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61. 发明授权

US4346193A Continuous process for making star-block copolymers 失效
标题翻译：制备星形嵌段共聚物的连续工艺
公开(公告)号：US4346193A
公开(公告)日：1982-08-24
申请号：US260150
申请日：1981-05-04
申请人： David R. Warfel
发明人： David R. Warfel
IPC分类号： C08F297/04 , C08G81/02
CPC分类号： C08F297/044 , C08G81/022
摘要： A continuous anionic solution process for preparing star-block copolymers of monovinylaromatic compounds and conjugated dienes having either monomodal or bimodal arm structure is described. The process utilizes a continuous tubular reactor made up of a sequence of four static mixer zones followed by a pressure control valve.
摘要翻译：描述了用于制备具有单峰或双峰臂结构的单乙烯基芳族化合物和共轭二烯的星形嵌段共聚物的连续阴离子溶液方法。该方法利用由四个静态混合器区序列组成的连续管状反应器，随后是压力控制阀。

62. 发明授权

US4291139A Process for preparation of block copolymers 失效
标题翻译：嵌段共聚物的制备方法
公开(公告)号：US4291139A
公开(公告)日：1981-09-22
申请号：US776048
申请日：1977-03-09
申请人： Adel F. Halasa , James E. Hall , Adolph Para
发明人： Adel F. Halasa , James E. Hall , Adolph Para
IPC分类号： C08F297/04
CPC分类号： C08F297/044
摘要： The process described herein involves the preparation of block copolymers of the S-B-S type wherein S represents a block of polystyrene and B represents a block of polybutadiene. In order to have the initial polystyrene block soluble in the polymerization medium, cyclohexane and aromatic hydrocarbons have been used as the diluent or solvent in these polymerizations. The present process permits the use of hexane as diluent by first preparing a "foot" or small block of homopolydiene to which the initial polystyrene block is thereafter attached. This small block of homopolydiene represents no more than 12 parts, preferably no more than 10 parts by weight of homopolydiene per 100 parts by weight of the block of polystyrene to which it is attached. Generally therefore this block has a molecular weight of 200-5000 depending on the size of the attached polystyrene block and is not large enough to alter the properties of the resultant S-B-S block copolymer except to give the initial polystyrene block greater dispersibility in hexane, heptane, etc.
摘要翻译：本文所述的方法涉及制备S-B-S型嵌段共聚物，其中S代表聚苯乙烯嵌段，B代表聚丁二烯嵌段。为了使初始聚苯乙烯嵌段可溶于聚合介质，环己烷和芳烃已经用作这些聚合中的稀释剂或溶剂。本方法允许使用己烷作为稀释剂，首先制备其后连接初始聚苯乙烯嵌段的“脚”或均聚二烯的小嵌段。该均聚亚丁基的该小块相对于每100重量份其所连接的聚苯乙烯嵌段，不超过12重量份，优选不超过10重量份的均聚二烯。因此，通常该嵌段的分子量为200-5000，取决于连接的聚苯乙烯嵌段的尺寸，并且不足以改变所得SBS嵌段共聚物的性能，除了使初始聚苯乙烯嵌段在己烷，庚烷，等等

63. 发明授权

US4167545A Branched block copolymers and their manufacture 失效
标题翻译：支链嵌段共聚物及其制备方法
公开(公告)号：US4167545A
公开(公告)日：1979-09-11
申请号：US896478
申请日：1978-04-14
申请人： Gerhard Fahrbach , Karl Gerberding , Erhard Seiler , Dieter Stein
发明人： Gerhard Fahrbach , Karl Gerberding , Erhard Seiler , Dieter Stein
IPC分类号： C08F297/04 , C08G81/02
CPC分类号： C08G81/022 , C08F297/044
摘要： Branched block copolymers of from 60 to 95 percent by weight of a monovinyl-aromatic compound and from 40 to 5 percent by weight of a conjugated diene.The branched block copolymers have a structure of the general formula(A.sup.1 --A.sup.2 --B.fwdarw.A.sup.3).sub.n --X--(A.sup.3 .rarw.B--A.sup.2).sub.mwhere the A's are non-elastomeric polymer segments based on the monovinyl-aromatic compound, the B's are elastomeric polymer segments based on the conjugated diene, X is the radical of an at least trifunctional coupling agent and n and m are numbers.The branched block copolymers may be used for the manufacture of highly transparent impact-resistant shaped articles, especially packaging materials.
摘要翻译： 60至95重量％的单乙烯基 - 芳族化合物和40至5重量％的共轭二烯的支链嵌段共聚物。

64. 发明授权

US4091053A Coupled resinous diene copolymer with good integral hinge flex life and high hardness 失效
标题翻译：偶联树脂二烯共聚物具有良好的整体铰链弯曲寿命和高硬度
公开(公告)号：US4091053A
公开(公告)日：1978-05-23
申请号：US699731
申请日：1976-06-24
申请人： Alonzo G. Kitchen
发明人： Alonzo G. Kitchen
IPC分类号： C08F2/00 , C08F2/02 , C08F297/00 , C08F297/02 , C08F297/04 , C08G81/02
CPC分类号： C08F297/044 , C08G81/022
摘要： A conjugated diene/monovinyl-substituted aromatic compound resinous copolymer such as a styrene/butadiene block copolymer is produced using two additions of the monovinyl-substituted aromatic component and initiator in a manner such that the product has 71 to 81 wt. percent monovinyl-substituted aromatic component and has a ratio based on the number average molecular weight of monovinyl-substituted aromatic component blocks in first and second polymer chains thus produced prior to coupling within the range of 3 to 7. The final product resulting from coupling such polymers has long integral hinge flex life and high hardness. This is accomplished by using no more than 5 millimoles of initiator per mole of monomer in the second addition.
摘要翻译：共轭二烯/单乙烯基取代的芳族化合物树脂共聚物如苯乙烯/丁二烯嵌段共聚物是使用两种添加的单乙烯基取代的芳族组分和引发剂，使得产物具有71至81重量％百分比单乙烯基取代的芳族组分，并且具有基于在偶联之前在3至7的范围内由此制备的第一和第二聚合物链中单乙烯基取代的芳族组分嵌段的数均分子量的比例。聚合物具有长整体铰链弯曲寿命和高硬度。这通过在第二次添加中使用不超过5毫摩尔引发剂/摩尔单体来实现。

65. 发明授权

US3992483A Promoters in the polymerization of monovinyl-aromatic compounds with primary lithium initiators 失效
标题翻译：单乙烯基芳族化合物与一次锂引发剂聚合中的促进剂
公开(公告)号：US3992483A
公开(公告)日：1976-11-16
申请号：US616534
申请日：1975-09-25
申请人： Daniel H. Willis
发明人： Daniel H. Willis
IPC分类号： C08F2/38 , C08F12/00 , C08F297/04 , C08G81/02 , C08F293/00
CPC分类号： C08G81/022 , C08F297/04 , C08F297/044 , Y10S525/901
摘要： 1,1-DIALKYLETHYLENES, SUCH AS ISOBUTENE, PROMOTE THE PRIMARY LITHIUM INITIATED POLYMERIZATION OF MONOVINYL-AROMATIC COMPOUNDS, SUCH AS SYTRENE, EITHER IN HOMOPOLYMERIZATIONS, OR IN THE FORMATION OF A--B--A block copolymers or (A--B).sub.a Z radial block copolymers, such as by sequential monomer addition with conjugated dienes.
摘要翻译： 1,1-DIALKYLETHYLENES，如ISOBUTENE，促进单酚锂芳族化合物的初始锂离子聚合，如甲基丙烯酸酯，或者在共聚合中，或形成ABA嵌段共聚物或（AB）aZ径向嵌段共聚物，如连续单体加成共轭二烯。

66. 发明申请

US20170275505A1 PRESSURE SENSITIVE ADHESIVES COMPRISING A POLYMODAL ASYMMETRIC MULTIARM ELASTOMERIC BLOCK COPOLYMER 审中-公开
公开(公告)号：US20170275505A1
公开(公告)日：2017-09-28
申请号：US15529629
申请日：2015-12-04
申请人： 3M INNOVATIVE PROPERTIES COMPANY
发明人： Surojit Sinha , Raja Krishnamurthy , Joon Chatterjee
IPC分类号： C09J7/02 , C08F297/04 , C09J153/02
CPC分类号： C08L9/00 , C08F297/044 , C09J7/387 , C09J153/02 , C09J2409/00 , C09J2453/00
摘要： Pressure sensitive adhesives made from a polymodal asymmetric elastomeric block copolymer, a tackifying resin and liquid polyisoprene are provided. Articles containing these pressure sensitive adhesives including protective sheeting, labels, laminated adhesives, tapes and adhesive films are described. The pressure sensitive adhesive based on polymodal asymmetric block copolymer described herein exhibits good adhesion on various substrates such as stainless steel (SS), polypropylene (PP) and high density polyethylene (HDPE) and enhanced high temperature shear without the effect of electron beam or UV curing.

67. 发明申请

US20170275392A1 BLOCK COPOLYMERS HAVING SEMI-CRYSTALLINE BLOCKS AND COMPOSITIONS AND ARTICLES MADE THEREFROM 审中-公开
公开(公告)号：US20170275392A1
公开(公告)日：2017-09-28
申请号：US15466207
申请日：2017-03-22
申请人： KRATON POLYMERS U.S. LLC
发明人： John E. Flood , Carl L. WILLIS , Robert C. Bening , Hendrik De Groot , Xavier D.D.J. Muyldermans , David T. Williamson , Dale L. Handlin, Jr. , Robert Dossett
IPC分类号： C08F8/04 , C08L23/14 , C08L53/02 , C08J5/18 , C08L23/06
CPC分类号： C08F8/04 , C08F297/044 , C08J5/18 , C08J2353/02 , C08J2423/06 , C08L23/06 , C08L23/0815 , C08L23/14 , C08L53/025 , C08L2205/02 , C08L2205/03 , C08L2207/066 , C08L23/12 , C08F297/04
摘要： Selectively hydrogenated block copolymers having semi-crystalline blocks hard blocks and copolymer soft blocks having a combination of excellent physical properties and solvent resistance have been discovered. The block copolymer comprises at least one A block of hydrogenated, polymerized 1,3-butadiene and at least one B block which is a random copolymer or a controlled distribution copolymer of conjugated diene and mono vinyl aromatic monomers in which the conjugated diene monomer units are selectively hydrogenated. Polar functionalized block embodiments of the block copolymers are also disclosed. Compositions comprising the block copolymer and articles made from the block copolymer have also been discovered. A method is disclosed which provides highly isotropic, high strength melt cast films of block copolymers.

68. 发明申请

US20170081457A1 Styrene-Butadiene Block Copolymers With A Terminal Butadiene Block For Tubing Applications 有权
公开(公告)号：US20170081457A1
公开(公告)日：2017-03-23
申请号：US14857875
申请日：2015-09-18
申请人： Chevron Phillips Chemical Company LP
发明人： Jinping Joe Zhou , Walter H. Pace , David A. Young
IPC分类号： C08F293/00 , A61L29/04 , A61L29/14 , C08L53/02
CPC分类号： C08F293/005 , A61L29/041 , A61L29/049 , A61L29/14 , C08F297/044 , C08L53/02 , C08L2203/02 , C08L25/06 , C08L25/10
摘要： Conjugated diene monovinylarene block copolymers containing a terminal conjugated diene end block and having superior kink resistance properties are disclosed. These copolymers can be used to produce tubing and other end-use articles, and can be a replacement for flexible PVC.

69. 发明授权

US09441090B1 Methods for controlling hardness of styrene-butadiene block copolymers 有权
标题翻译：控制苯乙烯 - 丁二烯嵌段共聚物硬度的方法
公开(公告)号：US09441090B1
公开(公告)日：2016-09-13
申请号：US14645841
申请日：2015-03-12
申请人： Chevron Phillips Chemical Company LP
发明人： Jinping Joe Zhou
IPC分类号： C08K5/15 , C08K5/1535 , C08K5/057
CPC分类号： C08K5/1535 , C08F297/044 , C08K5/057
摘要： Methods for controlling properties of a conjugated diene monovinylarene block copolymer using a modifier during polymerization are disclosed. For instance, the Shore A hardness of the copolymer can be decreased via the addition of the modifier compound.
摘要翻译：公开了在聚合过程中使用改性剂控制共轭二烯单乙烯基芳烃嵌段共聚物性能的方法。例如，可以通过加入改性剂化合物来降低共聚物的肖氏A硬度。

70. 发明申请

US20160115269A1 PROCESS FOR PRODUCING HYDROGENATED BLOCK COPOLYMER, HYDROGENATED BLOCK COPOLYMER OBTAINED BY THE PROCESS, AND COMPOSITION THEREOF 审中-公开
标题翻译：生产加氢嵌段共聚物的方法，由该方法获得的加氢嵌段共聚物及其组合物
公开(公告)号：US20160115269A1
公开(公告)日：2016-04-28
申请号：US14982892
申请日：2015-12-29
申请人： KURARAY CO., LTD.
发明人： Takaaki NISHIKAWA , Yosuke JOGO , Nobuhiro MORIGUCHI , Mizuho MAEDA
IPC分类号： C08F297/04 , C08K5/01
CPC分类号： C08F297/046 , C08F8/04 , C08F2800/20 , C08K5/01 , C08L53/025 , C08F297/044 , C08L91/00
摘要： The present invention relates to a method for producing a hydrogenated block copolymer, including the steps of: (a) forming a block copolymer by allowing a living polymer having a specific structure to react with a tetra- or more functional silane coupling agent; (b) hydrogenating the block copolymer to form a hydrogenated block copolymer; (c) isolating the resultant hydrogenated block copolymer; and (d) deactivating a functional group in the silane coupling agent and/or an unreacted functional group present in a coupling agent residue in the block copolymer or the hydrogenated block copolymer prior to the step (c), in which the number of functional groups derived from the coupling agent in the hydrogenated block copolymer recovered in the step (c) is 1.5 or less per block copolymer molecule; a hydrogenated block copolymer obtained by the method; and a composition containing the hydrogenated block copolymer.
摘要翻译：本发明涉及一种氢化嵌段共聚物的制备方法，包括以下步骤：（a）通过使具有特定结构的活性聚合物与四官能的硅烷偶联剂反应形成嵌段共聚物; （b）使嵌段共聚物氢化以形成氢化嵌段共聚物; （c）分离得到的氢化嵌段共聚物; 和（d）在步骤（c）之前使嵌段共聚物或氢化嵌段共聚物中的偶联剂残基中存在的硅烷偶联剂和/或未反应官能团中的官能团失活，其中官能团的数目衍生自步骤（c）中回收的氢化嵌段共聚物中的偶联剂的每嵌段共聚物分子为1.5以下; 通过该方法获得的氢化嵌段共聚物; 和含有氢化嵌段共聚物的组合物。

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