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71. 发明授权

US5488178A Ditertiary butyl peroxide preparation from tertiary butyl hydroperoxide 失效
标题翻译：二叔丁基过氧化物由叔丁基过氧化氢制备
公开(公告)号：US5488178A
公开(公告)日：1996-01-30
申请号：US401107
申请日：1995-03-08
申请人： John F. Knifton , Edward T. Marquis , Pei-Shing E. Dai
发明人： John F. Knifton , Edward T. Marquis , Pei-Shing E. Dai
IPC分类号： C07C409/16
CPC分类号： C07C409/16 , C07C407/00
摘要： Disclosed is a method of selective preparation of ditertiary butyl peroxide from tertiary butyl hydroperoxide and t-butanol which comprises reacting said tertiary butyl hydroperoxide and t-butanol over a solid acid catalyst selected from:a) an acidic montmorillonite clay;b) an acidic zeolite selected from the group consisting of dealuminized Y-zeolite and pentasil zeolite;c) an acidic organic resin; andd) heteropoly acids supported on an oxide selected from Group III or Group IV.
摘要翻译：公开了从叔丁基过氧化氢和叔丁醇中选择性制备二叔丁基过氧化物的方法，其包括使所述叔丁基过氧化氢和叔丁醇在选自以下的固体酸催化剂中反应：a）酸性蒙脱土粘土; b）选自脱铝Y沸石和pentasil沸石的酸性沸石; c）酸性有机树脂; 和d）负载在选自III或IV族的氧化物上的杂多酸。

72. 发明授权

US5457243A Neutralization of crude MTBE effluent streams using solid bases 失效
标题翻译：使用固体碱中和粗制MTBE流出物流
公开(公告)号：US5457243A
公开(公告)日：1995-10-10
申请号：US172345
申请日：1993-12-23
申请人： John F. Knifton , Mark A. Mueller , Michael W. Peters
发明人： John F. Knifton , Mark A. Mueller , Michael W. Peters
IPC分类号： C07C41/36 , C07C29/88 , C07C31/12 , C07C41/44 , C07C43/04 , C07C41/00
CPC分类号： C07C41/44 , C07C29/88 , C07C31/12
摘要： Disclosed is a method for removing organic acids and derivatives thereof from a crude methyl tertiary butyl ether (MTBE) stream of the type found in the feed to, or effluent from, a reactor for a one-step process for producing MTBE which comprises:contacting said crude MTBE stream in a treating zone over one or more beds of a solid base for a period of time sufficient to neutralize said organic acids and derivatives thereof; andwithdrawing a substantially organic acid-free crude MTBE product from said treating zone.
摘要翻译：公开了一种从用于生产MTBE的一步方法的反应器的反应器或从流出物中的流出物类型的粗甲基叔丁基醚（MTBE）流中除去有机酸及其衍生物的方法，其包括：接触所述粗制MTBE流在处理区中超过一个或多个固体碱床，时间足以中和所述有机酸及其衍生物; 以及从所述处理区取出基本上无机酸的粗MTBE产物。

73. 发明授权

US5338890A One step synthesis of methyl t-butyl ether from t-butanol using alkylsulfonic acid-modified oxide catalysts 失效
标题翻译：使用烷基磺酸改性氧化物催化剂从叔丁醇一步合成甲基叔丁基醚
公开(公告)号：US5338890A
公开(公告)日：1994-08-16
申请号：US92963
申请日：1993-07-19
申请人： John F. Knifton , John R. Sanderson
发明人： John F. Knifton , John R. Sanderson
IPC分类号： B01J31/02 , C07B61/00 , C07C41/09 , C07C43/04
CPC分类号： C07C41/09
摘要： Disclosed is a method wherein t-butanol is reacted with methanol in one step to provide methyl t-butyl ether at a temperature of about 20.degree. C. to 250.degree. C. and a pressure of about atmospheric to about 1000 psig employing a heterogenous catalyst comprising a Group IV oxide having an alkylsulfonic acid covalently bonded thereto, particularly alkylsulfonic acid covalently bonded to silica gel and having the structure: ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms and n is an integer in the range of 3 to 10.
摘要翻译：公开了一种方法，其中叔丁醇与甲醇在一个步骤中反应以在约20℃至250℃的温度和约大气压至约1000psig的压力下提供甲基叔丁基醚，使用异种催化剂包括与其共价键合的烷基磺酸的IV族氧化物，特别是与硅胶共价键合的烷基磺酸，具有以下结构：其中R是具有1至3个碳原子的烷基，n是整数范围为3至10。

74. 发明授权

US5313006A Cogeneration of isobutylene plus MTBE from crude t-butanol/methanol feedstocks 失效
标题翻译：来自粗品叔丁醇/甲醇原料的异丁烯加MTBE的热电联产
公开(公告)号：US5313006A
公开(公告)日：1994-05-17
申请号：US994015
申请日：1992-12-21
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： C07B61/00 , C07C1/24 , C07C41/09 , C07C43/04
CPC分类号： C07C41/09 , C07C1/24 , C07C2529/08
摘要： Disclosed is an improvement in a method for cogeneration of isobutylene and MTBE by etherification of tBA/MeOH over an ion-exchange resin which allows for more complete conversion of the remaining tBA fraction and comprises a second step consisting essentially of recovering the MTBE from the primary fractionator as an overhead fraction and etherifying the bottoms from the primary fractionator over an inorganic acid catalyst comprising a crystalline aluminosilicate faujasite-type Y-zeolite modified with a compound selected from a fluoride-containing compound including hydrofluoric acid, ammonium fluoride, fluorosulfonic acids and their cogeners and triflic anhydride at a temperature of greater than 120.degree. C.
摘要翻译：公开了通过tBA / MeOH通过离子交换树脂的醚化来进行异丁烯和MTBE的热电联产方法的改进，其允许剩余的tBA馏分更完全的转化，并且包括基本上由主要从回收的MTBE 分馏器作为塔顶馏分，并将来自主分馏器的塔底馏分在无机酸催化剂上进行醚化，所述无机酸催化剂包含用选自包含氢氟酸，氟化铵，氟代磺酸的含氟化合物及其它化合物的化合物改性的结晶硅铝酸盐八面沸石型Y-沸石共聚物和三氟甲磺酸酐在大于120℃的温度下

75. 发明授权

US5304681A Tert-butylamine synthesis over montmorillonite clays 失效
标题翻译：蒙脱石粘土上的叔丁胺合成
公开(公告)号：US5304681A
公开(公告)日：1994-04-19
申请号：US894841
申请日：1991-11-22
申请人： John F. Knifton , Neal J. Grice
发明人： John F. Knifton , Neal J. Grice
IPC分类号： B01J27/16 , B01J27/18 , B01J29/06 , C07B61/00 , C07C209/60 , C07C211/06
CPC分类号： C07C209/60
摘要： Disclosed is a method for preparation of alkylamines which comprises reacting ammonia and a monounsaturated olefin in the presence of a catalyst selected from the group consisting of:a. Acid modified montmorillonite clays;b. Heterogeneous catalysts comprising a fluorine-containing compound on an inert support; andc. Heteropoly acids on an inert support.
摘要翻译：公开了一种制备烷基胺的方法，其包括在选自以下的催化剂存在下使氨和单不饱和烯烃反应：a。酸改性蒙脱石粘土; b。在惰性载体上含有含氟化合物的非均相催化剂; 和c。惰性支持物上的杂多酸。

76. 发明授权

US5242621A Combinations of alkanoic hydrocarbyl dicarboxylic and carbocyclic alkanoic acids or salts useful as heat transfer fluid corrosion inhibitors 失效
标题翻译：链烷烃二羧酸和碳环链烷酸或可用作传热流体腐蚀抑制剂的盐的组合
公开(公告)号：US5242621A
公开(公告)日：1993-09-07
申请号：US892875
申请日：1992-06-03
申请人： David L. Miller , Brian L. Benac , John F. Knifton
发明人： David L. Miller , Brian L. Benac , John F. Knifton
IPC分类号： C09K5/08 , C09K5/20 , C09K15/06 , C23F11/12
CPC分类号： C23F11/126 , C09K5/20 , C23F11/10
摘要： Corrosion inhibitors containing alkanoic, hydrocarbyl dicarboxylic and carbocyclic-substituted, alkanoic acids or salts give high performance, heat transfer fluids and antifreezes, with improved properties including storage stability.

77. 发明授权

US5214217A Method for one-step synthesis of methyl t-butyl ether 失效
标题翻译：一步合成甲基叔丁基醚的方法
公开(公告)号：US5214217A
公开(公告)日：1993-05-25
申请号：US917218
申请日：1992-07-22
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： C07C41/09
CPC分类号： C07C41/09
摘要： A method is disclosed wherein t-butanol is reacted with methanol in a reaction zone in the presence of a catalyst to provide methyl-tert-butyl ether and the improvement of accomplishing the reaction in one-step which comprises:a. using a catalyst selected from the group consisting of acidic aluminas, and crystalline aluminosilicate faujasite-type zeolites, particularly dealuminized Y-type zeolites;b. continuously contacting said t-butanol and methanol in a molar amount of about 0.1 to 10 moles of methanol per mole of t-butanol with said catalyst at a temperature of about 20.degree. C. to about 250.degree. C. and a pressure of about atmospheric to about 1000 psig to obtain the methyl-tert-butyl product.
摘要翻译：公开了一种方法，其中在催化剂存在下，使叔丁醇与甲醇在反应区中反应，得到甲基叔丁基醚，并改进一步完成反应，该方法包括：a。使用选自酸性氧化铝和结晶硅铝酸盐八面沸石型沸石，特别是脱铝Y型沸石的催化剂; b。在约20℃至约250℃的温度和大约大气压的压力下，使所述叔丁醇和甲醇以摩尔量的约0.1至10摩尔甲醇/摩尔叔丁醇与所述催化剂连续接触至约1000psig，得到甲基 - 叔丁基产物。

78. 发明授权

US5179052A One step synthesis of metyl t-butyl ether from 5-butanol using fluorosulfonic acid-modified zeolite catalysts 失效
标题翻译：使用氟磺酸改性沸石催化剂一步合成来自5-丁醇的甲基叔丁基醚
公开(公告)号：US5179052A
公开(公告)日：1993-01-12
申请号：US819163
申请日：1991-11-29
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： C07C41/09
CPC分类号： C07C41/09
摘要： A method is disclosed wherein t-butanol is reacted with methanol in a reaction zone in one step to provide methyl tert-butyl ether and the improvement of accomplishing the reaction which comprises:a. Using a catalyst consisting of a crystalline aluminosilicate faujasite Y-type zeolite which has been treated with a fluorosulfonic acid;b. continuously contacting said t-butanol and methanol in a molar amount of about 0.1 to 10 moles of methanol per mole of t-butanol with said catalyst at a temperature of about 20.degree. C. to about 250.degree. C. and a pressure of about atmospheric to about 1000 psig to obtain the methyl tert-butyl ether product.
摘要翻译：公开了一种方法，其中在一个步骤中使叔丁醇与甲醇在反应区中反应，得到甲基叔丁基醚，并改进了完成反应，其包括：a。使用由氟磺酸处理的结晶硅铝酸盐八面沸石Y型沸石组成的催化剂; b。在约20℃至约250℃的温度和大约大气压的压力下，使所述叔丁醇和甲醇以摩尔量的约0.1至10摩尔甲醇/摩尔叔丁醇与所述催化剂连续接触至约1000psig，得到甲基叔丁基醚产物。

79. 发明授权

US5157162A One step synthesis of methyl t-butyl ether from t-butanol using fluorosulfonic acid-modified clay catalysts 失效
标题翻译：使用氟磺酸改性粘土催化剂从叔丁醇中一步合成甲基叔丁基醚
公开(公告)号：US5157162A
公开(公告)日：1992-10-20
申请号：US783015
申请日：1991-10-25
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： B01J31/06 , C07B61/00 , C07C41/09 , C07C43/04
CPC分类号： C07C41/09
摘要： A method is disclosed wherein t-butanol is reacted with methanol in a reaction zone in one step to provide methyl tert-butyl ether and the improvement of accomplishing the reaction which comprises:a. Using a catalyst consisting of a montmorillonite clay, optionally pretreated with a mineral acid, then treated with a fluorosulfonic acid;b. continuously contacting said t-butanol and methanol in a molar amount of about 0.1 to 10 moles of methanol per mole of t-butanol with said catalyst at a temperature of about 20.degree. C. to about 250.degree. C. and a pressure of about atmospheric to about 1000 psig to obtain the methyl tert-butyl ether product.
摘要翻译：公开了一种方法，其中在一个步骤中使叔丁醇与甲醇在反应区中反应，得到甲基叔丁基醚，并改进了完成反应，其包括：a。使用由蒙脱石粘土组成的催化剂，任选地用无机酸预处理，然后用氟磺酸处理; b。在约20℃至约250℃的温度和大约大气压的压力下，使所述叔丁醇和甲醇以摩尔量的约0.1至10摩尔甲醇/摩尔叔丁醇与所述催化剂连续接触至约1000psig，得到甲基叔丁基醚产物。

80. 发明授权

US5099072A Method for one-step synthesis of methyl t-butyl ether 失效
标题翻译：一步合成甲基叔丁基醚的方法
公开(公告)号：US5099072A
公开(公告)日：1992-03-24
申请号：US494280
申请日：1990-03-16
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： C07C41/09
CPC分类号： C07C41/09
摘要： A method is disclosed wherein t-butanol is reacted with methanol in a reaction zone in the presence of a catalyst to provide methyl-tert-butyl ether and the improvement of accomplishing the reaction in one-step which comprises:a. using an acidic montmorillonite silica-alumina catalyst;b. continuously contacting said t-butanol and methanol in a molar amount of about 0.1 to 10 moles of methanol per mole of t-butanol with said catalyst at a temperature of about 20.degree. C. to about 250.degree. C. and a pressure of about atmospheric to about 1000 psig to obtain the methyl-tert-butyl product.
摘要翻译：公开了一种方法，其中在催化剂存在下，使叔丁醇与甲醇在反应区中反应，得到甲基叔丁基醚，并改进一步完成反应，该方法包括：a。使用酸性蒙脱石二氧化硅 - 氧化铝催化剂; b。在约20℃至约250℃的温度和大约大气压的压力下，使所述叔丁醇和甲醇以摩尔量的约0.1至10摩尔甲醇/摩尔叔丁醇与所述催化剂连续接触至约1000psig，得到甲基 - 叔丁基产物。

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