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    • 71. 发明授权
    • Process for the preparation of isocyanate polyaddition products which
have hydroxyl groups in side chains
    • 用于制备在侧链具有羟基的异氰酸酯加成产物的方法
    • US4192937A
    • 1980-03-11
    • US921285
    • 1978-07-03
    • Klaus NollKlaus NachtkampJosef Pedain
    • Klaus NollKlaus NachtkampJosef Pedain
    • C08G18/00C08G18/08C08G18/10C08G18/65C08G18/38C08L75/12
    • C08G18/10Y10S528/904
    • The present invention relates to a process for the preparation of substantially linear isocyanate polyaddition products having side-chain hydroxyl groups by the reaction of reactive systems which contain free isocyanate groups and oxazolidine groups with water, characterized in that(a) substantially linear prepolymers which contain both isocyanate groups and oxazolidine groups in end positions or(b) a mixture containing substantially linear isocyanate prepolymers and bis-oxazolidinesare chain lengthened by mixing with water, using a quantity of water calculated to provide at least about 1 mol of water per mol of oxazolidine groups present in the reaction mixture. The present invention also relates in particular to an embodiment of this process in which the prepolymers used contain chemically built-in hydrophilic groups and/or external emulsifiers, and water is used in such excess that the reaction leads directly to aqueous dispersions or solutions of the polyaddition products. Lastly, the present invention also relates to isocyanate polyaddition products obtainable by the process according to the invention.
    • 本发明涉及通过含有游离异氰酸酯基和恶唑烷基的反应体系与水的反应制备具有侧链羟基的基本上线性的异氰酸酯加成产物的方法,其特征在于(a)基本上线性的预聚物,其含有 两个异氰酸酯基和恶唑烷基的末端位置或(b)含有基本上线性异氰酸酯预聚物和双恶唑烷的混合物通过与水混合而被链长延长,使用一定量的水,每摩尔计算得到至少约1mol水 存在于反应混合物中的恶唑烷基团。 本发明还特别涉及该方法的一个实施方案,其中使用的预聚物含有化学内置的亲水基团和/或外部乳化剂,并且水的使用过量,使得反应直接导致水分散体或 加聚产品。 最后,本发明还涉及通过本发明的方法获得的异氰酸酯加聚产物。
    • 75. 发明授权
    • Process for the production of polyisocyanates containing isocyanurate groups and their use
    • 用于生产含有异氰脲酸酯基团的多异氰酸酯的方法及其用途
    • US06765111B1
    • 2004-07-20
    • US08784875
    • 1997-01-16
    • Josef PedainManfred BockCarl-Gerd Dieris
    • Josef PedainManfred BockCarl-Gerd Dieris
    • C08G1820
    • C08G18/792C07D251/34
    • The present invention is directed to a process for the production of polyisocyanates containing isocyanurate groups by trimerizing a portion of the isocyanate groups of hexamethylene diisocyanate using N,N,N-trialkyl-N-benzyl-quaternary ammonium hydroxides as the trimerization catalyst, terminating the trimerization reaction at the desired degree of trimerization by adding a catalyst poison and/or by thermally deactivating the catalyst and removing unreacted hexamethylene diisocyanate to a residual content of at most 0.2% by weight, characterized in that a) the hexamethylene diisocyanate used as starting material is freed from carbon dioxide to a residual content of less than 20 ppm (weight) and b) the catalyst is used in a quantity of less than about 0.03% by weight, based on the weight of the hexamethylene diisocyanate used. The present invention is also directed to the polyisocyanates containing isocyanurate groups obtained by this process and to their use, optionally blocked by blocking agents for isocyanate groups, as the isocyanate component for the production of polyisocyanate polyaddition products.
    • 本发明涉及通过使用N,N,N-三烷基-N-苄基季铵氢氧化物作为三聚催化剂使六亚甲基二异氰酸酯的一部分异氰酸酯基团三聚而制备含有异氰脲酸酯基团的多异氰酸酯的方法, 通过加入催化剂毒物和/或通过使催化剂热失活并除去未反应的六亚甲基二异氰酸酯至残留含量至多为0.2重量%的三聚反应,其特征在于a)用作原料的六亚甲基二异氰酸酯是 从二氧化碳释放到残留含量小于20ppm(重量),和b)催化剂的用量小于约0.03重量%,基于所用的六亚甲基二异氰酸酯的重量。本发明还涉及 涉及通过该方法获得的含有异氰脲酸酯基团的多异氰酸酯及其用途,任选地被嵌段封端 作为异氰酸酯基团的异氰酸酯组分,用于生产多异氰酸酯加聚产物。
    • 80. 发明授权
    • Water-based coating compositions and their use for the production of
flexible coatings
    • 水性涂​​料组合物及其用于生产柔性涂料的用途
    • US5455297A
    • 1995-10-03
    • US169943
    • 1993-12-20
    • Josef PedainHeino MullerDieter MagerManfred Schonfelder
    • Josef PedainHeino MullerDieter MagerManfred Schonfelder
    • C08G18/08C08G18/70C08G18/80C09D5/02C09D175/00C09D175/04C08G18/34
    • C08G18/0823C08G18/706C08G18/8048C08G18/8077Y10T428/31605
    • The present invention relates to a heat-crosslinkable water-based coating composition containing as bindera) a water-soluble or water-dispersible polyol component andb) a water-soluble or water-dispersible blocked polyisocyanate which has an average NCO functionality of 2.0 to 2.6 and is based on the reaction product ofb1) a polyisocyanate mixture having an average NCO functionality of 2.5 to 3.5 and containing (i) at least 15% by weight of an organic diisocyanate,b2) a blocking agent for isocyanate groups in an amount of 50 to 80 equivalent-%, based on the isocyanate groups of component b1) andb3) an aliphatic monohydroxymonocarboxylic acid in a quantity of 20 to 50 equivalent-%, based on the isocyanate groups of component b1) and the hydroxyl groups of component b3), wherein the equivalent ratio, based on the isocyanate-reactive groups of blocking agent b2) and the hydroxyl groups of component b3) to the isocyanate groups of component b1) is at least 0.9:1.
    • 本发明涉及一种热交联性水性涂料组合物,其包含作为粘合剂的a)水溶性或水分散性多元醇组分和b)具有平均NCO官能度为2.0的水溶性或水分散性封端多异氰酸酯 基于b1)具有2.5至3.5的平均NCO官能度并且包含(i)至少15重量%的有机二异氰酸酯的聚异氰酸酯混合物的反应产物,b2)用于异氰酸酯基团的封闭剂 基于组分b1)的异氰酸酯基团和基于组分b1)的异氰酸酯基团的b3)相对于基团b1)的异氰酸酯基团的量为20至50当量的脂族单羟基单羧酸的量为50至80当量% 组分b3),其中基于组分b1)的异氰酸酯基团的封端剂b2)和组分b3)的羟基的异氰酸酯反应性基团的当量比至少为0.9:1。