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    • 65. 发明授权
    • Composition for dip forming and molding obtained by dip forming
    • 通过浸渍成型获得的浸渍成型和成型用组合物
    • US07662890B2
    • 2010-02-16
    • US10589366
    • 2005-03-29
    • Misao AidaOsamu IshizuHisanori Ota
    • Misao AidaOsamu IshizuHisanori Ota
    • C08F8/00C08F236/14A41D19/00
    • B29C41/003B29C41/14B29L2031/4864C08J5/02C08J2309/08C08J2313/02C08K3/011C08K3/22C08K5/0025C08L13/02
    • A dip-forming composition of the present invention comprises a dip-forming latex containing a copolymer obtained by copolymerizing 100 parts by weight of a monomer mixture containing 70 to 85 parts by weight of a conjugated diene monomer, 10 to 28 parts by weight of an aromatic vinyl monomer, 2 to 5 parts by weight of an ethylenically unsaturated acid monomer and 0 to 18 parts by weight of other monomer copolymerizable with these monomers, said copolymer having a toluene insoluble content of 30% by weight or more and a toluene swelling degree of 70 times or less; and a vulcanizing agent, a vulcanization accelerator and zinc oxide which are blended in said latex in amounts of 0.5 to 2 parts by weight, 0.25 to 1 part by weight and 0.5 to 1 part by weight, respectively, on the basis of 100 parts by weight of a solid content of the latex. There can be provided a dip-formed article exhibiting an excellent touch and feel, sufficient tensile strength and elongation at break and an excellent persistence of close fitting, as well as a dip-forming composition capable of providing such a dip-formed article.
    • 本发明的浸渍形成组合物包括含有共聚物的共聚物的浸渍形成胶乳,所述共聚物通过共聚100重量份的含有70至85重量份共轭二烯单体的单体混合物,10至28重量份的 芳香族乙烯基单体,2〜5重量份的烯属不饱和酸单体和0〜18重量份可与这些单体共聚的其它单体,所述共聚物的甲苯不溶成分为30重量%以上,甲苯溶胀度 为70次以下; 和硫化剂,硫化促进剂和氧化锌,其量分别为0.5〜2重量份,0.25〜1重量份和0.5〜1重量份,基于100重量份 胶乳固体含量的重量。 可以提供具有优异的触感和触感,足够的拉伸强度和断裂伸长率和极好的紧密贴合性的浸渍成型制品,以及能够提供这种浸渍成型制品的浸渍形成组合物。
    • 69. 发明申请
    • THERMOPLASTIC POLYMER POWDER
    • 热塑性聚合物粉末
    • US20090152383A1
    • 2009-06-18
    • US12370875
    • 2009-02-13
    • Toyoaki KURIHARAKenichi Hamda
    • Toyoaki KURIHARAKenichi Hamda
    • B02C23/18
    • C08F297/026B29C41/003B29C41/18C08L53/00
    • A thermoplastic polymer powder which (i) consists mainly of an acrylic block copolymer comprising one or more acrylic ester polymer blocks (A) and bonded thereto at least one polymer block selected among methacrylic ester polymer blocks (B) and acrylic ester polymer blocks (C) differing in structure from the blocks (A); (ii) has a complex dynamic viscosity η*(5) of 5.0×103 Pa·s or lower as measured under the conditions of a temperature of 250° C. and an oscillation frequency of 5 rad/sec; (iii) has a Newtonian viscosity index n represented by the equation n=log η*(5)−log η*(50) [wherein η*(5) and η*(50) indicate the complex dynamic viscosities (unit, Pa·s) as measured under the conditions of a temperature of 250° C. and oscillation frequencies of 5 and 50 rad/sec, respectively] of 0.50 or smaller; and (iv) has an average particle diameter of 1 mm or smaller. The thermoplastic polymer powder is suitable for use in molding techniques employing a powder, such as slush molding and in powder coating. A molding, skin material, and the like which are excellent in weatherability, flexibility, mechanical strength, low-temperature properties, adhesion to polar resins, rubber elasticity, safety, etc. can be smoothly produced from the powder.
    • 一种热塑性聚合物粉末,其主要由包含一种或多种丙烯酸酯聚合物嵌段(A)的丙烯酸嵌段共聚物组成并与至少一种选自甲基丙烯酸酯聚合物嵌段(B)和丙烯酸酯聚合物嵌段(C) )结构与块(A)不同; (ii)在250℃的温度和5rad / sec的振荡频率的条件下测定的复数动态粘度η(5)为5.0×10 3 Pa·s以下; (iii)具有由等式n = log eta *(5)-log eta *(50)表示的牛顿粘度指数n [其中eta *(5)和eta *(50)表示复数动态粘度(单位Pa .s)在温度250℃,振荡频率分别为5和50弧度/秒的条件下测定]为0.50以下; 和(iv)的平均粒径为1mm以下。 热塑性聚合物粉末适用于使用粉末的成型技术,例如搪塑和粉末涂料。 可以从粉末中平滑地制造耐候性,柔软性,机械强度,低温性,与极性树脂的粘合性,橡胶弹性,安全性等优异的成型品,表皮材料等。
    • 70. 发明申请
    • DECORATIVE GOLF CLUB GRIP
    • 装饰高尔夫俱乐部
    • US20090025852A1
    • 2009-01-29
    • US12055289
    • 2008-03-25
    • BEN HUANG
    • BEN HUANG
    • B32B37/12B05D3/00
    • B05C9/06A63B53/14A63B60/06A63B60/08A63B60/10A63B60/14B25G1/10B29C39/18B29C39/20B29C41/003B29C41/08B29C41/32B29K2075/00B29L2031/463Y10T156/10Y10T428/24802
    • A grip for the handle of a golf club having at least a polymerized region with two or more polymers. The first and second polymers cooperate to form a pattern on the top surface of the region. The region may be combined with a substrate to form a sheet. The sheet may be formed into a grip interface having any of a number of shapes including a panel shape. In the case of a panel shaped grip interface, the panel is then attached to an underlisting sleeve to form the grip. The grip reduces impact shock and provides a feeling of tackiness in the manner of a spirally wrapped polyurethane-felt grip while allowing the use of multiple colors being polymerized together. The grip may be easily installed onto a golf club shaft and further accommodates the use of polymers including various different characteristics including level of tackiness or durometer.
    • 用于具有至少具有两种或更多种聚合物的聚合区域的高尔夫球杆的手柄的握柄。 第一和第二聚合物配合以在该区域的顶表面上形成图案。 该区域可以与基底组合以形成片材。 片材可以形成为具有包括面板形状的多种形状中的任一种的把手接口。 在面板形握柄接口的情况下,将面板附接到下面的套筒以形成把手。 握把减少了冲击冲击,并且以螺旋缠绕的聚氨酯 - 手感抓地力的方式提供了粘性的感觉,同时允许使用多种颜色聚合在一起。 把手可以容易地安装在高尔夫球杆杆上,并进一步适应包括各种不同特征(包括粘性或硬度等级)的聚合物的使用。