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    • 70. 发明授权
    • Process for preparing an aqueous emulsion of a polymer by emulsion
polymerization in the presence of an emulsifier
    • 在乳化剂存在下通过乳液聚合制备聚合物水乳液的方法
    • US4469839A
    • 1984-09-04
    • US458193
    • 1983-01-17
    • Motokazu MaruhashiSumio Nakagawa
    • Motokazu MaruhashiSumio Nakagawa
    • C08F2/26
    • C08F2/26
    • An emulsifier useful for preparing an aqueous emulsion having a high viscosity which comprises a copolymer of (1) at least one monomer selected from a vinyl ester, vinyl alcohol, an alkyl acrylate and an alkyl methacrylate and (2) at least one monomer selected from an acrylic acid derivative of the general formula:CH.sub.2 .dbd.CR.sup.1 --CO--A--R.sup.2 --SO.sub.3 Mand a maleic acid derivative of the general formula: ##STR1## wherein R.sup.1 is hydrogen or methyl group, R.sup.2 is an alkylene group, R.sup.3 is hydrogen, an alkyl group or an alkali metal, M is hydrogen or an alkali metal, and A is --O-- or --NR-- in which R is hydrogen, an alkyl group or --R.sup.2 SO.sub.3 M. Emulsions prepared by employing the above copolymer as emulsifier have very high viscosities and moreover excellent storage, freeze-thaw and dilution stabilities. The use of the above copolymer in combination with a surface active agent provides emulsions containing scarcely aggregates and coarse particles and having an improved flowability.
    • 一种用于制备具有高粘度的水性乳液的乳化剂,其包含(1)至少一种选自乙烯基酯,乙烯醇,丙烯酸烷基酯和甲基丙烯酸烷基酯的单体的共聚物和(2)至少一种选自以下的单体: 通式为:CH2 = CR1-CO-A-R2-SO3M的丙烯酸衍生物和下列通式的马来酸衍生物:其中R 1为氢或甲基,R 2为亚烷基,R 3为氢 ,烷基或碱金属,M为氢或碱金属,A为-O-或-NR-,其中R为氢,烷基或-R2SO3M。 通过使用上述共聚物作为乳化剂制备的乳液具有非常高的粘度和优异的储存,冻融和稀释稳定性。 使用上述共聚物与表面活性剂组合提供了几乎不具有聚集体和粗颗粒并且具有改善的流动性的乳液。