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    • 62. 发明授权
    • Herbicidal active substance combinations
    • 除草活性物质组合
    • US5447903A
    • 1995-09-05
    • US842356
    • 1992-03-25
    • Oswald OrtLothar WillmsHans-Joachim ZeissKlaus BauerHermann Bieringer
    • Oswald OrtLothar WillmsHans-Joachim ZeissKlaus BauerHermann Bieringer
    • A01N35/06A01N41/10A01N43/38A01N31/08A01N43/76
    • A01N35/06A01N41/10
    • Combinations of active substances of the formula (I) ##STR1## where R.sup.1 is halogen, lower alkoxy, alkyl or haloalkyl, NO.sub.2, CN, (S(O).sub.n R.sup.10 [sic],R.sup.2 and R.sup.3 are H, halogen, lower alkyl, alkoxy, haloalkoxy or haloalkyl, CN, NO.sub.2, S(O).sub.m R.sup.11, NR.sup.11 R.sup.13, NR.sup.14 --COR.sup.15, CO--R.sup.16,R.sup.4 and R.sup.6 -R.sup.9 are H or lower alkyl,R.sup.5 is H, lower alkyl or alkyl--O--CO--,R.sup.10 is lower alkyl, haloalkyl or alkoxy,R.sup.11 is lower alkyl or haloalkyl or phenyl, benzyl or NR.sup.17 R.sup.18,R.sup.12 and R.sup.13 are H or lower alkyl,R.sup.14 is H or lower alkyl,R.sup.15 is lower alkyl,R.sup.16 is H, lower alkyl, haloalkyl or alkoxy,R.sup.17 and R.sup.18 are H or lower alkyl,n and m in each case are 0 to 2, with herbicides from the group comprising fenoxaprop-ethyl, fenoxaprop-P-ethyl, quinchlorac, molinate, thiobencarb, butachlor, pretilachlor, mefenacet, esprocarb, dimepiperate, HW-52; cinmethylin, anilophos, benfuresate, triazofenamide,. benzofenap, pyrazoxyfen and TFH-450, have advantages on application, for example a synergistic increase in action, in particular in the case of important weeds in cereals, maize and rice.
    • PCT No.PCT / EP90 / 01720 Sec。 371日期:1992年3月25日 102(e)1992年3月25日PCT PCT 1990年10月12日PCT公布。 公开号WO91 / 05469 (I)的活性物质的组合其中R 1是卤素,低级烷氧基,烷基或卤代烷基,NO 2,CN,(S(O)n R 10, R3是H,卤素,低级烷基,烷氧基,卤代烷氧基或卤代烷基,CN,NO2,S(O)mR11,NR11R13,NR14-COR15,-CO-R16,R4和R6-R9是H或低级烷基,R5是H, 低级烷基或烷基-O-CO-,R10为低级烷基,卤代烷基或烷氧基,R11为低级烷基或卤代烷基或苯基,苄基或NR17R18,R12和R13为H或低级烷基,R14为H或低级烷基,R15为 低级烷基,R 16为H,低级烷基,卤代烷基或烷氧基,R 17和R 18为H或低级烷基,n和m各自为0至2,其中除草诺酮,乙酸, 喹喔啉,茉莉酸,硫代苯甲酸,丁草胺,预草甘膦,mefenacet,esprocarb,dimepiperate,HW-52; cinmethylin,anilophos,benfuresate,triazofenamide,苯并芬,吡唑芬芬和TFH-450在应用上具有优势, 特别是在谷物,玉米和稻米中重要杂草的情况下。
    • 66. 发明授权
    • Heterocyclically substituted phenoxysulfonylureas, and the use thereof
as herbicides or plant growth regulators
    • US5102443A
    • 1992-04-07
    • US351958
    • 1989-05-15
    • Heinz KehneLothar WillmsKlaus BauerHermann BieringerHelmut Burstell
    • Heinz KehneLothar WillmsKlaus BauerHermann BieringerHelmut Burstell
    • A01N47/34A01N47/36A01P13/00C07D239/42C07D239/47C07D239/48C07D239/52C07D239/56C07D249/14C07D251/16C07D251/18C07D251/22C07D251/26C07D251/46C07D251/50C07D251/52C07D251/70C07D471/04C07D473/32C07D475/00C07D487/04C07D491/044C07D491/048C07D491/052C07D521/00
    • C07D521/00A01N47/36
    • Heterocyclically substituted phenoxysulfonylureas, processes for the preparation thereof, and the use thereof as herbicides or plant growth regulators. Compounds of the formula I or the salts thereof ##STR1## where R.sup.1 is (C.sub.1 -C.sub.8)alkyl, (C.sub.2 -C.sub.8)alkenyl or (C.sub.2 -C.sub.8)alkynyl, these radicals being substituted by halogen, saturated or unsaturated (C.sub.1 -C.sub.6)alkoxy, (C.sub.1 -C.sub.6)alkylthio, -sulfinyl or -sulfonyl, (C.sub.1 -C.sub.6)alkoxycarbonyl, NO.sub.2, CN or phenyl; furthermore is (C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl or (C.sub.3 -C.sub.8)cycloalkyl, which can be substituted by halogen or by alkoxy or alkylthio; (C.sub.5 -C.sub.8)cycloalkenyl, cyclopropylmethyl, epoxypropyl; furfuryl, tetrahydrofurfuryl or phenoxy (C.sub.1 -C.sub.4)alkyl, it being possible for the last three substituents mentioned to be substituted by halogen, alkyl or alkoxy; or phenyl which can be substituted by halogen, alkyl, alkoxy, NO.sub.2, CF.sub.3, CN or OCHF.sub.2 ; or, in the event that R.sup.2 is alkenyl, alkynyl, phenyl or phenoxy, each of which can be substituted as indicated below, alkylsulfonyl or alkylsulfinyl and n.noteq., R.sup.1 is also (C.sub.1 -C.sub.8)alkyl,R.sup.2 radicals independently of one another are (C.sub.1 -C.sub.8)-alkyl, (C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, phenyl, phenoxy, (C.sub.1 -C.sub.4)alkoxy, (C.sub.1 -C.sub.4)alkylthio, (C.sub.1 -C.sub.4)-alkoxycarbonyl, (C.sub.2 -C.sub.4)alkenyloxycarbonyl, (C.sub.2 - C.sub.4)alkynyloxycarbonyl, it being possible for all the abovementioned radicals to be substituted by halogen, (C.sub.1 -C.sub.4)alkoxy or (C.sub.1 -C.sub.4)alkylthio; furthermore halogen, NO.sub.2, (C.sub.1 -C.sub.4)alkylsulfonyl or (C.sub.1 -C.sub.4)alkylsulfinyl;n is 0, 1, 2 or 3; y is O or S;R.sup.3 is hydrogen, (C.sub.1 -C.sub.8)alkyl, (C.sub.2 -C.sub.8)alkenyl, (C.sub.3 -C.sub.8)-alkynyl or (C.sub.1 -C.sub.4)alkoxy;R.sup.4 is a heterocyclic radical of the formulae ##STR2## E is CH or N, G is O or CH.sub.2,R.sup.5 and R.sup.6 are hydrogen, halogen, alkyl, alkoxy or alkylthio, it being possible for the abovementioned alkyl-containing radicals to be substituted by halogen, alkoxy or alkylthio, furthermore a radical of the formula --NR.sup.12 R.sup.13, --OCHR.sup.7 --CO.sub.2 R.sup.12, cycloalkyl, alkenyl, alkynyl, alkenyloxy or alkynyloxy,R.sup.7 is hydrogen or alkyl; R.sup.8 is alkyl, --CHF.sub.2 or --CH.sub.2 CF;R.sup.9 and R.sup.10 are hydrogen, alkyl, alkoxy or halogen, R.sup.11 is hydrogen, alkyl, --CHF.sub.2 or CH.sub.2 CF.sub.3, and R.sup.12 and R.sup.13 are hydrogen, alkyl, alkenyl or alkynyl, have outstanding herbicidal and plant growth-regulating properties.
    • 70. 发明授权
    • Nitrogen-substituted phenylsulfonylureas; processes for their
preparation, and their use as herbicides and plant growth regulators
    • 氮取代苯磺酰脲; 其制备方法及其作为除草剂和植物生长调节剂的用途
    • US5696053A
    • 1997-12-09
    • US453967
    • 1995-05-30
    • Gerhard SchnabelLothar WillmsKlaus BauerHermann Bieringer
    • Gerhard SchnabelLothar WillmsKlaus BauerHermann Bieringer
    • C07D251/16A01N47/36C07D239/42C07D251/46C07D251/50C07D405/12C07D521/00C07D239/69A01N43/54
    • C07D521/00A01N47/36
    • Salts of the formula (I) ##STR1## in which n is 0, 1, 2 or 3, R is halogen, alkyl or alkoxy, mainly in each case independently of other substituents R in the event that n is greater than 1, R.sup.1 is a substituted or unsubstituted hydrocarbon radical or a substituted or unsubstituted heterocyclic radical, R.sup.2 is an acyl radical, R.sup.3 is hydrogen or C.sub.1 -C.sub.5 -alkyl, M.sym. is a metal or ammonium ion, X and Y independently of one another are halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio, each of the three last-mentioned radicals being unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, C.sub.1 -C.sub.4 -alkoxy and C.sub.1 -C.sub.4 -alkylthio, or are C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.2 -C.sub.6 -alkynyloxy, mono- or di(C.sub.1 -C.sub.4 -alkyl)amino, and Z is CH or N, are suitable as herbicides and plant growth regulators, The compounds (I) can be prepared by processes of claims 5 to 7, for example by hydrogenating 2-alkoxycarbonyl-5-nitrophenylsulfonylureas in the presence of anhydrides.
    • 式(I)的盐,其中n是0,1,2或3,R是卤素,烷基或烷氧基,在n大于1的情况下,主要在每种情况下独立于其它取代基R,R 1 是取代或未取代的烃基或取代或未取代的杂环基,R 2是酰基,R 3是氢或C 1 -C 5 - 烷基,M(+)​​是金属或铵离子,X和Y彼此独立地是 卤素,C 1 -C 6 - 烷基,C 1 -C 6 - 烷氧基或C 1 -C 6 - 烷硫基,三个最后提及的基团中的每一个是未取代的或被一个或多个选自卤素,C 1 -C 4 - 烷氧基 或C 1 -C 4 - 烷硫基,或者是C 3 -C 6 - 环烷基,C 2 -C 6 - 烯基,C 2 -C 6炔基,C 3 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,一或二(C 1 -C 4 - 烷基) 氨基和Z是CH或N,适合作为除草剂和植物生长调节剂。化合物(I)可以通过权利要求5至7的方法制备,例如通过氢化2-烷氧基羰基-5-硝基苯基磺酰脲 在酸酐的存在下。