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61. 发明授权

US5049571A 1-nitro-2,2-diaminoethylene derivatives 失效
标题翻译： 1-硝基-2,2-二氨基乙烯衍生物
公开(公告)号：US5049571A
公开(公告)日：1991-09-17
申请号：US469658
申请日：1990-01-24
申请人： Laurenz Gsell
发明人： Laurenz Gsell
IPC分类号： C07D213/42 , A01N43/40 , C07D213/38 , C07D213/50 , C07D213/61 , C07D213/63 , C07D213/70 , C07D213/71 , C07D213/72 , C07D213/73 , C07D213/74 , C07D213/75 , C07D213/79 , C07D213/84
CPC分类号： C07D213/61 , A01N43/40 , C07D213/38
摘要： There are disclosed novel 1-nitro-2,2-diaminoethylene derivatives of formula I ##STR1## wherein X is chlorine, fluorine, unsubstituted or halogen-substituted C.sub.1 -C.sub.5 alkyl; unsubstituted or halogen-substituted C.sub.1 -C.sub.5 alkoxy, unsubstituted or halogen-substituted C.sub.1 -C.sub.5 alkylthio, unsubstituted or halogen-substituted alkylsulfinyl, unsubstituted or halogen-substituted alkylsulfonyl; or also nitro, cyano, thiocyanato, C.sub.3 -C.sub.5 haloalkenyl, C.sub.3 -C.sub.5 haloalkynyl, hydroxy, C.sub.1 -C.sub.5 alkoxycarbonyl, amino, C.sub.1 -C.sub.4 dialkylamino, C.sub.1 -C.sub.5 alkylcarbonyl, C.sub.1 -C.sub.5 alkylcarbamoyl or C.sub.1 -C.sub.5 alkylcarbonyloxy,n is an integer from 0 to 4,R.sub.1 is hydrogen, C.sub.1 -C.sub.5 alkyl or C.sub.3 -C.sub.7 cycloalkyl,R.sub.2 is hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.3 -C.sub.7 cycloalkyl,R.sub.3 is hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.3 -C.sub.7 cycloalkyl, benzyl or pyridinylmethyl, or R.sub.2 and R.sub.3, together with the linking nitrogen atom, are the pyrrolidinyl or piperazinyl radical, with the proviso that not more than one of the substituents R.sub.1, R.sub.2 and R.sub.3 is hydrogen, and the cis and trans-isomers and salts thereof. The invention also relates to the preparation of these novel compounds and to compositions containing them and to the use thereof in pest control, especially for controlling insects.

62. 发明授权

US4918088A Pest control 失效
标题翻译：除害虫
公开(公告)号：US4918088A
公开(公告)日：1990-04-17
申请号：US218190
申请日：1988-07-13
申请人： Laurenz Gsell
发明人： Laurenz Gsell
IPC分类号： A01N47/44 , C07D213/36 , C07D213/38 , C07D213/40
CPC分类号： C07D213/40 , A01N47/44 , C07D213/38
摘要： The invention relates to the use of compounds of formula I ##STR1## wherein A is a radical ##STR2## and tautomers thereof, for controlling noxious insects and pests of the order Acarina, and to compositions which contain these compounds. The compounds of formula I are particularly suitable for controlling noxious feeding and sucking insects.
摘要翻译：本发明涉及式I化合物（I）的用途，其中A是一种自由基及其互变异构体，用于控制有害昆虫和蜱螨目的害虫，以及含有这些化合物的组合物。式I化合物特别适合于控制有害的饲喂和吸吮昆虫。

63. 发明授权

US4918086A 1-nitro-2,2-diaminoethylene derivatives 失效
标题翻译： 1-硝基-2,2-二氨基乙烯衍生物
公开(公告)号：US4918086A
公开(公告)日：1990-04-17
申请号：US224623
申请日：1988-07-27
申请人： Laurenz Gsell
发明人： Laurenz Gsell
IPC分类号： C07D213/42 , A01N43/40 , C07D213/38 , C07D213/50 , C07D213/61 , C07D213/63 , C07D213/70 , C07D213/71 , C07D213/72 , C07D213/73 , C07D213/74 , C07D213/75 , C07D213/79 , C07D213/84
CPC分类号： C07D213/61 , A01N43/40 , C07D213/38
摘要： There are disclosed novel 1-nitro-2,2-diaminoethylene derivatives of formula I ##STR1## wherein X is chlorine, fluorine, unsubstituted or halogen-substituted C.sub.1 -C.sub.5 alkyl; unsubstituted or halogen-substituted C.sub.1 -C.sub.5 alkoxy, unsubstituted or halogen-substituted C.sub.1 -C.sub.5 akylthio, unsubstituted or halogen-substituted alkylsulfinyl, unsubstituted or halogen-substituted alkylsulfonyl; or also nitro, cyano, thiocyanato, C.sub.3 -C.sub.5 haloalkenyl, C.sub.3 -C.sub.5 haloalkynyl, hydroxy, C.sub.1 -C.sub.5 alkoxycarbonyl, amino, C.sub.1 -C.sub.4 dialkylamino, C.sub.1 -C.sub.5 alkylcarbonyl, C.sub.1 -C.sub.5 alkylcarbamoyl or C.sub.1 -C.sub.5 alkylcarbonyloxy,n is an integer from 0 to 4,R.sub.1 is hydrogen, C.sub.1 -C.sub.5 alkyl or C.sub.3 -C.sub.7 cycloalkyl,R.sub.2 is hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.3 -C.sub.7 cycloalkyl,R.sub.3 is hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.3 -C.sub.7 cycloalkyl, benzyl or pyridinylmethyl, or R.sub.2 and R.sub.3, together with the linking nitrogen atom, are the pyrrolidinyl or piperazinyl radical,with the proviso that not more than one of the substituents R.sub.1, R.sub.2 and R.sub.3 is hydrogen, and the cis and trans-isomers and salts thereof. The invention also relates to the preparation of these novel compounds and to compositions containing them and to the use thereof in pest control, especially for controlling insects.
摘要翻译：公开了式I的新的1-硝基-2,2-二氨基乙烯衍生物其中X是氯，氟，未取代的或卤素取代的C 1 -C 5烷基; 未取代或卤素取代的C1-C5烷氧基，未取代或卤素取代的C1-C5烷硫基，未取代或卤素取代的烷基亚磺酰基，未取代或卤素取代的烷基磺酰基; 或者也可以是硝基，氰基，氰硫基，C3-C5卤代烯基，C3-C5卤代炔基，羟基，C1-C5烷氧基羰基，氨基，C1-C4二烷基氨基，C1-C5烷基羰基，C1-C5烷基氨基甲酰基或C1-C5烷基羰氧基，n是0-4的整数，R1 是氢，C 1 -C 5烷基或C 3 -C 7环烷基，R 2是氢，C 1 -C 5烷基，C 3 -C 7环烷基，R 3是氢，C 1 -C 5烷基，C 3 -C 7环烷基，苄基或吡啶基甲基，或者R 2和R 3与连接氮原子是吡咯烷基或哌嗪基，条件是不超过一个取代基R 1，R 2和R 3是氢，以及其顺式和反式异构体及其盐。本发明还涉及这些新化合物的制备和含有它们的组合物及其在病虫害防治中的用途，特别是用于防治昆虫。

64. 发明授权

US4490375A 4-N,N-Dimethylcarbamoyloxy-6-aminopyrimidines and salts thereof, and their use for combating pests 失效
标题翻译： 4-N，N-二甲基氨基甲酰氧基-6-氨基嘧啶及其盐及其用于防治害虫
公开(公告)号：US4490375A
公开(公告)日：1984-12-25
申请号：US442683
申请日：1982-11-18
申请人： Karl Hoegerle , Laurenz Gsell , Rudolf Wehrli
发明人： Karl Hoegerle , Laurenz Gsell , Rudolf Wehrli
IPC分类号： A01N47/18 , C07D239/46 , C07D239/47 , A01N43/54
CPC分类号： C07D239/47 , A01N47/18
摘要： 4-N,N-Dimethylcarbamoyloxy-6-aminopyrimidines, and salts thereof, of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.5 -alkynyl, or together they are a C.sub.2 -C.sub.5 -alkylene group, R.sub.3 is halogen or C.sub.1 -C.sub.5 -alkyl, and R.sub.4 is C.sub.1 -C.sub.5 -alkyl, or R.sub.3 is hydrogen and R.sub.4 is C.sub.2 -C.sub.5 -alkyl.There are described a process for producing these pyrimidines, their use for combating pests, and also the intermediates of the formula ##STR2## wherein R.sub.1 and R.sub.2 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.5 -alkynyl, or together they are a C.sub.2 -C.sub.5 -alkylene group, R.sub.3 is halogen or C.sub.1 -C.sub.5 -alkyl, and R.sub.4 is C.sub.1 -C.sub.5 -alkyl, or R.sub.3 is hydrogen and R.sub.4 is C.sub.2 -C.sub.5 -alkyl.
摘要翻译： 4-N，N-二甲基氨基甲酰氧基-6-氨基嘧啶及其盐，其中R 1和R 2彼此独立地为氢，C 1 -C 5 - 烷基，C 1 -C 5 - 卤代烷基，C 3 -C 6 - 环烷基，C 2 -C 5 - 烯基或C 2 -C 5 - 炔基，或者它们一起是C 2 -C 5亚烷基，R 3是卤素或C 1 -C 5 - 烷基，R 4是C 1 -C 5 - 烷基，或者R 3是氢， R4是C2-C5-烷基。描述了制备这些嘧啶的方法，它们用于防治害虫的方法，以及式IMA的中间体，其中R 1和R 2彼此独立地为氢，C 1 -C 5 - 烷基，C 1 -C 5 - 卤代烷基， C 3 -C 6 - 环烷基，C 2 -C 5 - 烯基或C 2 -C 5 - 炔基，或者它们一起是C 2 -C 5 - 亚烷基，R 3是卤素或C 1 -C 5 - 烷基，R 4是C 1 -C 5烷基，或 R3是氢，R4是C2-C5-烷基。

65. 发明授权

US4348414A Cyclobutanone oxime carbamates, and use thereof in pest control 失效
标题翻译：环丁酮肟氨基甲酸酯，以及其在害虫防治中的用途
公开(公告)号：US4348414A
公开(公告)日：1982-09-07
申请号：US252527
申请日：1981-04-09
申请人： Laurenz Gsell , Jean-Claude Gehret
发明人： Laurenz Gsell , Jean-Claude Gehret
IPC分类号： A01N47/24 , A01N33/24
CPC分类号： A01N47/24
摘要： Cyclobutanone oxime carbamates of the formula ##STR1## wherein n is 1 to 5 and X.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio.A process for obtaining the compounds of the formula I and their use in pest control as well as the cyclobutanone oximes used as intermediates are described.
摘要翻译：式（I）的环丁酮肟氨基甲酸酯，其中n为1至5，X 1为氢，卤素，C 1 -C 4烷氧基或C 1 -C 4烷硫基。描述了获得式I化合物及其在病虫害防治中的用途以及用作中间体的环丁酮肟的方法。

66. 发明授权

US4231962A 3-Phenoxybenzylideneamines and 3-benzylbenzylideneamines 失效
标题翻译： 3-苯氧基亚苄基胺和3-苄基亚苄基胺
公开(公告)号：US4231962A
公开(公告)日：1980-11-04
申请号：US042756
申请日：1979-05-29
申请人： Dieter Reinehr , Laurenz Gsell
发明人： Dieter Reinehr , Laurenz Gsell
IPC分类号： C07C45/51 , C07C47/546 , C07C47/55 , C07C47/575 , C07C119/10
CPC分类号： C07C45/516 , C07C47/546 , C07C47/55 , C07C47/575
摘要： 3-Phenoxybenzylideneamines and 3-benzylbenzylideneamines of the formula ##STR1## in which R.sub.1 is hydrogen or alkyl, R.sub.2 is alkyl, with alkyl groups denoted by R.sub.1 and R.sub.2 together not containing more than 12 C atoms, or R.sub.1 and R.sub.2 together being alkylene having 4-11 C atoms, R.sub.3 is hydrogen, halogen, methyl or methoxy, and X.sub.1 is oxygen or --CH.sub.2 --; a process for obtaining them, and also their use for producing the corresponding aldehydes.
摘要翻译： 3-苯氧基亚苄基胺和式“IMAGE”的3-苄基亚苄基胺，其中R 1是氢或烷基，R 2是烷基，其中由R 1和R 2表示的烷基不包含大于12个C原子，或者R 1和R 2一起是亚烷基， 4-11个C原子，R3是氢，卤素，甲基或甲氧基，X1是氧或-CH2-; 获得它们的方法，以及它们用于生产相应醛的用途。

67. 发明授权

US4230722A Dihalovinylcyclopropanethiolic acid esters and their use in pest control 失效
标题翻译：二卤乙烯基环丙硫醇酸酯及其在病虫害防治中的应用
公开(公告)号：US4230722A
公开(公告)日：1980-10-28
申请号：US49367
申请日：1979-06-18
申请人： Roger Malherbe , Daniel Bellus , Laurenz Gsell
发明人： Roger Malherbe , Daniel Bellus , Laurenz Gsell
IPC分类号： A01N37/14 , A01N53/00 , A01N53/08 , C07C327/10 , C07C327/20 , C07C327/22 , C07C153/023
CPC分类号： A01N53/00 , C07C327/00
摘要： Dihalovinylcyclopropanethiolic acid esters of the formula ##STR1## wherein X.sub.1 represents fluorine, chlorine or bromine, R.sub.1 represents hydrogen, methyl, ethynyl or cyano, and Y represents hydrogen, fluorine, chlorine or bromine, processes for their manufacture, and a method of controlling pests which comprises the use of these compounds.
摘要翻译：式（I）的二卤乙烯基环丙硫醇酸酯，其中X1表示氟，氯或溴，R1表示氢，甲基，乙炔基或氰基，Y表示氢，氟，氯或溴，其制备方法和方法控制害虫，包括使用这些化合物。

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