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61. 发明授权

US5210064A Stabilization of thermal images 失效
标题翻译：热图像稳定
公开(公告)号：US5210064A
公开(公告)日：1993-05-11
申请号：US795102
申请日：1991-11-20
申请人： Rita S. Shon Baker , Larry C. Takiff
发明人： Rita S. Shon Baker , Larry C. Takiff
IPC分类号： B41M5/323 , B41M5/337
CPC分类号： B41M5/34 , B41M5/323 , B41M5/3375
摘要： The addition, to a thermal imaging medium comprising a color-forming compound which undergoes a change of color upon heating above a color-forming temperature for a color-forming time, the color-forming compound being of the cyclic sulfonamide type described in U.S. Pat. Nos. 4,720,449 and 4,960,901, of a quinone or hydroquinone increases the sensitivity of the imaging medium and helps to prevent fading of images produced therefrom while the images are being projected.
摘要翻译：另外，对于包含成色化合物的热成像介质，在成色温度高于成色时间的情况下在加热时发生颜色变化，成色化合物为US Pat中描述的环状磺酰胺类型。醌或氢醌的4,720,449和4,960,901号增加了成像介质的灵敏度，并有助于防止在投影图像时由其产生的图像的褪色。

62. 发明授权

US5153169A Imaging media containing hindered amine light stabilizers or nitrones 失效
标题翻译：含有受阻胺光稳定剂或硝酮的成像介质
公开(公告)号：US5153169A
公开(公告)日：1992-10-06
申请号：US695932
申请日：1991-05-06
申请人： James R. Freedman , Michael A. Young
发明人： James R. Freedman , Michael A. Young
IPC分类号： B41M5/323 , B41M5/337
CPC分类号： B41M5/3375 , B41M5/323
摘要： An imaging medium has at least one color-forming layer comprising a thermal color-forming composition adapted to undergo a change of color upon increase in the temperature of the color-forming layer above a color-forming temperature for a color-forming time, the color-forming layer further comprising a color stabilizer which is a hindered amine light stabilizer or a nitrones. The color stabilizer prevents development of color in the medium during storage before or after imaging, thereby reducing the minimum optical density of the imaged medium and/or color distortion in the image.
摘要翻译：成像介质具有至少一个成色层，其包含热成色组合物，该成色组合物适于在成色层的成色温度高于成色时间时，随着成色层的温度升高而发生颜色变化，成色层还包含作为受阻胺光稳定剂或硝酮的颜色稳定剂。颜色稳定器防止在成像之前或之后的存储期间介质中的颜色显影，从而降低成像介质的最小光密度和/或图像中的/或颜色失真。

63. 发明授权

US5143891A Divinyl carbinol or carbinol derivative chromogenic compounds and their use in record material 失效
标题翻译：二乙醇胺或碳氢化合物衍生化学化合物及其在记录材料中的用途
公开(公告)号：US5143891A
公开(公告)日：1992-09-01
申请号：US613019
申请日：1990-11-15
申请人： Kenneth J. Shanton
发明人： Kenneth J. Shanton
IPC分类号： B41M5/132 , B41M5/136 , B41M5/165 , B41M5/323 , C07C215/68 , C07C217/76 , C07C225/22 , C07D209/12 , C07D209/86
CPC分类号： C07D209/86 , B41M5/136 , B41M5/323 , C07C215/68 , C07C217/76 , C07D209/12
摘要： A chromogenic compound for use in pressure- or heat-sensitive record material has the general formula (I):R.sub.1 --CH.dbd.CH--CR.sub.3 (OR.sub.4)--CH.dbd.CH--R.sub.2 (I)in which: R.sub.1 and R.sub.2 are the same or different and each is a group of one of the formula (II): ##STR1## in which the benzene ring of the group of formula (IIa) is optionally further substituted, and in which: R.sub.10 and R.sub.11 are each independently hydrogen or an optionally-substituted alkyl, aryl or aralkyl group, or R.sub.10 and R.sub.11 together with the nitrogen atom to which they are attached form an optionally-substituted heterocyclic ring, which may include one or more further hetero atoms; R.sub.12, and R.sub.13 and R.sub.14 are each independently hydrogen or an optionally-substituted alkyl, aryl or aralkyl group; R.sub.3 is an optionally-substituted aryl group; and R.sub.4 is hydrogen or an optionally-substituted alkyl, aryl or aralkyl group.

64. 发明授权

US5116978A Process for bis(indolyl)ethylene synthesis 失效
标题翻译：双（吲哚基）乙烯合成方法
公开(公告)号：US5116978A
公开(公告)日：1992-05-26
申请号：US615731
申请日：1990-11-19
申请人： Ponnampalam Mathiaparanam
发明人： Ponnampalam Mathiaparanam
IPC分类号： B41M5/136 , B41M5/145 , B41M5/323 , B41M5/327
CPC分类号： B41M5/323 , B41M5/136 , B41M5/145 , B41M5/327
摘要： A process for producing a bis-(indolyl)ethylene of the formula ##STR1## is described, wherein A, B, a, b, R, Z, R.sup.5', R.sup.6 and R.sup.6' are as defined in the specification, said method comprising reacting an indole of the formula ##STR2## with an acylindole of the formula in the presence of a Vilsmeier reagent selected from the group consisting of phosphoryl chloride, phosgene, oxalyl chloride, benzoyl chloride, thionyl chloride, alkanesulfonyl chloride, arene-sulfonyl chloride, alkylchoroformate, and arylchloroformate, together with a Lewis Acid selected from the group consisting of zinc chloride, boron trifluoride and aluminum chloride.
摘要翻译：描述了制备式“IMAGE”的双（吲哚基）乙烯的方法，其中A，B，a，b，R，Z，R 5'，R 6和R 6'如说明书中所定义，所述方法包括在选自磷酰氯，光气，草酰氯，苯甲酰氯，亚硫酰氯，烷烃磺酰氯，芳烃磺酰氯，苯磺酰氯，磺酰氯，烷基氯甲酸酯和氯甲酸芳基酯，以及选自氯化锌，三氟化硼和氯化铝的路易斯酸。

65. 发明授权

US5084593A Leuco dyes and recording material employing the same 失效
标题翻译：白癜风和记录材料使用
公开(公告)号：US5084593A
公开(公告)日：1992-01-28
申请号：US627583
申请日：1990-12-14
申请人： Hiroshi Gotoh , Shigeru Kusakata , Isao Shiojima
发明人： Hiroshi Gotoh , Shigeru Kusakata , Isao Shiojima
IPC分类号： B41M5/136 , B41M5/155 , B41M5/323 , B41M5/333
CPC分类号： B41M5/323 , B41M5/136 , B41M5/155 , B41M5/3335
摘要： Leuco dyes of the formula (I) are disclosed, ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent an alkyl group having 1 to 10 carbon atoms; X represents hydrogen, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms or a halogen; and Y represents R.sub.5 --Z--SO.sub.2 NH--, R.sub.6 --Z--CONH--, or ##STR2## in which Z represents ##STR3## R.sub.5 and R.sub.6 each represent hydrogen, an alkyl group having 1 to 10 carbon atoms, or a halogen; and R.sub.7 and R.sub.8 each represent hydrogen, a cyano group, or --COR.sub.9, in which R.sub.9 represents a lower alkyl group, a lower alkoxyl group, a phenyl group which may be substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms, or a halogen; a naphthyl group which may be substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms or a halogen with the proviso that R.sub.7 and R.sub.8 are not both hydrogen. Further a recording material comprising any of the above-mentioned leuco dyes and a particular phenolic compound as a color developer capable of inducing color formation in the leuco dye is disclosed.
摘要翻译：公开了式（I）的无色染料，其中R 1，R 2，R 3和R 4各自表示具有1至10个碳原子的烷基; X表示氢，碳原子数1〜10的烷基，碳原子数1〜10的烷氧基或卤素; 并且Y表示R5-Z-SO2NH-，R6-Z-CONH-或其中Z表示R5和R6各自表示氢，具有1-10个碳原子的烷基或卤素的并且R 7和R 8各自表示氢，氰基或-COR 9，其中R 9表示低级烷基，低级烷氧基，可被碳原子数1〜4的烷基取代的苯基，烷氧基具有1至4个碳原子的基团，或卤素; 可以被碳原子数1〜4的烷基取代的萘基，碳原子数1〜4的烷氧基或卤素，条件是R 7和R 8不都是氢。还公开了一种记录材料，其包含任何上述无色染料和特定的酚类化合物作为能够诱导无色染料形成颜色的彩色显影剂。

66. 发明授权

US5013707A Pressure- or heat-sensitive recording material 失效
标题翻译：压敏或热敏记录材料
公开(公告)号：US5013707A
公开(公告)日：1991-05-07
申请号：US450650
申请日：1989-12-14
申请人： Rox Phaff , Rudolf Zink
发明人： Rox Phaff , Rudolf Zink
IPC分类号： B41M5/136 , B41M5/145 , B41M5/323 , B41M5/327
CPC分类号： B41M5/323 , B41M5/136 , B41M5/145 , B41M5/327
摘要： Pressure-sensitive or heat-sensitive recording material in which the color reactant system contains, as essential components,(A) an electron-donating compound of the formula ##STR1## in which Y.sub.1 and Y.sub.2 are substituents which are detachable as anions and can be identical, different or bound to one another and Q.sub.1 is --O--, --S--, >N--R or >N--NH--R,Q.sub.2 is --CH.sub.2 --, --CO--, --CS-- or SO.sub.2 --,R is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.10 cycloalkyl, aryl or aralkyl and ring A is an aromatic radical which has 6 ring atoms and can contain an aromatic fused ring, it being possible not only for ring A but also for the fused ring to be substituted,(B) two organic condensation components which are identical to or different from one another and together are capable of forming a chromogenic compound with component (A) and(C) an electron-withdrawing and color-developing component.
摘要翻译：作为必要成分，着色反应体系含有（A）下式的供电子化合物（1）的压敏或热敏记录材料，其中Y 1和Y 2是作为阴离子可分离的取代基并且可以彼此相同，不同或相互结合，并且Q 1是-O - ， - S - ，> NR或> N-NH-R，Q 2是-CH 2 - ， - CO - ， - SO-或SO 2 - 是氢，C 1 -C 12烷基，C 5 -C 10环烷基，芳基或芳烷基，环A是具有6个环原子并且可以含有芳香稠环的芳族基团，不仅可以是环A而且也可以是稠环（B）两个彼此相同或不同的有机缩合组分，并且一起能够与组分（A）和（C）形成吸电子和显色组分的显色化合物。

67. 发明授权

US4939117A Leuco dyes and recording material employing the same 失效
标题翻译：无色染料和采用其的记录材料
公开(公告)号：US4939117A
公开(公告)日：1990-07-03
申请号：US291675
申请日：1988-12-29
申请人： Shigeru Kusakata , Hiroshi Gotoh , Isao Shiojima
发明人： Shigeru Kusakata , Hiroshi Gotoh , Isao Shiojima
IPC分类号： B41M5/323
CPC分类号： B41M5/323
摘要： A leuco dye of the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 each represent a lower alkyl group; A represents ##STR2## in which R.sup.9 and R.sup.10 each represent hydrogen, provided that both R.sup.9 and R.sup.10 may not be hydrogen, --CN or --COR.sup.14 in which R.sup.14 represents a phenyl group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms, or a halogen, a naphthyl group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms or a halogen, or a lower alkoxyl group, ##STR3## in which ##STR4## represents a phenyl group or a naphthyl group, R.sup.11 represents hydrogen, a lower alkyl group, a halogen, an amino group, which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, or a nitro group, or ##STR5## in which R.sup.12 represents a lower alkyl group, or ##STR6## in which R.sup.13 represents hydrogen, a lower alkyl group, a halogen, a hydroxyl group, a trifluoromethyl group, a nitro group, an amino group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, or amide group. These dyes absorb in the near-infrared region and yields colored images with a color developer therefor with excellent preservability.
摘要翻译：式（I）的无色染料：其中R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8各自表示低级烷基; A表示，其中R 9和R 10各自表示氢，条件是R 9和R 10可以不是氢，-CN或-COR 14，其中R 14表示未被取代或被具有1至 4个碳原子，具有1至4个碳原子的烷氧基或卤素，未被取代或被具有1至4个碳原子的烷基取代的萘基，具有1至4个碳原子的烷氧基或卤素，或低级烷氧基，其中表示苯基或萘基，R11表示氢，低级烷基，卤素，氨基，未取代或被烷基取代的低级烷氧基具有1至4个碳原子的硝基或硝基，或其中R 12表示低级烷基的“IMAGE”，或其中R 13表示氢，低级烷基，卤素，羟基，三氟甲基硝基，未取代或被取代的氨基具有1〜4个碳原子的烷基或酰胺基。这些染料在近红外区域吸收并产生具有显色剂的彩色图像，具有优异的保存性。

68. 发明授权

US4939116A Thermosensitive recording material 失效
标题翻译：热敏记录材料
公开(公告)号：US4939116A
公开(公告)日：1990-07-03
申请号：US349649
申请日：1989-05-10
申请人： Takashi Ueda , Keiichi Maruta , Hiroshi Yaguchi
发明人： Takashi Ueda , Keiichi Maruta , Hiroshi Yaguchi
IPC分类号： B41M5/323 , B41M5/333
CPC分类号： B41M5/323 , B41M5/3335 , Y10S428/913 , Y10S428/914
摘要： A thermosensitive recording material is disclosed, which comprises (a) a support material; (b) a first thermosensitive coloring layer which comprises a first colorless or light-colored leuco dye having formula (I), ##STR1## and a first color developer having formula (II) capable of inducing color formation in said first leuco dye upon application of heat thereto; ##STR2## (c) a second thermosensitive coloring layer which comprises at least a second leuco dye having formula (III), ##STR3## the first and second thermosensitive coloring layers being formed on the support.

69. 发明授权

US4904637A Recording material comprising chromogenic 3,1-benzoxazines 失效
标题翻译：包含显色3,1-苯并恶嗪的记录材料
公开(公告)号：US4904637A
公开(公告)日：1990-02-27
申请号：US311002
申请日：1989-02-14
申请人： Horst Berneth
发明人： Horst Berneth
IPC分类号： B41M5/136 , B41M5/323 , C07D265/16 , C07D413/04 , C07D413/10 , C07D413/12 , C09B11/02 , C09B11/04 , C09B19/00 , G02F1/17
CPC分类号： C09B11/04 , B41M5/136 , B41M5/323 , C07D265/16 , C07D413/04 , C09B11/02
摘要： Compounds of the formula ##STR1## wherein Z.sup.1 denotes hydrogen, alkyl, cycloalkyl or ##STR2## R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl, heteroalkyl or heteryl,X.sup.1, X.sup.2 and X.sup.3 denote hydrogen, halogen, alkyl, cycloalkyl, aryl, alkanoylamino, aroylamino or heteryl, and at least one of these radicals denotes NH.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,Y.sup.1, Y.sup.2 and Y.sup.3 denote hydrogen, alkyl, cycloalkyl, aralkyl, aryl or heteryl andY.sup.1 +Y.sup.2 denote the remaining members of a 5-membered or 6-membered ring which optionally contains further hetero-atoms,are outstanding suitable as color-forming agents for pressure-sensitive, heat-sensitive and electrosensitive recording materials with an acid developer. Deep copies which are fast to light are obtained.

70. 发明授权

US4870050A Novel compounds, processes and marking systems 失效
标题翻译：新型化合物，工艺和标记系统
公开(公告)号：US4870050A
公开(公告)日：1989-09-26
申请号：US167223
申请日：1988-03-11
申请人： William M. Hung
发明人： William M. Hung
IPC分类号： B41M5/136 , B41M5/323 , C07C211/49 , C07D209/14 , C07D295/135
CPC分类号： C07D295/135 , B41M5/136 , B41M5/323 , C07C211/49 , C07D209/14 , Y10S428/913 , Y10S428/914
摘要： Bis{[1-(2-A-2-B)ethenyl]}[2-R.sup.2 -4-X-phenyl-or 1-(2-R.sup.2 -4-X-phenyl) ethenyl]methanes useful as color formers, particularly in transfer imaging, pressure sensitive and thermal-responsive carbonless duplicating systems, are prepared by the interaction of two molecular proportions of the corresponding 1-A-1-B-ethene with the appropriate 2-R.sup.2 -4-X-phenyl-(CH.dbd.CH).sub.n --CHO presence of an acidic catalyst.
摘要翻译：可用作成色剂的双{[1-（2-A-2-B）乙烯基]} [2-R2-4-X-苯基或1-（2-R2-4-X-苯基）乙烯基] 特别是在转印成像，压力敏感和热响应无碳复制系统中，通过相应的1-A-1-B-乙烯的两个分子比例与适当的2-R2-4-X-苯基 - （ CH = CH）n-CHO存在酸性催化剂。

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