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61. 发明申请

US20070112227A1 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US20070112227A1
公开(公告)日：2007-05-17
申请号：US11592842
申请日：2006-11-03
申请人： Sudip Mukhopadhyay , Haridasan Nair , Hsueh Tung , Michael Van Der Puy , Robert Johnson , Daniel Merkel
发明人： Sudip Mukhopadhyay , Haridasan Nair , Hsueh Tung , Michael Van Der Puy , Robert Johnson , Daniel Merkel
IPC分类号： C07C17/00
CPC分类号： C07C17/25 , B01J23/02 , B01J23/44 , B01J23/755 , B01J23/78 , B01J23/83 , B01J35/06 , C07C17/00 , C07C17/269 , C07C21/18 , C07C19/08
摘要： Disclosed is a process for the preparation of fluorinated olefins. In preferred embodiments C3 olefins are produced by methods comprising contacting a compound of the Formula (I) C(R1aR2bR3c) (I) with a compound of Formula (II) C(R1aR2bR3c)Cn(R1aR2bR3c) II wherein R1a, R2b, and R3c are independently a hydrogen atom or a halogen selected from the group consisting of fluorine; chlorine, bromine and iodine, provided that the compound of formula I has at least three halogen substituents and that said at three halogen substituents comprise at least one fluorine; a, b and c are independently=0, 1, 2 or 3 and (a+b+c)=2 or 3; and n is 0 or 1, under conditions effective to produce at least one C3 fluoroolefin.
摘要翻译：公开了一种制备氟化烯烃的方法。在优选的实施方案中，C3烯烃通过以下方法制备：包括使式（I）的化合物<？in-line-formula description =“In-line Formulas”end =“lead”→C（R 1> （I）＆lt;＆lt;＆lt; 2＆gt;＆lt; 3＆gt; in-line-formula description =“In-line Formulas”end =“tail”？>与式（II）的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> C（R 1）1 R 2 R 2 R 3 R 3 R 3，（R 1）R 1 R 2 R 2 R 2 R 2 R 2 R 2 其中R 1' R 1，R 2，R 3和R 3独立地是氢原子或选自氟的卤素; 氯，溴和碘，条件是式I化合物具有至少三个卤素取代基，并且在三个卤素取代基上含有至少一个氟; a，b和c独立地为= 0,1,2或3，（a + b + c）= 2或3; 在有效产生至少一种C3氟代烯烃的条件下，n为0或1。

62. 发明授权

US07138553B2 Method for purifying tetrachloroethylene and process for producing hydrofluorocarbons 有权
公开(公告)号：US07138553B2
公开(公告)日：2006-11-21
申请号：US10363639
申请日：2002-07-05
申请人： Hiromoto Ohno , Toshio Ohi , Makoto Miyamura
发明人： Hiromoto Ohno , Toshio Ohi , Makoto Miyamura
IPC分类号： C07C17/00 , C07C19/08
CPC分类号： C07C17/21 , C07C17/206 , C07C17/38 , C07C17/389 , C07C19/08 , C07C21/12 , C07C19/12
摘要： Tetrachloroethylene containing a stabilizer is contacted with a zeolite having an average pore size of 3.4 to 11 Å and/or a carbonaceous adsorbent having an average pore size of 3.4 to 11 Å in a liquid phase to obtain a high purity tetrachloroethylene. A halogenated alkene and/or a halogenated alkane are reacted with hydrogen fluoride in the presence of a fluorination catalyst to produce a first hydrofluorocarbon, a halogenated alkene and/or a halogenated alkane are reacted with hydrogen fluoride in the presence of a fluorination catalyst to produce a second hydrofluorocarbon, and the products are joined and then distilled to obtain the first and second hydrofluorocarbons.

63. 发明授权

US07129383B2 Processes for the preparation of 2-chloro-1,1,1,2,3,3,3-heptafluoropropane, hexafluoropropene and 1,1,1,2,3,3,3-heptafluoropropane 失效
标题翻译：制备2-氯-1,1,1,2,3,3,3-七氟丙烷，六氟丙烯和1,1,1,2,3,3,3-七氟丙烷的方法
公开(公告)号：US07129383B2
公开(公告)日：2006-10-31
申请号：US10523223
申请日：2003-08-21
申请人： Mario J. Nappa , Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Sekhar Subramoney , Munirpallam A. Subramanian , Allen C. Sievert
发明人： Mario J. Nappa , Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Sekhar Subramoney , Munirpallam A. Subramanian , Allen C. Sievert
IPC分类号： C07C17/00 , C07C17/266 , C07C17/10
CPC分类号： C07C19/08 , B01J23/26 , B01J23/866 , B01J35/002 , B01J37/0236 , B01J37/03 , B01J37/26 , C07C17/206 , C07C17/21 , C07C17/23 , C07C17/25 , C07C19/10 , C07C21/18
摘要： A process for the preparation of 2-chloro-1,1,1,3,3,3-heptafluoropropane is disclosed which involves (a) contacting a mixture comprising hydrogen fluoride, chlorine, and at least one starting material selected from the group consisting of halopropenes of the formula CX3CCI═CX2 and halopropanes of the formula the CX3CCIYCX3, wherein each X is independently F or Cl, and Y is H, Cl or F (provided that the number of X and Y which are F totals no more than six) with a chlorofluorination catalyst in a reaction zone to produce a product mixture comprising CF3CCIFCF3, HCI, HF. and underfluorinated halogenated hydrocarbon intermediates. The process is characterized by said chlorofluorination catalyst comprising at least one chromium-containing component selected from (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by nickel, trivalent cobalt or both nickel and trivalent cobalt, provided that no more than 2 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by nickel and that the total amount of chromium atoms in the alpha-chromium oxide lattice that are replaced by nickel and trivalent cobalt is no more than 6 atom %, and (ii) a fluorinated crystalline oxide of (i). Also disclosed is a process for the manufacture of a mixture of HFC-227ea and hexafluoropropene by reacting a starting mixture comprising CFC-217ba and hydrogen in the vapor phase at an elevated temperature, optionally in the presence of a hydrogenation catalyst. This process involves preparing the CFC-217ba by the process described above.
摘要翻译：公开了一种制备2-氯-1,1,1,3,3,3-七氟丙烷的方法，其涉及（a）使包含氟化氢，氯和至少一种起始原料的混合物接触，所述起始材料选自的式CX3CCI-CX2的卤代丙烯和式CX3CCIYCX3的卤代丙烷，其中每个X独立地为F或Cl，Y为H，Cl或F（条件是总计X不超过6的X和Y的数目）与反应区中的氯氟化催化剂反应以产生包含CF 3 CClF 3，HCl，HF的产物混合物。和不完全氟化的卤代烃中间体。该方法的特征在于所述氯氟化催化剂包含至少一种含铬组分，其选自（i）α-氧化铬晶格中至少0.05原子％的铬原子被镍取代的结晶α-氧化铬，三价钴或镍和三价钴，条件是α-铬氧化物晶格中不超过2原子％的铬原子被镍代替，并且α-氧化铬晶格中的铬原子的总量被镍和三价钴不超过6原子％，和（ii）（i）的氟化结晶氧化物。还公开了通过在升高的温度下，任选地在氢化催化剂存在下，使包含CFC-217ba和氢的起始混合物在气相中反应制备HFC-227ea和六氟丙烯的混合物的方法。该方法包括通过上述方法制备CFC-217ba。

64. 发明授权

US07126035B2 Catalyst composition for oxychlorination 失效
标题翻译：用于氧氯化的催化剂组合物
公开(公告)号：US07126035B2
公开(公告)日：2006-10-24
申请号：US10502056
申请日：2003-02-04
申请人： Christian Kuhrs , Ruprecht Meissner
发明人： Christian Kuhrs , Ruprecht Meissner
IPC分类号： C07C17/00 , C07C22/00
CPC分类号： B01J27/138 , B01J21/04 , B01J23/8946 , B01J27/122 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0201 , C07C17/156 , C07C19/045
摘要： The present invention relates to a catalyst composition for the oxychlorination of ethylene, comprising a mixture of metal salts on a support, where said metal salts are applied to the support in such ratios that the catalyst composition comprises a) from 3 to 12% by weight of copper as copper salt, b) from 0 to 3% by weight of an alkaline earth metal as alkaline earth metal salt, c) from 0 to 3% by weight of an alkaline metal as alkaline metal salt, d) from 0.001 to 0.1% by weight, preferably from 0.005 to 0.05% by weight, of at least one metal selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, and/or from 0.0001 to 0.1% by weight, preferably from 0.001 to 0.05% by weight, of gold, as corresponding metal salt or tetrachloroauric acid, where all percentages by weight are based on the total weight of the catalyst including support material. The invention further provides a process for preparing 1,2-dichloroethane by oxychlorination of ethylene in the presence of the above catalyst composition as catalyst.
摘要翻译：本发明涉及用于乙烯氧氯化的催化剂组合物，其包含在载体上的金属盐的混合物，其中所述金属盐以这样的比例施加到载体上，使得催化剂组合物包含a）3至12重量％的铜作为铜盐，b）0-3重量％的碱土金属作为碱土金属盐，c）0-3重量％的作为碱金属盐的碱金属，d）0.001至0.1 至少一种选自钌，铑，钯，锇，铱和铂的金属，和/或0.0001至0.1重量％，优选为0.001重量％，优选0.005至0.05重量％至0.05重量％的金，作为相应的金属盐或四氯月桂酸，其中所有的重量百分数都是基于包括载体材料的催化剂的总重量。本发明还提供了在上述催化剂组合物作为催化剂存在下，通过乙烯氧氯化制备1,2-二氯乙烷的方法。

65. 发明授权

US07102040B2 Fluoropolymer lined metallic vessel design 有权
标题翻译：含氟聚合物内衬金属容器设计
公开(公告)号：US07102040B2
公开(公告)日：2006-09-05
申请号：US10408153
申请日：2003-04-04
申请人： Yuon Chiu , Merwyn E. Howells , Stephen A. Cottrell
发明人： Yuon Chiu , Merwyn E. Howells , Stephen A. Cottrell
IPC分类号： C07C17/00 , C07C19/08
CPC分类号： B01J19/02 , B01J2219/0002 , B01J2219/00094 , B01J2219/0245 , C07C17/206
摘要： The invention provides an apparatus useful in fluorinating organic compounds, or more particularly to a reactor system suitable for the fluorination of organic compounds on a commercial scale. The apparatus is also useful in chemical reactions including heating or cooling.
摘要翻译：本发明提供了一种可用于氟化有机化合物的装置，或更具体地涉及适用于商业规模氟化有机化合物的反应器系统。该装置还可用于包括加热或冷却在内的化学反应。

66. 发明申请

US20060161028A1 Process for production of iodine compounds and process for production of high-purity 5-iodo-2-methylbenzoic acid 失效
标题翻译：生产碘化合物的方法和生产高纯度5-碘-2-甲基苯甲酸的方法
公开(公告)号：US20060161028A1
公开(公告)日：2006-07-20
申请号：US10545005
申请日：2004-02-10
申请人： Toshio Hidaka , Takafumi Yoshimura , Yoshifumi Sato , Norio Fushimi , Masaharu Doya
发明人： Toshio Hidaka , Takafumi Yoshimura , Yoshifumi Sato , Norio Fushimi , Masaharu Doya
IPC分类号： C07C17/00
CPC分类号： C07C253/30 , C07B39/00 , C07C17/12 , C07C17/156 , C07C17/158 , C07C51/363 , C07C51/43 , C07C25/02 , C07C25/13 , C07C25/18 , C07C25/125 , C07C63/70 , C07C255/50
摘要： Provided is a production method for an iodine compound in which iodine is reacted with a substrate in the presence of a porous material having a pore diameter of 500 nm or less or in the presence of the above porous material and an oxidizing agent and a production process for high purity 5-iodo-2-methylbenzoic acid comprising an iodination reaction step carried out by the above-mentioned, a crystal precipitation and separation step in which a product is precipitated by adding water or cooling and then separated and a purification step in which crystal separated is recrystallized using an organic solvent. According to the production method for an iodine compound described above, iodine can be introduced into various substrates at a high selectivity. Since expensive metals and specific reagents do not have to be used, it can readily be carried out in an industrially scale, and the product having a high purity can be obtained. Further, the process comprising the iodination reaction, separation and purification steps described above makes it possible to readily obtain at a high yield, 5-iodo-2-methylbenzoic acid having a high purity which is useful in uses for functional chemical products such as medicines. The process of the present invention comprising iodination reaction, separation and purification steps is characterized by that it is simple in terms of a procedure and that the purification load is smaller, and it is very advantageous in industrially carrying out.
摘要翻译：提供一种碘化合物的制造方法，其中碘在孔径为500nm以下的多孔质材料的存在下，或者在上述多孔质材料和氧化剂的存在下，与基材反应，制造方法包括通过上述进行的碘化反应步骤的高纯度5-碘-2-甲基苯甲酸，其中通过加入水或冷却然后分离产物而沉淀产物的晶体沉淀和分离步骤和纯化步骤，其中使用有机溶剂重结晶晶体分离。根据上述碘化合物的制造方法，能够以高选择性将碘引入各种基材中。由于不需要使用昂贵的金属和特定试剂，因此可以容易地以工业规模进行，可以获得高纯度的产物。此外，包括上述碘化反应，分离和纯化步骤的方法使得可以容易地以高产率获得具有高纯度的5-碘-2-甲基苯甲酸，其可用于诸如药物的功能性化学产品的用途。包括碘化反应，分离和纯化步骤的本发明方法的特征在于它在程序方面简单，净化负荷较小，在工业上非常有利。

67. 发明授权

US07078576B2 Process for producing isopropyl chloride 失效
标题翻译：生产异丙基氯的方法
公开(公告)号：US07078576B2
公开(公告)日：2006-07-18
申请号：US10851154
申请日：2004-05-24
申请人： Tomoko Matsumoto , Tateo Nakano , Yutaka Yokoyama , Tomoji Makiguchi
发明人： Tomoko Matsumoto , Tateo Nakano , Yutaka Yokoyama , Tomoji Makiguchi
IPC分类号： C07C17/00
CPC分类号： C07C17/08 , C07C19/01
摘要： The present invention is an industrially advantageous process for isopropyl chloride production in which the catalytic activity can be maintained under the milder reaction conditions than in the conventional processes, and which requires no special reactor.Propylene and hydrogen chloride is reacted in a gas phase, in the presence of iron or a halogenated aluminum oxide (preferably, aluminum oxide reacted with hydrogen chloride). Preferably, a temperature during the reaction is 20 to 100° C., and a pressure of the reaction is 1013 to 3039 hPa (absolute pressure).
摘要翻译：本发明是工业上有利的异丙基氯生产方法，其中催化活性可以在比常规方法更温和的反应条件下保持，并且不需要特殊的反应器。丙烯和氯化氢在铁或卤化氧化铝（优选与氯化氢反应的氧化铝）的存在下在气相中反应。优选地，反应期间的温度为20〜100℃，反应压力为1013〜3039hPa（绝对压力）。

68. 发明授权

US07067706B2 Method for preparing a hydro(chloro)fluoroalkane and catalyst 失效
标题翻译：制备氢（氯）氟烷烃和催化剂的方法
公开(公告)号：US07067706B2
公开(公告)日：2006-06-27
申请号：US10257590
申请日：2001-04-09
申请人： Vincent Wilmet , Francine Janssens
发明人： Vincent Wilmet , Francine Janssens
IPC分类号： C07C17/00 , B01J23/00
CPC分类号： C07C17/21 , B01J23/26 , C07C17/206 , C07C19/08 , C07C19/12
摘要： Process for the preparation of a hydro(chloro)fluoroalkane according to which a halogenated precursor of the hydro(chloro)fluoroalkane is reacted with hydrogen fluoride in the presence of a catalyst comprising chromium (Cr) and at least one other metal selected from the group consisting of aluminium, barium, bismuth, calcium, cerium, copper, iron, magnesium, strontium, vanadium and zirconium.
摘要翻译：制备氢氯代氟烷烃的方法，其中氢（氯）氟代烷烃的卤化前体与氟化氢在含铬（Cr）和至少一种选自下组的其它金属存在下反应：由铝，钡，铋，钙，铈，铜，铁，镁，锶，钒和锆组成。

69. 发明授权

US07026520B1 Catalytic conversion of hydrofluoroalkanol to hydrofluoroalkene 有权
标题翻译：氢氟烷醇催化转化成氢氟烯烃
公开(公告)号：US07026520B1
公开(公告)日：2006-04-11
申请号：US11006922
申请日：2004-12-08
申请人： Sudip Mukhopadhyay , HsuehSung Tung , Haridasan K. Nair
发明人： Sudip Mukhopadhyay , HsuehSung Tung , Haridasan K. Nair
IPC分类号： C07C17/00 , C07C17/08 , C07C21/18 , C07C23/00 , C07C25/13
CPC分类号： C07C17/00 , C07C17/25 , C07C21/18
摘要： Methane is used as the selective dehydrating agent for the production of 2,3,3,3-tetrafluoro-1-propene (R1234yf) from 2,2,3,3,3-pentafluoro-1-propanol. Supported transition metal catalysts are prepared and used for this reaction with high activity. Almost 58% selectivity to R1234yf is obtained at an alcohol conversion level of 60% using unsupported Ni-mesh as the catalyst. Pd and Pt show almost similar level of conversion; however, the selectivity to the desired product is low. The activity of the metal catalyst was found to be a function of the type of support material, activated carbon showing better activity than alumina. Different important process parameters such as temperature, pressure, and contact time are studied to optimize the process. High pressure and temperature are deleterious to the rate of 1234yf formation; yet, the highest yield to 1234yf is obtained while performing a reaction at 494° C. with a contact time of 23 sec.
摘要翻译：甲烷用作用于从2,2,3,3,3-五氟-1-丙醇生产2,3,3,3-四氟-1-丙烯（R1234yf）的选择性脱水剂。制备负载型过渡金属催化剂，并以高活性用于该反应。使用未负载的Ni-网作为催化剂，在60％的醇转化率下获得对R1234yf几乎58％的选择性。 Pd和Pt显示几乎相似的转化水平; 然而，对所需产物的选择性低。发现金属催化剂的活性是支撑材料的类型的函数，活性炭表现出比氧化铝更好的活性。研究了不同的重要工艺参数，如温度，压力和接触时间，以优化工艺。高压和高温对于1234yf的形成是有害的; 然而，在494℃下以23秒的接触时间进行反应，获得了对1234yf的最高产率。

70. 发明授权

US07015368B2 Purification process of thermoprocessable tetrafluoroethylene copolymers 有权
公开(公告)号：US07015368B2
公开(公告)日：2006-03-21
申请号：US10205494
申请日：2002-07-26
申请人： Hua Wu , Vincenzo Arcella
发明人： Hua Wu , Vincenzo Arcella
IPC分类号： C07C17/38 , C07C17/00 , C07C17/02 , C07C17/04 , C07C17/08
CPC分类号： C08J3/075 , C08F6/16 , C08F6/22 , C08J2327/18 , C08L27/18
摘要： A purification process of thermoprocessable tetrafluoroethylene (TFE) copolymers comprising the following steps: A) the polymer latex is transformed into gel form, under mechanical stirring, by addition of an acid electrolyte having pH values ≦2; B) washing of the polymer gel with aqueous solutions having pH from 1 to 7.

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