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71. 发明授权

US5102443A Heterocyclically substituted phenoxysulfonylureas, and the use thereof as herbicides or plant growth regulators 失效
公开(公告)号：US5102443A
公开(公告)日：1992-04-07
申请号：US351958
申请日：1989-05-15
申请人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
发明人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
IPC分类号： A01N47/34 , A01N47/36 , A01P13/00 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D249/14 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/26 , C07D251/46 , C07D251/50 , C07D251/52 , C07D251/70 , C07D471/04 , C07D473/32 , C07D475/00 , C07D487/04 , C07D491/044 , C07D491/048 , C07D491/052 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Heterocyclically substituted phenoxysulfonylureas, processes for the preparation thereof, and the use thereof as herbicides or plant growth regulators. Compounds of the formula I or the salts thereof ##STR1## where R.sup.1 is (C.sub.1 -C.sub.8)alkyl, (C.sub.2 -C.sub.8)alkenyl or (C.sub.2 -C.sub.8)alkynyl, these radicals being substituted by halogen, saturated or unsaturated (C.sub.1 -C.sub.6)alkoxy, (C.sub.1 -C.sub.6)alkylthio, -sulfinyl or -sulfonyl, (C.sub.1 -C.sub.6)alkoxycarbonyl, NO.sub.2, CN or phenyl; furthermore is (C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl or (C.sub.3 -C.sub.8)cycloalkyl, which can be substituted by halogen or by alkoxy or alkylthio; (C.sub.5 -C.sub.8)cycloalkenyl, cyclopropylmethyl, epoxypropyl; furfuryl, tetrahydrofurfuryl or phenoxy (C.sub.1 -C.sub.4)alkyl, it being possible for the last three substituents mentioned to be substituted by halogen, alkyl or alkoxy; or phenyl which can be substituted by halogen, alkyl, alkoxy, NO.sub.2, CF.sub.3, CN or OCHF.sub.2 ; or, in the event that R.sup.2 is alkenyl, alkynyl, phenyl or phenoxy, each of which can be substituted as indicated below, alkylsulfonyl or alkylsulfinyl and n.noteq., R.sup.1 is also (C.sub.1 -C.sub.8)alkyl,R.sup.2 radicals independently of one another are (C.sub.1 -C.sub.8)-alkyl, (C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, phenyl, phenoxy, (C.sub.1 -C.sub.4)alkoxy, (C.sub.1 -C.sub.4)alkylthio, (C.sub.1 -C.sub.4)-alkoxycarbonyl, (C.sub.2 -C.sub.4)alkenyloxycarbonyl, (C.sub.2 - C.sub.4)alkynyloxycarbonyl, it being possible for all the abovementioned radicals to be substituted by halogen, (C.sub.1 -C.sub.4)alkoxy or (C.sub.1 -C.sub.4)alkylthio; furthermore halogen, NO.sub.2, (C.sub.1 -C.sub.4)alkylsulfonyl or (C.sub.1 -C.sub.4)alkylsulfinyl;n is 0, 1, 2 or 3; y is O or S;R.sup.3 is hydrogen, (C.sub.1 -C.sub.8)alkyl, (C.sub.2 -C.sub.8)alkenyl, (C.sub.3 -C.sub.8)-alkynyl or (C.sub.1 -C.sub.4)alkoxy;R.sup.4 is a heterocyclic radical of the formulae ##STR2## E is CH or N, G is O or CH.sub.2,R.sup.5 and R.sup.6 are hydrogen, halogen, alkyl, alkoxy or alkylthio, it being possible for the abovementioned alkyl-containing radicals to be substituted by halogen, alkoxy or alkylthio, furthermore a radical of the formula --NR.sup.12 R.sup.13, --OCHR.sup.7 --CO.sub.2 R.sup.12, cycloalkyl, alkenyl, alkynyl, alkenyloxy or alkynyloxy,R.sup.7 is hydrogen or alkyl; R.sup.8 is alkyl, --CHF.sub.2 or --CH.sub.2 CF;R.sup.9 and R.sup.10 are hydrogen, alkyl, alkoxy or halogen, R.sup.11 is hydrogen, alkyl, --CHF.sub.2 or CH.sub.2 CF.sub.3, and R.sup.12 and R.sup.13 are hydrogen, alkyl, alkenyl or alkynyl, have outstanding herbicidal and plant growth-regulating properties.

72. 发明授权

US5015284A Alkyl- and alkenylsulfonylureas which are substituted in the heterocycle, and their use as herbicides or plant growth regulators 失效
标题翻译：在杂环中被取代的烷基和烯基磺酰脲，以及它们作为除草剂或植物生长调节剂的用途
公开(公告)号：US5015284A
公开(公告)日：1991-05-14
申请号：US334695
申请日：1989-04-06
申请人： Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
发明人： Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
IPC分类号： A01N47/34 , A01N47/36 , C07D239/26 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D239/70 , C07D249/14 , C07D251/42 , C07D405/12 , C07D471/04 , C07D473/16 , C07D473/18 , C07D473/32 , C07D473/40 , C07D475/00 , C07D475/02 , C07D475/06 , C07D487/04 , C07D491/048 , C07D491/052 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Compounds of the formula I, their stereoisomers or their salts ##STR1## wherein A denotes >C(R.sup.4).sub.2 or >C.dbd.C(R.sup.5).sub.2 ; R.sup.1 denotes H, an optionally substituted aliphatic or cycloaliphatic radical, forfuryl, tetrahydrofurfuryl or (substituted) phenyl; R.sup.2 denotes H, alkyl, alkenyl, alkynyl or alkoxy; R.sup.3 denotes a radical of the formulae ##STR2## X denotes O, S or NR.sup.12 and Y denotes O or S, possess excellent herbicidal and plant-growth regulating properties.
摘要翻译：式I化合物，其立体异构体或其盐其中A表示> C（R 4）2或> C = C（R 5）2; R 1表示H，任选取代的脂族或脂环族基，糠基，四氢糠基或（取代的）苯基; R2表示H，烷基，烯基，炔基或烷氧基; R 3表示式的基团，其中X表示O，S或NR 12，Y表示O或S，具有优异的除草和植物生长调节性质。

73. 发明授权

US4925480A Heterocyclically substituted N-sultamsulfonamides, and their use as herbicides and plant growth regulators 失效
标题翻译：杂环取代的N-磺基磺酰胺，以及它们作为除草剂和植物生长调节剂的用途
公开(公告)号：US4925480A
公开(公告)日：1990-05-15
申请号：US263817
申请日：1988-10-28
申请人： Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
发明人： Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
IPC分类号： A01N47/36 , C07D417/12 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Compounds of the formula I or their salts ##STR1## wherein R.sup.1 and R.sup.2 denote H, halogen, alkyl, alkenyl, alkynyl or alkoxy, which can be substituted, or denote --(CH.sub.2).sub.n --COOR.sup.11 ;R.sup.3 denotes H, alkyl, alkenyl or alkynyl;R.sup.4 denotes a heterocyclic radical of the formulae ##STR2## where E is CH or N; X is O or S nd a, b, c, d, e in each case denote 0, 1 or 2, with the proviso that c+d+e.gtoreq.2, possess excellent herbicidal and plant growth-regulating properties.
摘要翻译：式I化合物或其盐（Ⅰ）其中R1和R2表示可被取代的或表示 - （CH2）n-COOR11的H，卤素，烷基，烯基，炔基或烷氧基。 R3表示H，烷基，烯基或炔基; R4表示式为“IMAGE”的杂环基，其中E为CH或N; X为O或S a，b，c，d，e各自表示0,1或2，条件是c + d + e> / = 2具有优异的除草和植物生长调节性质。

74. 发明授权

US4614535A Herbicidal imidazolinones 失效
标题翻译：除草咪唑啉酮
公开(公告)号：US4614535A
公开(公告)日：1986-09-30
申请号：US669620
申请日：1984-11-08
申请人： Roland Schmierer , Reinhard Handte , Rainer Liebl , Hilmar Mildenberger , Klaus Bauer , Hermann Bieringer , Helmut Burstell
发明人： Roland Schmierer , Reinhard Handte , Rainer Liebl , Hilmar Mildenberger , Klaus Bauer , Hermann Bieringer , Helmut Burstell
IPC分类号： A01N43/50 , C07D233/70 , C07D233/86 , C07D235/02 , C07D401/04 , C07D401/02
CPC分类号： C07D235/02 , C07D233/70 , C07D401/04
摘要： Imidazolinones of the formula ##STR1## in which A denotes N or C--R.sup.4 ; B denotes halogenoalkyl, alkoxymethyl, cyanomethyl or thiocyanatomethyl; X denotes alkyl; and Y denotes alkyl, cycloalkyl, alkenyl, phenyl or benzyl; or X and Y, together with C, denote a spiro-cycloalkyl group; Z denotes H, (substituted) alkyl, alkenyl, propargyl or an alkyl, carboxylic acid ester or sulfonic acid ester group; and R.sup.1 -R.sup.4 denote H, halogen, alkyl, alkoxy, alkoxycarbonyl, halogenoalkyl, NO.sub.2, CN, (substituted) phenoxy or (substituted) phenyl, or in each case two adjacent radicals together denote the radical --CH.dbd.CH--CH--CH--, are active herbicides and growth regulators.
摘要翻译：式（I）的咪唑啉酮，其中A表示N或C-R4; B表示卤代烷基，烷氧基甲基，氰基甲基或硫代氰基甲基; X表示烷基; Y表示烷基，环烷基，烯基，苯基或苄基; 或X和Y与C一起表示螺环烷基; Z表示H，（取代的）烷基，烯基，炔丙基或烷基，羧酸酯或磺酸酯基; 并且R 1 -R 4表示H，卤素，烷基，烷氧基，烷氧基羰基，卤代烷基，NO 2，CN，（取代的）苯氧基或（取代的）苯基，或者在每种情况下两个相邻的基团一起表示基团-CH = CH-CH-CH - 是活性除草剂和生长调节剂。

75. 发明授权

US4531969A Herbicidal esters of D-1-(phenoxy-4-phenoxy)propionic acid 失效
标题翻译： D-1-（苯氧基-4-苯氧基）丙酸的除草酯
公开(公告)号：US4531969A
公开(公告)日：1985-07-30
申请号：US971427
申请日：1978-12-20
申请人： Hans J. Nestler , Gerhard Horlein , Reinhard Handte , Hermann Bieringer , Friedhelm Schwerdtle , Peter Langeluddeke
发明人： Hans J. Nestler , Gerhard Horlein , Reinhard Handte , Hermann Bieringer , Friedhelm Schwerdtle , Peter Langeluddeke
IPC分类号： C07C69/712 , A01N31/08 , A01N37/36 , A01N37/42 , A01N39/02 , A01N43/08 , A01N43/20 , A01N43/40 , A01N43/52 , A01N43/72 , A01N43/74 , A01N43/76 , A01N43/78 , A01N47/12 , A01N47/16 , A01N47/18 , A01N47/20 , A01N47/22 , A01N47/24 , A01P13/00 , A61K31/41 , C07C41/00 , C07C41/26 , C07C43/29 , C07C43/295 , C07C51/00 , C07C51/367 , C07C59/08 , C07C59/125 , C07C59/13 , C07C59/58 , C07C59/68 , C07C59/70 , C07C67/00 , C07C67/343 , C07C69/003 , C07C69/67 , C07C69/68 , C07C201/00 , C07C205/38 , C07C219/06 , C07C231/00 , C07C231/12 , C07C233/00 , C07C235/20 , C07C235/22 , C07C235/24 , C07C241/00 , C07C243/28 , C07C253/00 , C07C255/16 , C07C255/37 , C07C313/00 , C07C323/12 , C07C325/00 , C07C327/22 , C07C327/42 , C07D213/64 , C07D213/643 , C07D213/647 , C07D235/26 , C07D263/54 , C07D263/58 , C07D277/66 , C07D277/68 , C07D303/48 , C07D307/12 , C07D307/42 , C07D413/12 , A01N39/00
CPC分类号： A01N39/02 , A01N43/08 , A01N43/20 , A01N43/40 , A01N43/52 , A01N43/74 , A01N43/76 , A01N43/78 , A01N47/12 , A01N47/16 , A01N47/18 , A01N47/20 , C07C243/00 , C07C323/00 , C07C327/00 , C07C41/26 , C07C59/68 , C07C67/31 , C07C69/736 , C07D213/643 , C07D213/647 , C07D235/26 , C07D263/58 , C07D277/68 , C07D307/12 , C07B2200/07 , C07C2101/08 , C07C2101/14
摘要： Optically active enantiomers of the formula I ##STR1## where R is a group of the formulae ##STR2## R.sub.1 and R.sub.2, among others, are halogen or CF.sub.3 and Z is a carboxyl, carboxylate, carboxylic acid ester, thioester, carbonamide, carboxylic acid anilide, carbohydrazide or thioamide group, are interesting herbicides the effect of which is considerably superior to that of the optically inactive racemates.
摘要翻译：（I）其中R是下式的基团：其中R是下式的基团：其中R是下式的基团：其中R是下式的基团：（VI））R1和R2等是卤素或CF 3，Z是羧基，羧酸酯，羧酸酯，硫酯，碳酰胺，羧酸酰苯胺，碳酰肼或硫代酰胺基，是有意义的除草剂，其效果明显优于光学无活性的外消旋体。

76. 发明授权

US4482373A Benzoxazolyloxy phenoxy esters and use as monocotyledonous weed grass herbicides 失效
标题翻译：苯并唑氧基苯氧基酯，用作单子叶杂草除草剂
公开(公告)号：US4482373A
公开(公告)日：1984-11-13
申请号：US529923
申请日：1983-09-07
申请人： Reinhard Handte , Karl Matterstock , Hermann Bieringer , Helmut Kocher
发明人： Reinhard Handte , Karl Matterstock , Hermann Bieringer , Helmut Kocher
IPC分类号： C07D263/14 , A01N43/52 , A01N43/74 , A01N43/76 , A01N43/78 , C07D235/26 , C07D263/58 , C07D277/10 , C07D277/68
CPC分类号： C07D263/58 , A01N43/52 , A01N43/74 , C07D235/26 , C07D277/68
摘要： Compounds of formula ##STR1## wherein R is halogen, CF.sub.3, NO.sub.2, CN, (C.sub.1 -C.sub.4)alkyl or (C.sub.1 -C.sub.4)-alkoxy, n is zero or 1, X is O, S, NH, or N-(C.sub.1 -C.sub.4)alkyl, Y is O or S, R.sup.1 is H or (C.sub.1 -C.sub.4)alkyl and Z is, among others, a cyanalkyl, (subst.) carbalkoxyalkyl, (subst.) carbalkoxyphenyl, sulfoxyalkyl or oxime group, are selective herbicides active especially against weed grasses.
摘要翻译：式（Ⅰ）化合物其中R为卤素，CF 3，NO 2，CN，（C 1 -C 4）烷基或（C 1 -C 4） - 烷氧基，n为0或1，X为O，S，NH或 N-（C 1 -C 4）烷基，Y是O或S，R 1是H或（C 1 -C 4）烷基，Z是尤其是氰基烷基，（低级）烷氧基烷基，（低级）烷氧基苯基，磺基烷基或肟组是选择性除草剂，特别是针对杂草。

77. 发明授权

US4383850A Benzthiazole or benzoxazole ethers, herbicidal compositions and use 失效
标题翻译：苯并噻唑或苯并恶唑醚，除草组合物和用途
公开(公告)号：US4383850A
公开(公告)日：1983-05-17
申请号：US367882
申请日：1982-04-13
申请人： Reinhard Handte , Klaus Bauer , Hermann Bieringer
发明人： Reinhard Handte , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N43/76 , A01N43/74 , A01N43/78 , C07D263/58 , C07D277/68 , C07D413/12 , C07D417/12
CPC分类号： C07D263/58 , A01N43/74 , C07D277/68
摘要： Compounds of the formula ##STR1## in which R denotes halogen, CF.sub.3, NO.sub.2 or CN, n denotes 0-2, X denotes O or S and Z denotes radicals of the formulae ##STR2## or --C.sub.p H.sub.2p --R.sub.3 (in which, inter alia, R.sub.3 can be a heterocyclic radical), are valuable herbicides, particularly against monocotyledonous weeds.
摘要翻译：其中R表示卤素，CF 3，NO 2或CN的式（I）化合物，n表示0-2，X表示O或S，Z表示式“IMAGE”或-CpH2p-R3的基团（在其中R3可以是杂环基），是有价值的除草剂，特别是针对单子叶杂草。

78. 发明授权

US4134753A Herbicidal agents 失效
公开(公告)号：US4134753A
公开(公告)日：1979-01-16
申请号：US816700
申请日：1977-07-18
申请人： Gerhard Horlein , Hubert Schonowsky , Hermann Bieringer , Peter Langeluddeke
发明人： Gerhard Horlein , Hubert Schonowsky , Hermann Bieringer , Peter Langeluddeke
IPC分类号： C07C69/712 , A01N37/38 , A01N39/02 , A01N39/04 , A01P13/00 , C07C51/00 , C07C59/125 , C07C59/68 , C07C67/00 , C07C201/00 , C07C205/38 , C07C231/00 , C07C231/02 , C07C231/12 , C07C233/00 , C07C235/20 , C07C235/24 , C07C241/00 , C07C243/28 , C07C253/00 , C07C255/53 , C07C255/54 , C07C313/00 , C07C319/20 , C07C323/20 , C07C323/62 , C07C325/00 , C07C327/22 , A01N9/24 , C07C51/12
CPC分类号： C07C205/38 , A01N39/02 , A01N39/04 , C07C323/00 , C07C327/00 , C07C59/68
摘要： Compounds of the formula ##STR1## exhibit, in the pre-emergence process and in the post-emergence process, a good herbicidal action against a number of dicotyledonous weeds, they are well tolerated in monocotyledonous crops, such as wheat, barley, rice, sorghum and maize, and are also selectively active in some dicotyledonous crops such as soy beans, groundnuts and the like.

79. 发明授权

US08338332B1 Herbicidal composition for tolerant or resistant cotton crops 有权
标题翻译：用于耐受或抗性棉花作物的除草组合物
公开(公告)号：US08338332B1
公开(公告)日：2012-12-25
申请号：US09371769
申请日：1999-08-10
申请人： Erwin Hacker , Hermann Bieringer , Lothar Willms
发明人： Erwin Hacker , Hermann Bieringer , Lothar Willms
IPC分类号： A01N57/00
CPC分类号： A01N57/20 , A01N33/22 , A01N37/22 , A01N37/48 , A01N43/40 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/70 , A01N43/76 , A01N47/30 , A01N55/02 , A01N2300/00
摘要： Herbicide combinations (A)+(B), if appropriate in the presence of safeners, with an effective content of (A) broad-spectrum herbicides from the group (A1) glufosinate (salts) and related compounds (A2) glyphosate (salts) and related compounds such as sulfosate, (A3) imidazolinones such as imazethapyr, imazapyr, imazaquin, imazamox or their salts and (A4) herbicidal azoles from the group of the protoporphyrinogen oxidase inhibitors (PPO inhibitors) and (A5) the hydroxybenzonitriles and (B) herbicides from the group consisting of (B0) one or more structurally different herbicides from the abovementioned group (A), (B1) foliar- and soil-acting herbicides which are effective against monocotyledonous and dicotyledonous harmful plants, (B2) predominantly foliar-acting herbicides which are effective against dicotyledonous harmful plants, (B3) predominantly foliar-acting herbicides which are effective against monocotyledonous harmful plants, and (B4) foliar- and soil-acting herbicides which are effective against predominantly monocotyledonous harmful plants are suitable for controlling harmful plants in cotton which consists of tolerant or resistant mutants or transgenic cotton plants.
摘要翻译：（A）+（B），如果适合，在安全剂存在下，有效含量（A）来自（A1）草铵膦（盐）和相关化合物（A2）的广谱除草剂草甘膦（盐）以及来自原卟啉原氧化酶抑制剂（PPO抑制剂）和（A5）羟基苯腈和（B）的组合的相关化合物如磺酸盐，（A3）咪唑啉酮如咪草烟，咪草烟，咪草喹，咪唑氧胺或其盐和（A4）除草唑）除草剂（B0）来自上述组（A）的一种或多种结构不同的除草剂，（B1）对单子叶和双子叶有害植物有效的叶面和土壤作用除草剂，（B2）主要是叶面 - （B3）主要是对单子叶有害植物有效的叶面作用除草剂，以及（B4）叶面和土壤作用除草剂，其中ar e主要对单子叶有害植物有效，适用于控制由耐受性或抗性突变体或转基因棉花植物组成的棉花中的有害植物。

80. 发明申请

US20120101287A1 Amino-1,3,5-triazines N-substituted with chiral bicyclic radicals, process for their preparation, compositions thereof, and their use as herbicides and plant growth regulators 审中-公开
标题翻译：用手性双环自由基N-取代的氨基-1,3,5-三嗪，其制备方法，组合物及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US20120101287A1
公开(公告)日：2012-04-26
申请号：US13338351
申请日：2011-12-28
申请人： Hartmut Ahrens , Hansjöerg Dietrich , Klemens Minn , Thomas Auler , Hermann Bieringer , Martin Hills , Heinz Kehne , Hubert Menne
发明人： Hartmut Ahrens , Hansjöerg Dietrich , Klemens Minn , Thomas Auler , Hermann Bieringer , Martin Hills , Heinz Kehne , Hubert Menne
IPC分类号： C07D311/58 , C07C233/14 , C07C233/11 , C07C235/14 , C07C211/42 , C07C279/26
CPC分类号： C07D405/12 , A01N43/68 , C07D251/18 , C07D311/68 , C07D401/12
摘要： The invention related to an optically active compound of formula (I) or a salt thereof: wherein the various symbols are as defined in the description, to processes for their preparation, to compositions thereof, and to their use as herbicides or plant growth regulators. The invention also relates to novel intermediates of formula (III), (V) and (XIII) as defined in the description.
摘要翻译：本发明涉及式（I）的光学活性化合物或其盐：其中各种符号如说明书中所定义，其制备方法，组合物及其作为除草剂或植物生长调节剂的用途。本发明还涉及如说明书中定义的式（III），（V）和（XIII）的新型中间体。

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