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    • 63. 发明申请
    • ZIEGLER-NATTA CATALYST COMPOSITION WITH CONTROLLED MORPHOLOGY
    • ZIEGLER-NATTA催化剂组合物与控制形态
    • US20120202955A1
    • 2012-08-09
    • US13022021
    • 2011-02-07
    • LEI ZHANGKenneth BlackmonDavid Rauscher
    • LEI ZHANGKenneth BlackmonDavid Rauscher
    • C08F4/60
    • C08F10/00C08F110/02C08F4/6557C08F2500/04C08F2500/11C08F2500/12C08F2500/17C08F2500/18C08F2500/20C08F2500/23C08F2500/26
    • Catalyst Systems, processes of forming the same and polymers and polymerization processes are described herein. The process of forming the catalyst system generally includes providing a first compound including a magnesium dialkoxide and aluminum alkoxide: contacting the first compound with a first agent and a second agent to form a solution of reaction product “A”, the first agent including a titanating agent and the second agent including a first metal halide; contacting the solution of reaction product “A” with a third agent to form a solid reaction product “B”, the third agent including a second metal halide: contacting the solid reaction product “B” with a fourth agent to form a solid reaction product “C”, the fourth agent including a third metal halide: optionally contacting the solid reaction product “C” with a fifth agent to form a solid reaction product “D”, the fifth agent including a fourth metal halide; and contacting the solid reaction product “C” or “D” with a sixth agent to form a catalyst component, the sixth agent including a first organoaluminum compound.
    • 催化剂体系,其形成方法,聚合物和聚合方法在本文中描述。 形成催化剂体系的方法通常包括提供包含二烷氧基镁和烷氧化铝的第一化合物:使第一化合物与第一试剂和第二试剂接触以形成反应产物“A”的溶液,第一试剂包括滴定 试剂和第二试剂包括第一金属卤化物; 使反应产物“A”的溶液与第三试剂接触以形成固体反应产物“B”,第三试剂包括第二金属卤化物:使固体反应产物“B”与第四试剂接触以形成固体反应产物 “C”,第四剂包括第三金属卤化物:任选地使固体反应产物“C”与第五试剂接触以形成固体反应产物“D”,第五试剂包括第四金属卤化物; 并使固体反应产物“C”或“D”与第六试剂接触以形成催化剂组分,第六试剂包括第一有机铝化合物。