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61. 发明授权

US4692521A N-substituted acyl-lactam compound 失效
标题翻译： N-取代的酰基 - 内酰胺化合物
公开(公告)号：US4692521A
公开(公告)日：1987-09-08
申请号：US808558
申请日：1985-12-13
申请人： Jozef J. M. Bongers , Albert A. Van Geenen
发明人： Jozef J. M. Bongers , Albert A. Van Geenen
IPC分类号： C07D207/263 , C07D211/76 , C07D223/08 , C07D223/10 , C07D225/02 , C07D227/08 , C07D227/087 , C08G18/10 , C08G63/685 , C08G63/91 , C08G65/32 , C08G69/00 , C08G69/14 , C08G69/18 , C08G69/20 , C08G69/40 , C08G69/42 , C08G69/44 , C08G77/32 , C08G77/388 , C08G85/00
CPC分类号： C08G69/44 , C07D227/08 , C08G18/10 , C08G69/14 , C08G69/18 , C08G69/20 , C08G69/40 , C08G69/42 , C08G2120/00
摘要： The invention relates to N-substitutecd acyl lactam compounds of the formula ##STR1## where R is a polyol residue originating from a polyol with the formula R-(OH).sub.x where x is a number.ltoreq.2R' a bivalent cyclic or non-cyclic alkyl, aralkyl, alkaryl or aryl radicalR" a bivalent radical having the following general formula ##STR2## wherein R'" is H, alkyl, cycloalkyl, aryl, alkaryl or aralkyl,R.sup.iv is H, alkyl, cycloalkyl, aryl, alkaryl or aralkyl whereR"' and R.sup.iv may jointly form a substituted or non-substituted cycloalkyl residuen is 0 or 1 and(-L) represents a non-opened lactam ring of the formula ##STR3## wherein Y is hydrocarbon residue with 3-11 carbon atoms. It has been found that this group of compounds is very suitable as activator in the preparation of nylon block copolymers, more specifically in the RIM or RRIM systems.
摘要翻译：本发明涉及式（IMAGE）的N-取代的酰基内酰胺化合物，其中R是衍生自具有式R-（OH）x的多元醇的多元醇残基，其中x是二价环状的数字，非环烷基，芳烷基，烷芳基或芳基R“具有以下通式的二价基团，其中R”'是H，烷基，环烷基，芳基，烷芳基或芳烷基，Riv是H，烷基，环烷基，芳基，烷芳基或芳烷基，其中R“'和Riv可以共同形成取代或未取代的环烷基残基n为0或1，（-L）表示式”IMAGE“的未开封的内酰胺环，其中Y为具有3-11个碳原子的烃残基。已经发现，这组化合物在制备尼龙嵌段共聚物中非常适合作为活化剂，更具体地说在RIM或RRIM系统中。

62. 发明授权

US4691004A Copolymerization of lactam with diene polymer having amino or imino end groups 失效
标题翻译：内酰胺与具有氨基或亚氨基端基的二烯聚合物的共聚合
公开(公告)号：US4691004A
公开(公告)日：1987-09-01
申请号：US789991
申请日：1985-10-22
申请人： Masao Nishiyama , Yasuo Hirano
发明人： Masao Nishiyama , Yasuo Hirano
IPC分类号： C08G69/00 , C08G69/16 , C08G69/18 , C08G69/14
CPC分类号： C08G69/16
摘要： A process for producing a lactam copolymer, which comprises copolymerizing an omega-lactam and a diene polymer having an amino or imino group at molecular ends by the action of an alkaline catalyst and a polyfunctional co-catalyst, the proportions of the components satisfying the following equations (I) and (II)a/c>1/4 (I)b/c>1 (II)wherein a, b and c represent the equivalent weights of the alkaline catalyst, the polyfunctional co-catalyst and the diene polymer, respectively, per equivalent of omega-lactam.
摘要翻译：一种制备内酰胺共聚物的方法，其包括通过碱性催化剂和多官能助催化剂的作用，在分子末端使ω-内酰胺和具有氨基或亚氨基的二烯聚合物共聚，其组分满足以下式（I）和（II）a / c> 1/4（I）b / c> 1（II）其中a，b和c表示碱性催化剂，多官能助催化剂和二烯聚合物，分别为每当量的ω-内酰胺。

63. 发明授权

US4684746A Activated anionic polymerization of lactams 失效
标题翻译：内酰胺活性阴离子聚合
公开(公告)号：US4684746A
公开(公告)日：1987-08-04
申请号：US750000
申请日：1985-07-01
申请人： Rolf-Volker Meyer , Friedrich Fahnler , Rolf Dhein , Dietrich Michael
发明人： Rolf-Volker Meyer , Friedrich Fahnler , Rolf Dhein , Dietrich Michael
IPC分类号： C08G69/00 , C08G18/10 , C08G18/80 , C08G69/14 , C08G69/18 , C08G69/20 , C08G69/40 , C07C127/24
CPC分类号： C08G69/40 , C08G18/10 , C08G18/8074 , C08G69/18
摘要： Improved activators for anionic polymerization of lactams are biuret-containing polyisocyanates based on non-aromatic diisocyanates.
摘要翻译：用于内酰胺阴离子聚合的改进的活化剂是基于非芳族二异氰酸酯的含缩二脲聚异氰酸酯。

64. 发明授权

US4649177A Process for the preparation of nylon block polymers 失效
标题翻译：尼龙嵌段聚合物的制备方法
公开(公告)号：US4649177A
公开(公告)日：1987-03-10
申请号：US774761
申请日：1985-09-11
申请人： James D. Gabbert , Albert Y. Garner , Ross M. Hedrick
发明人： James D. Gabbert , Albert Y. Garner , Ross M. Hedrick
IPC分类号： C08G65/335 , C08G69/16 , C08G69/40 , C08G69/42 , C08G69/44 , C08G69/14
CPC分类号： C08G69/42 , C08G65/3355 , C08G69/16 , C08G69/40 , C08G69/44
摘要： A process for preparing a nylon block copolymer which comprises bringing into reactive contact lactam monomer, basic lactam polymerization catalyst and a composition containing one or more lactam functional materials selected from the group represented by the formula: ##STR1## wherein, Q is ##STR2## with Y=C.sub.3 -C.sub.11 alkylene; b is an integer equal to 2 or more;R.sub.1 is an alkyl, aryl, aralkyl, alkyloxy, halogen, aryloxy, or aralkyloxy group;Z is a segment of: (1) a polyether, provided said polyether is not solely polyarylene polyether; (2) a polyester containing polyether or polymeric hydrocarbon segments (3) a hydrocarbon; (4) a polysiloxane; or (5) combinations thereof.
摘要翻译：一种制备尼龙嵌段共聚物的方法，其包括使内酰胺单体，碱性内酰胺聚合催化剂和含有一种或多种选自下式所示基团的组合物的组合物：其中Q为其中Y = C3-C11亚烷基; b是等于2或更大的整数; R1是烷基，芳基，芳烷基，烷氧基，卤素，芳氧基或芳烷氧基; Z是以下部分：（1）聚醚，所述聚醚不仅仅是聚亚芳基聚醚; （2）含聚醚或聚合烃段的聚酯（3）烃; （4）聚硅氧烷; 或（5）其组合。

65. 发明授权

US4600770A Water soluble imide coating composition and method of making from lactam, dianhydride and diamine 失效
标题翻译：水溶性酰亚胺涂料组合物和由内酰胺，二酐和二胺制备的方法
公开(公告)号：US4600770A
公开(公告)日：1986-07-15
申请号：US694095
申请日：1985-01-23
申请人： John Gagliani , John V. Long
发明人： John Gagliani , John V. Long
IPC分类号： C08G73/00 , C08G73/10 , C08G73/14 , C09D179/08 , C08G69/14
CPC分类号： C08G73/14
摘要： Methods of making water soluble polyimide resin compositions. A carboxy terminated bisimide is prepared by reacting a suitable aromatic dianhydride with a suitable oxoimine. The bisimide is then mixed with a sufficient quantity of a water soluble solvent to dissolve the bisimide. Water is added to make a solution of the desired viscosity. An aromatic diamine is added to this water solution. To the mixture is added a suitable quantity of a tertiary amine to stabilize the resin. The solution is coated onto a surface and dried to produce a smooth, flexible coating. The coating can then be heated to an appropriate temperature to produce a fully polymerized coating which is thermally stable and resistant to oils and solvents.
摘要翻译：制备水溶性聚酰亚胺树脂组合物的方法。通过使合适的芳族二酐与合适的氧化亚胺反应来制备羧基封端的双酰亚胺。然后将双酰亚胺与足量的水溶性溶剂混合以溶解双酰亚胺。加入水以制成所需粘度的溶液。向该水溶液中加入芳香族二胺。向混合物中加入适量的叔胺以稳定树脂。将溶液涂布在表面上并干燥以产生光滑的柔性涂层。然后可以将涂层加热到合适的温度以产生热稳定且耐油和溶剂的完全聚合的涂层。

66. 发明授权

US4383107A Mixture containing N-cyanolactam for the preparation of nitrogen-containing polyadducts 失效
标题翻译：含有N-酰基内酰胺的混合物用于制备含氮聚合物
公开(公告)号：US4383107A
公开(公告)日：1983-05-10
申请号：US293560
申请日：1981-08-17
申请人： Friedrich Lohse , Dieter Trachsler , Claude Jeannerat
发明人： Friedrich Lohse , Dieter Trachsler , Claude Jeannerat
IPC分类号： C08G73/00 , C08G73/06 , C08G69/14
CPC分类号： C08G73/0655
摘要： A mixture for the preparation of novel crosslinked nitrogen-containing polyadducts, which comprises(a) an N-cyanolactam of the formula I or II ##STR1## and (b) a monomeric or oligomeric organic compound having at least 2 C atoms and at least 2 amino groups or at least 1 amino group and 1 hydroxyl group.The curable mixtures of components (a) and (b) and, if desired, a monoamino compound are suitable for use as casting resins or adhesives, or for the preparation of foams and coatings.The symbols are each as defined in claim 1.
摘要翻译：一种用于制备新的交联含氮多加成物的混合物，其包含（a）式I或II的N-胞内酰胺（II）和（b）单体或低聚有机化合物具有至少2个C原子和至少2个氨基或至少1个氨基和1个羟基。组分（a）和（b）的可固化混合物，如果需要，单一氨基化合物适合用作浇铸树脂或粘合剂，或用于制备泡沫和涂料。符号分别如权利要求1中所定义。

67. 发明授权

US4368317A Mixtures for the preparation of nitrogen-containing polyadducts 失效
标题翻译：用于制备含氮多加合物的混合物
公开(公告)号：US4368317A
公开(公告)日：1983-01-11
申请号：US262571
申请日：1981-05-11
申请人： Friedrich Lohse , Dieter Trachsler
发明人： Friedrich Lohse , Dieter Trachsler
IPC分类号： C08L79/00 , C08G73/00 , C08G73/06 , C08G69/14
CPC分类号： C08G73/0655 , Y10T428/31551 , Y10T428/31786
摘要： A mixture for the preparation of novel cross-linked nitrogen-containing polyadducts, which contains(a) a N-cyanolactam of the formula I or II ##STR1## and (b) a monomeric or oligomeric organic compound having not less than 2 C atoms and not less than 2 hydroxyl groups.The mixture, with or without addition of a monohydroxy compound, can be used as a casting resin or adhesive, or for the production of foams or coatings.The symbols in the formula are all as defined in claim 1.
摘要翻译：一种用于制备新型交联含氮多加合物的混合物，其包含（a）式I或II的N-胞内酰胺（II）和（b）单体或低聚物不少于2个C原子和不少于2个羟基的有机化合物。具有或不加入单羟基化合物的混合物可用作浇铸树脂或粘合剂，或用于生产泡沫或涂料。式中的符号全部如权利要求1中所定义。

68. 发明授权

US4163826A Self-bonding magnet wires and coils made therefrom 失效
标题翻译：自粘电磁线及其制成的线圈
公开(公告)号：US4163826A
公开(公告)日：1979-08-07
申请号：US881940
申请日：1978-02-28
申请人： Munetaka Kawaguchi , Masayoshi Miyake
发明人： Munetaka Kawaguchi , Masayoshi Miyake
IPC分类号： C08G69/00 , C08G69/14 , C08G69/36 , C08G69/48 , C08J3/09 , C09D177/00 , H01B3/30 , H01B7/02 , H01F5/06
CPC分类号： C08J3/091 , H01B3/305 , H01B3/308 , H01F5/06 , C08J2377/00 , Y10S428/90 , Y10T428/2925 , Y10T428/2936 , Y10T428/2947 , Y10T428/31739
摘要： A self-bonding magnet wire suitable for use in making coils, especially deflection yoke coils for television, obtained by coating and baking on a bare conductor or an insulated wire conductor an enamel comprising a polymer solution prepared by reacting two or more copolyamides, at least one of which is a copolyamide containing a nylon-12 unit in the molecule thereof, under heating in a solvent containing at least one compound with a phenolic hydroxyl group in the molecule thereof.
摘要翻译：适用于制造线圈，特别是用于电视机的偏转线圈线圈的自粘合磁线，其通过在裸导体或绝缘导线导体上涂覆和烘烤获得，该搪瓷包含通过使两种或多种共聚酰胺反应制备的聚合物溶液，至少其中之一是在其分子中含有至少一种具有酚羟基的化合物的溶剂加热下含有尼龙-12单元的共聚酰胺。

69. 发明授权

US4126614A Oxacaprolactams 失效
标题翻译： OXACAPROLACTAMS
公开(公告)号：US4126614A
公开(公告)日：1978-11-21
申请号：US890360
申请日：1978-03-27
申请人： Shigeto Suzuki
发明人： Shigeto Suzuki
IPC分类号： C07D267/10 , C07D273/00 , C08G69/14 , C08G69/40 , C07D267/12
CPC分类号： C07D273/00 , C07D267/10 , C08G69/14 , C08G69/40
摘要： 3-OXACAPROLACTAM IS PREPARED BY A PROCESS WHICH COMPRISES: CONTACTING AN ORGANIC ACID ANHYDRIDE SOLUTION OF A CYANOALKOXYALKANOATE WITH HYDROGEN IN THE PRESENCE OF A NOBLE METAL HYDROGENATION CATALYST TO PREPARE AN AMIDE-ESTER; AND HEATING THE AMIDE-ESTER IN EXCESS WATER AT A TEMPERATURE ABOVE ABOUT 200.degree. C.

70. 发明授权

US4055552A Hot-melt adhesives based on anionic terpolymers of lactams 失效
标题翻译：基于内酰胺阴离子三元共聚物的热熔胶
公开(公告)号：US4055552A
公开(公告)日：1977-10-25
申请号：US689964
申请日：1976-05-26
申请人： Zbynek Bukac , Jan Sebenda , Richard Suchy
发明人： Zbynek Bukac , Jan Sebenda , Richard Suchy
IPC分类号： C08G69/18 , C09J177/02 , C08G69/14
CPC分类号： C08G69/18 , C09J177/02 , Y10T428/31739
摘要： The invention relates to hot-melt adhesives based on anionic copolymers of lactams, where one of the starting lactams is 8.octanolactam in the amount of 10-90 mol.% and the other at least 2 lactams containing 6 or more 6 atoms in the ring are in the amount 90-10 mol.%. These further lactams are preferably 6-hexanolactam and 12-dodecanolactam. The melt adhesives may contain further additives, as dyes, fillers, molecular weight regulators, etc. The anionic copolymerization used for their manufacturing is the simple and rapid technique which requires lower temperatures and can be easily performed continuously. The said polyamide melt adhesives are applicable e.g. in clothing and footwear industry and other textile and leather working.
摘要翻译：本发明涉及基于内酰胺阴离子共聚物的热熔粘合剂，其中起始内酰胺之一为10-90mol。％的8-辛内酰胺，另外至少2个内含6个或6个以上6个原子的内酰胺环的量为90-10摩尔％。这些其它的内酰胺优选为6-己内酰胺和12-十二内酰胺。熔融粘合剂可以含有作为染料，填料，分子量调节剂等的其它添加剂。用于其制造的阴离子共聚是需要较低温度并且可以容易地连续进行的简单且快速的技术。所述聚酰胺熔融粘合剂可用于例如在服装和制鞋业等纺织和皮革工作。

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