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    • 71. 发明申请
    • Oxygen Scavenging Compositions and Method of Preparation
    • 氧气清除组合物和制备方法
    • US20080171169A1
    • 2008-07-17
    • US11911288
    • 2006-04-07
    • Zhenguo Liu
    • Zhenguo Liu
    • B32B1/02C08G63/66C08G63/52C09K3/00C08F120/00
    • C08G63/52B65D81/266C08G63/676C08K5/098C08K2201/012C08L23/02C08L67/02C08L67/06C08L77/00Y10T428/1352Y10T428/1397C08L2666/06C08L2666/18
    • The object of the invention is to provide a polyester composition that actively scavenges oxygen, with or without a transition metal catalyst. This was achieved by using a monomer selected from the group consisting of linear difunctional monomers having the general formula: X—(CH2)n—CH═CH—(CH2)m—X′ wherein X and X′ are each independently selected from the group consisting of OR and COOR, wherein R is selected from the group consisting of H and alkyl groups with one or more carbon atoms; and n and m are each independently 1 or more. The preferred monomer is 2-butene-1,4-diol (BEDO), and the preferred polyester is the reaction product of this diol with terephthalic acid to form poly(oxy-2-butene-1,4-diyloxycarbonyl-1,4-phenylenecarbonyl)—PBET. Copolymers of PBET are also within the scope of this invention. The polyester oxygen scavenging composition is then blended with conventional container resin such as polyesters, polyamides or polyolefins to make a container.
    • 本发明的目的是提供一种聚酯组合物,其有或没有过渡金属催化剂主动地清除氧气。 这通过使用选自以下通式的线性二官能单体:X - (CH 2)n - CH- CH-(CH 2) 其中X和X'各自独立地选自OR和COOR,其中R选自H和烷基 具有一个或多个碳原子; n和m各自独立地为1以上。 优选的单体是2-丁烯-1,4-二醇(BEDO),优选的聚酯是该二醇与对苯二甲酸的反应产物,以形成聚(氧-2-丁烯-1,4-二氧基羰基-1,4 - 苯基羰基)-PBET。 PBET的共聚物也在本发明的范围内。 然后将聚酯氧清除组合物与常规容器树脂如聚酯,聚酰胺或聚烯烃混合以制成容器。