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    • 63. 发明申请
    • Polyurethane resin aqueous despersion and sheet material obtained from the same
    • 由其得到的聚氨酯树脂水性浸出物和片材
    • US20060111510A1
    • 2006-05-25
    • US10546486
    • 2003-02-25
    • Tadashi TanakaYoshiyuki IwasakiYoshio KobayashiYoshiyuki Ueno
    • Tadashi TanakaYoshiyuki IwasakiYoshio KobayashiYoshiyuki Ueno
    • C08G18/08
    • C08G18/10C08G18/0819C08G18/0823C08G18/0828C08G18/0895C08G18/12C08G18/4238C08G18/44C08G18/6659D06N3/14C08G18/32C08G18/3234C08G18/3228C08G18/302
    • The present invention provides an isocyanate group terminated prepolymer aqueous dispersion (A) that is composed of water and an isocyanate group terminated prepolymer (a) dispersed in the water, whose content in the (A) is in a range of 60 wt % to 85 wt %, wherein the (A) optionally contains a-surfactant in a range of 0 wt % to 10 wt % based on a weight of the (a), and a solvent in a range of 0 ppm to 5,000 ppm based on the weight of the (a). The present invention also provides a polyurethane resin aqueous dispersion (B) that is composed of a polyurethane resin (b), whose content in the (B) is in a range of 20 wt % to 65 wt %, wherein the (b) is obtained by a chain extension reaction of the (A). The present invention is capable of providing a polyurethane resin aqueous dispersion having excellent storage stability. The aqueous dispersion can be used in a polyurethane resin sheet material, a paint, an adhesive, a tackiness agent, or a fiber-treating agent that has less flammability, a high level of safety to the human body, and environmental friendliness, and is effectively applied in a leather-like polyurethane resin sheet material in which migration is prevented.
    • 本发明提供一种由水分散在水中的异氰酸酯基封端的预聚物(a)组成的异氰酸酯基封端的预聚物水分散体(A),其中(A)的含量在60重量%〜85的范围内 重量%,其中(A)任选地包含基于(a)的重量在0重量%至10重量%范围内的α-表面活性剂,并且基于重量的溶剂在0ppm至5,000ppm的范围内 (a)项。 本发明还提供一种由(B)含量在20重量%〜65重量%的范围内的聚氨酯树脂(b)构成的聚氨酯树脂水分散体(B),其中(b)为 通过(A)的扩链反应获得。 本发明能够提供具有优异的储存稳定性的聚氨酯树脂水分散体。 水性分散体可以用于具有较低的可燃性,对人体的高度安全性和环境友好性的聚氨酯树脂片材,涂料,粘合剂,粘合剂或纤维处理剂,并且是 有效地应用于防止迁移的皮革状聚氨酯树脂片材。
    • 65. 发明申请
    • Method and system for mammalian joint resurfacing
    • 哺乳动物关节表面置换的方法和系统
    • US20040107000A1
    • 2004-06-03
    • US10722019
    • 2003-11-24
    • Jeffrey C. FeltMark A. RydellPaul J. BuscemiAlexander ArsenyevChristopher H. Porter
    • A61F002/38
    • A61B17/562A61F2/30721A61F2/34A61F2/38A61F2/3872A61F2/3877A61F2/389A61F2002/30535A61F2250/0058A61L27/18A61L2430/24C08G18/10C08G18/4854C08G18/61C08G18/69C08L75/04C08G18/32
    • A method and system for the creation or modification of the wear surface of orthopedic joints, involving the preparation and use of one or more partially or fully preformed and procured components, adapted for insertion and placement into the body and at the joint site. In a preferred embodiment, component(s) can be partially cured and generally formed ex vivo and further and further formed in vivo at the joint site to enhance conformance and improve long term performance. In another embodiment, a preformed balloon or composite material can be inserted into the joint site and filled with a flowable biomaterial in situ to conform to the joint site. In yet another embodiment, the preformed component(s) can be fully cured and formed ex vivo and optionally further fitted and secured at the joint site. Preformed components can be sufficiently pliant to permit insertion through a minimally invasive portal, yet resilient enough to substantially assume, or tend towards, the desired form in vivo with additional forming there as needed.
    • 一种用于创建或修改整形外科关节磨损表面的方法和系统,涉及准备和使用一种或多种部分或完全预成型和采购的部件,适于插入和放置在身体和关节部位。 在一个优选的实施方案中,组分可以部分固化,并且通常在体外形式离体进一步形成并且在接合部位进一步形成,以增强一致性并改善长期性能。 在另一个实施方案中,预先形成的球囊或复合材料可以插入到关节部位中并且在原位填充可流动的生物材料以符合关节部位。 在另一个实施方案中,预成型组分可以完全固化并离体形成,并任选地进一步装配并固定在接头部位。 预成型组件可以足够柔顺以允许通过微创入口插入,但足够弹性足以基本上假设或倾向于体内所需的形式,并根据需要进一步形成。
    • 66. 发明授权
    • Polyurethane/polyurethane-urea resin and process for producing the same
    • 聚氨酯/聚氨酯 - 脲树脂及其制造方法
    • US06503997B1
    • 2003-01-07
    • US09700658
    • 2000-11-17
    • Joichi SaitoJosho Kashiwame
    • Joichi SaitoJosho Kashiwame
    • C08G1812
    • C08G18/4866C08G18/10C08G18/12C08G18/4812C08G18/32C08G18/48
    • A polyurethane/polyurethane urea resin obtained by reacting an isocyanate group-terminated polyurethane prepolymer (A) obtained by reaction of high molecular weight active hydrogen compound and a polyisocyanate compound, with a chain extender (B), in a solvent and thereafter by removing the solvent, wherein the isocyanate group-terminated polyurethane prepolymer (A) is an isocyanate group-terminated polyurethane prepolymer obtained by reacting the following polyol (1) with a polyisocyanate compound in the presence of an excess amount of an isocyanate group, followed by reacting the following polyol (2) with the reaction product of polyol (1) in the presence of an excess amount of an isocyanate group; Polyol (1): a polyoxyalkylene polyol having a hydroxyl group value of at most 70, a total unsaturation degree of at most 0.07 meq/g and an oxypropylene group content of at least 70 wt % containing a secondary hydroxyl terminal group, Polyol (2): polyoxytetramethylene glycol, polyester polyol, polycaprolactone polyol or a polycarbonate polyol.
    • 将通过高分子量活性氢化合物与多异氰酸酯化合物反应获得的异氰酸酯基封端的聚氨酯预聚物(A)与扩链剂(B)在溶剂中反应得到的聚氨酯/聚氨酯脲树脂, 溶剂,其中异氰酸酯基封端的聚氨酯预聚物(A)是通过在过量的异氰酸酯基团的存在下使下列多元醇(1)与多异氰酸酯化合物反应获得的异氰酸酯基封端的聚氨酯预聚物, 多元醇(2)与多元醇(1)的反应产物在过量的异氰酸酯基团存在下反应;多元醇(1):羟基值至多为70的聚氧化烯多元醇,总不饱和度为 最多0.07meq / g,含有至少70wt%的氧亚丙基基团含有仲羟基端基,多元醇(2):聚氧四亚甲基二醇,聚酯多元醇 ,聚己内酯多元醇或聚碳酸酯多元醇。