 cycloalkyl group, or a C7-20 alkylaryl or arylalkyl group, or the two groups R2 together form a divalent C2-18 group, the carbonated chain of the R2 groups containing or carrying at least one heteroatom selected from S, N and O. The invention also relates to a method for preparing one such catalyst, and to the use of said catalyst for hydrotreatment or hydroconversion.
摘要翻译：本发明涉及一种烃加氢转化催化剂，其包含基于难熔氧化物的载体，第Ⅷ族金属和VIB族金属。所述催化剂的特征在于其还包含至少一种选自式（I）的烯二醇的有机化合物，其中R 1代表C 2〜10亚烯基，优选C 2-4亚烯基，C 6-18亚芳基或C 7-18亚烷基亚芳基，每个R 独立地表示氢原子或C 1-18烷基，C 1-18链烯基，C 6 -18芳基，C 3-8环烷基或C 7-20烷基芳基或芳基烷基，或两个基团R 1， 2一起形成二价C 2-18基团，含有或携带至少一个选自S，N的杂原子的R 2 2基团的碳酸化链和本发明还涉及一种制备这种催化剂的方法，以及所述催化剂用于加氢处理或加氢转化的方法。

79. 发明授权

US06489428B1 Titanated chromium-based catalysts to produce polyethylene 有权
标题翻译：钛酸化的铬基催化剂生产聚乙烯
公开(公告)号：US06489428B1
公开(公告)日：2002-12-03
申请号：US09712462
申请日：2000-11-14
申请人： Guy Debras , Jean-Pierre Dath
发明人： Guy Debras , Jean-Pierre Dath
IPC分类号： C08F11002
CPC分类号： C08F10/00 , C08F210/16 , Y02P20/52 , C08F210/14 , C08F2500/07 , C08F2500/12 , C08F2500/17 , C08F2500/04 , C08F2500/13 , C08F4/025 , C08F4/22 , C08F4/69146
摘要： The present invention relates to a supported chromium-based catalyst titanated under specific conditions and used for the homopolymerisation or the copolymerisation of ethylene. The polyethylene obtained with this catalyst has high shear resirance and environmental stress crack resistance, and can be used for manufacturing films with improved tear properties.
摘要翻译：本发明涉及在特定条件下钛酸化并用于乙烯的均聚或共聚的负载型铬基催化剂。用该催化剂得到的聚乙烯具有高剪切抗拉性和耐环境应力开裂性，可用于制造具有改进的撕裂性能的膜。

80. 发明授权

US6015866A Production of polyethylene having a bimodal molecular weight distribution 失效
标题翻译：生产具有双峰分子量分布的聚乙烯
公开(公告)号：US6015866A
公开(公告)日：2000-01-18
申请号：US996256
申请日：1997-12-22
申请人： Guy Debras , Jean-Pierre Dath
发明人： Guy Debras , Jean-Pierre Dath
IPC分类号： C08F4/02 , C08F4/24 , C08F4/69 , C08F10/02 , C08F210/16 , C08F4/06
CPC分类号： C08F10/02 , C08F210/16 , Y02P20/52
摘要： A process for producing high density polyethylene, the process comprising polymerising ethylene, or copolymerising ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms, in the presence of a catalyst system comprising first and second chromium-based catalysts, the first chromium-based catalyst having been reduced and reoxidised and the second chromium-based catalysts having been activated, fluordised before or during the activation step, and reduced, the first and second chromium-based catalysts having a pore volume difference of at least O.8 cc/g. There is further provided a catalyst system for the production of high density polyethylene by polymerising ethylene or copolymerising ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms, the catalyst system comprising first and second chromium-based catalysts, the first chromium-based catalyst having been reduced and reoxidised and the second chromium-based catalyst having been activated, fluoridised before or after the activation step, and reduced, and the first and second chromium-based catalysts having a pore volume difference of at least 0.8 cc/g. There is further provided the use of the catalyst system for increasing the bimodalty of the molecular weight distribution of a high density polyethylene.
摘要翻译：一种生产高密度聚乙烯的方法，该方法包括在包含第一和第二铬基催化剂的催化剂体系存在下聚合乙烯或共聚乙烯和含有3-10个碳原子的α-烯烃共聚单体，第一种铬的催化剂已经被还原和再氧化，并且第二铬基催化剂已经被活化，在活化步骤之前或期间发黄，并且还原了具有至少O.8cc的孔体积差的第一和第二种铬基催化剂 /G。还提供了一种用于通过聚合乙烯或共聚乙烯和包含3至10个碳原子的α-烯烃共聚单体生产高密度聚乙烯的催化剂体系，所述催化剂体系包含第一和第二铬基催化剂，第一铬 - 已经还原和再氧化并且第二铬基催化剂已经在活化步骤之前或之后被活化，氟化并还原，并且第一和第二铬孔催化剂的孔体积差异至少为0.8cc / g 。还提供了用于增加高密度聚乙烯的分子量分布的双峰的催化剂体系的用途。

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