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61. 发明申请

US20060252857A1 Aminoaryl-1-3-5-triazines and their use as uv absorbers 审中-公开
标题翻译：氨基芳基-1,3,5-三嗪及其作为紫外线吸收剂的用途
公开(公告)号：US20060252857A1
公开(公告)日：2006-11-09
申请号：US10558317
申请日：2004-05-17
申请人： Thomas Schäfer , Frédérique Wendeborn , Michèle Gerster , Pascal Hayoz , Beat Schmidhalter , Jean-Luc Budry
发明人： Thomas Schäfer , Frédérique Wendeborn , Michèle Gerster , Pascal Hayoz , Beat Schmidhalter , Jean-Luc Budry
IPC分类号： C08K5/34 , C07D265/00
CPC分类号： C08K5/3492 , C07D251/22 , C07D251/24
摘要： A novel process for preparing a aminophenyl-triazines of the formula (I′), comprises reacting a corresponding halogenophenyltriazine of the formula (I″), with an amine of the formula (IX), H—NR′2R′3, wherein X is chloro or preferably fluoro and the symbols A, A′, R′2, R′3 and R44 are organic residues as defined in claim 1. Products of this process and derivatives thereof are useful as stabilizers and UV absorbers for protecting an organic material against damage by light, oxygen and/or heat, or as recording dye in an optical recording medium, especially for writing or reading digital information in a recording layer using laser radiation of wavelength less than 450 nm.
摘要翻译：制备式（I'）的氨基苯基 - 三嗪的新方法包括使相应的式（I“）的卤代苯基三嗪与式（IX）的胺，H-NR' 其中X是氯或优选氟，符号A，A'，R'2，R'3，和R 44是如权利要求1所定义的有机残基。该方法的产物及其衍生物可用作用于保护有机材料免受光，氧和/或热的损害的稳定剂和UV吸收剂，或作为光记录介质中的记录染料，特别是用于在记录中写入或读取数字信息层使用波长小于450nm的激光辐射。

62. 发明授权

US06913712B2 Stabilizer mixture 有权
公开(公告)号：US06913712B2
公开(公告)日：2005-07-05
申请号：US10168219
申请日：2000-12-14
申请人： Pascal Hayoz
发明人： Pascal Hayoz
IPC分类号： C07D251/24 , C08K5/3492 , C08K15/32 , C08K5/34 , C08K15/16 , C08K15/26
CPC分类号： C08K5/3492 , C07D251/24
摘要： Mixtures of compounds comprising a compound G2 and at least one further compound from the group G0, G1, G3, G4, G5, G6, the compounds G0-G6 corresponding to formula (I) in which, in the compound G0, the radicals R1, R2, R3, R4, R5 and R6 are each hydrogen; G1, the radical R1 is Q and R2, R3, R4, R5 and R6 are each hydrogen; G2, the radicals R1 and R2 independently of one another are each Q and R3, R4, R5 and R6 are each hydrogen; G3 the radicals R1, R2 and R3 independently of one another are each Q and R4, R5 and R6 are each hydrogen; G4, the radicals R1, R2, R3 and R4 independently of one another are each Q and R5 and R6 are each hydrogen; G5, the radicals R1, R2, R3, R4 and R5 independently of one another are each Q and R6 is hydrogen; G6, the radicals R1, R2, R3, R4, R5 and R6 independently of one another are each Q; and Q and the other symbols are as defined in claim 1, are effective as stabilizers for organic material with respect to damaging exposure to light, oxygen and/or heat.

63. 发明授权

US06653484B2 Polyoxyalkylene substituted and bridged benzotriazole derivatives 失效
公开(公告)号：US06653484B2
公开(公告)日：2003-11-25
申请号：US10006634
申请日：2001-11-08
申请人： Vien Van Toan , Andreas Valet , Pascal Hayoz
发明人： Vien Van Toan , Andreas Valet , Pascal Hayoz
IPC分类号： C07D24920
CPC分类号： A61K8/4966 , A61Q17/04 , C07C49/84 , C07C59/315 , C07D249/20 , C07D251/24 , C08K5/132 , C08K5/34 , C08K5/3475 , C08K5/3492 , Y10S430/132
摘要： Triazine, benzotriazole and benzophenone derivatives which are substituted or bridged with polyoxyalkylene groups, according to claim 1, and their use as UV absorbers, especially in photographic materials, in inks, including inkjet inks and printing inks, in transfer prints, in paints and varnishes, organic polymeric materials, plastics, rubber, glass, packaging materials, in sunscreens of cosmetic preparations and in skin protection compositions.

64. 发明授权

US06509400B2 Trisresorcinyltriazines 有权
标题翻译：三氯甲基三嗪
公开(公告)号：US06509400B2
公开(公告)日：2003-01-21
申请号：US09973397
申请日：2001-10-09
申请人： Thomas Schäfer , Thomas Bolle , Pascal Hayoz
发明人： Thomas Schäfer , Thomas Bolle , Pascal Hayoz
IPC分类号： C08K53492
CPC分类号： C07D251/24
摘要： Compounds of the formula in which Z, Z′ and Z″ independently of one another are a group of the formula II and R7 is a radical of the formula III, IV or V in which n is 1 or 2; R4, R5 and R6 independently of one another are C1-C18alkyl; C5-C12cycloalkyl; C2-C18alkenyl; phenyl; C7-C11phenylalkyl; C7-C11alkylphenyl; C1-C18alkyl substituted by phenyl, OH, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C18alkenyloxy, COOH, COOR11, O—COR12, CONH2, CONHR13, CONR13R14, CN, NH2, NHR13, NR13R14, NHCOR12, C6-C15bicycloalkyl, C6-C16bicycloalkyl-alkoxy, C6-C16bicycloalkenyl-alkoxy or C6-C15tricycloalkoxy; C5-C12cycloalkyl substituted by OH, C1-C4alkyl, C2-C6alkenyl or O—COR12; or COR15; CO—X—R11; or SO2—R16; or C3-C50alkyl interrupted by O and/or substituted by OH, phenoxy or C7-C18alkylphenoxy; or R5 and R6 together form a ring structure; X and Y independently of one another are O, NH, NR13 or S; and the other symbols are as defined in claim 1 are effective as stabilizers for organic material against the damaging effect of light, oxygen and/or heat.
摘要翻译： Z，Z'和Z'彼此独立的烷氧基化合物是式II和R7的基团，其是n为1或2的式III，IV或Vin的基团; R 4，R 5和R 6彼此独立地为C 1 -C 18烷基; C5-C12环烷基; C 2 -C 18烯基; 苯基; C7-C11苯基烷基; C7-C11烷基苯基; 被苯基，OH，C1-C18烷氧基，C5-C12环烷氧基，C3-C18链烯氧基，COOH，COOR11，O-COR12，CONH2，CONHR13，CONR13R14，CN，NH2，NHR13，NR13R14，NHCOR12，C6-C15双环烷基，C6 C16双环烷基 - 烷氧基，C6-C16双环烯基 - 烷氧基或C6-C15三环烷氧基; 被OH，C 1 -C 4烷基，C 2 -C 6烯基或O-COR 12取代的C 5 -C 12环烷基; 或COR15; CO-X-R11; 或SO2-R16; 或被O和/或被OH，苯氧基或C 7 -C 18烷基苯氧基取代的C 3 -C 50烷基; 或R5和R6一起形成环结构; X和Y彼此独立地是O，NH，NR 13或S; 而其它符号如权利要求1中所定义的作为有机材料的稳定剂有效地抵抗光，氧和/或热的破坏作用。

65. 发明授权

US6013704A Hydroxyphenyltriazines 失效
标题翻译：羟基苯基三嗪
公开(公告)号：US6013704A
公开(公告)日：2000-01-11
申请号：US929147
申请日：1997-09-10
申请人： Pascal Hayoz , Andreas Valet , Vien Van Toan
发明人： Pascal Hayoz , Andreas Valet , Vien Van Toan
IPC分类号： G03C7/392 , C07D251/24 , C07D405/12 , C07D405/14 , C08K5/3435 , C08K5/3492 , C09K15/30 , C07D251/00
CPC分类号： C07D405/12 , C07D251/24 , C07D405/14 , C08K5/3435 , C08K5/3492
摘要： There are described compounds of formula A whereinr.sub.1 and r.sub.2 are each independently of the other 0 or 1;Y.sub.1 to Y.sub.9 are each independently of the others --H, --OH, C.sub.1 -C.sub.20 alkyl, C.sub.4 -C.sub.20 cycloalkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.1 -C.sub.20 alkoxy, C.sub.4 -C.sub.12 cycloalkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.7 -C.sub.20 aralkyl, halogen, --C.tbd.N, C.sub.1 -C.sub.5 haloalkyl, --SO.sub.2 R', --SO.sub.3 H, --SO.sub.3 M, wherein M is an alkali metal, --COOR', --CONHR', --CONR'R", --OCOOR', --OCOR', --OCONHR', (meth)acrylamino, (meth)-acryloxy, C.sub.6 -C.sub.12 aryl; C.sub.6 -C.sub.12 aryl substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, CN and/or by halogen; C.sub.3 -C.sub.12 heteroaryl; C.sub.3 -C.sub.12 heteroaryl substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, CN and/or by halogen; or Q of formula I, and at least one substituent Y.sub.1 to Y.sub.9 must be Q ##STR1## wherein q is 0 or 1,R is a cyclic radical andR.sub.1 and T are as defined in claim 1. The novel compounds are suitable, especially in combination with hindered amines, for the stabilisation of organic material against the damaging action of light, oxygen and heat.
摘要翻译：描述式A的化合物，其中r1和r2各自独立地为0或1; Y 1至Y 9各自独立地为-H，-OH，C 1 -C 20烷基，C 4 -C 20环烷基，C 2 -C 20 - 烯基，C 1 -C 20烷氧基，C 4 -C 12环烷氧基，C 2 -C 20链烯氧基，C 7 -C 20芳烷基，卤素，-C 3 N，C1-C5卤代烷基，-SO2R'，-SO3H，-SO3M，其中M是碱金属，-COOR'，-CONHR'，-CONR'R“，-OCOOR'，-OCOR'，-OCONHR' （甲基）丙烯酰氨基，（甲基）丙烯酰氧基，C6-C12芳基; 被C 1 -C 12烷基，C 1 -C 12烷氧基，CN和/或被卤素取代的C 6 -C 12芳基; C3-C12杂芳基; 被C 1 -C 12烷基，C 1 -C 12烷氧基，CN和/或被卤素取代的C 3 -C 12杂芳基; 或式I的Q，并且至少一个取代基Y1至Y9必须为Q，其中q为0或1，R为环状基团，R 1和T如权利要求1所定义。该新化合物特别适用于受阻胺，用于稳定有机材料，防止光，氧和热的破坏作用。

66. 发明授权

US5998116A Color-photographic recording material 失效
标题翻译：彩色摄影材料
公开(公告)号：US5998116A
公开(公告)日：1999-12-07
申请号：US925017
申请日：1997-09-08
申请人： Pascal Hayoz , Christophe Bulliard , David George Leppard
发明人： Pascal Hayoz , Christophe Bulliard , David George Leppard
IPC分类号： C07D249/20 , C07D251/24 , G03C1/815 , G03C7/392
CPC分类号： G03C7/39256 , G03C1/8155 , Y10S430/132
摘要： The invention relates to a color-photographic recording material comprising, on a support, a blue-sensitive, a green-sensitive and/or a red-sensitive silver-halide emulsion layer, a protection layer above the sensitive layers, and, if desired, separation layers between the sensitive layers, where at least one of said layers includes a UV absorber of the formula ##STR1## The stabilizers of the formula (1) or (1a) have good inherent stability and high light absorption; the photographic recording material described has excellent stability of the magenta, cyan and yellow layers.
摘要翻译：本发明涉及一种彩色照相记录材料，其在载体上包含感蓝敏感和/或感红卤化银乳剂层，敏感层之上的保护层，如果需要，敏感层之间的分离层，其中至少一个所述层包括下式的UV吸收剂：式（1）或（1a）的稳定剂具有良好的固有稳定性和高的光吸收; 所述的摄影记录材料具有极好的品红，青色和黄色层的稳定性。

67. 发明授权

US5869588A Polymeric compounds derived from 2-hydroxy-phenyl-s-triazines substituted with ethylenically unsaturated moieties 失效
标题翻译：衍生自被烯属不饱和部分取代的2-羟基 - 苯基-s-三嗪的聚合物
公开(公告)号：US5869588A
公开(公告)日：1999-02-09
申请号：US865148
申请日：1997-05-29
申请人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
发明人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
IPC分类号： C07D251/24 , C08F12/00 , C08F12/26 , C08F16/14 , C08F16/28 , C08F16/32 , C08F18/00 , C08F18/24 , C08F20/36 , C08F20/52 , C08F26/02 , C08F212/14 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/42 , C08F220/56 , C08F226/06 , C08K5/3492 , C09D7/12 , C09K3/00 , C09K15/30 , G03C1/815 , C08F26/06 , C08F26/08 , C08K5/34
CPC分类号： G03C1/8155 , C07D251/24 , C08F12/26 , C08F20/36 , C08K5/3492 , C09D7/1241 , C08K5/34926
摘要： The invention relates to novel 2-hydroxyphenyltriazines and to homopolymers and copolymers obtainable therefrom, as described in greater detail in claims 1 and 5; the novel compounds can be used as UV absorbers in or for organic materials.
摘要翻译：本发明涉及新的2-羟基苯基三嗪及其可从其获得的均聚物和共聚物，如权利要求1和5中更详细描述的; 新型化合物可用作有机材料中的UV吸收剂或用于有机材料。

68. 发明授权

US5668200A Stabilizer combination 失效
标题翻译：稳定剂组合
公开(公告)号：US5668200A
公开(公告)日：1997-09-16
申请号：US586267
申请日：1996-01-16
申请人： Andreas Valet , Gerhard Rytz , Pascal Hayoz
发明人： Andreas Valet , Gerhard Rytz , Pascal Hayoz
IPC分类号： G03C7/392 , C07D251/14 , C08K5/3477 , C08K5/3492 , C08L101/00 , C09D7/12
CPC分类号： C08K5/3492
摘要： A mixture comprising a compound of the formula I and a compound of the formula II ##STR1## in which n is 1 or 2; R.sub.1, R'.sub.1, R.sub.2, R'.sub.2, R.sub.3 and R.sub.4, independently of one another, are H, C.sub.1 -C.sub.12 alkyl; C.sub.2 -C.sub.6 alkenyl; C.sub.1 -C.sub.12 alkoxy; C.sub.2 -C.sub.18 alkenoxy; halogen; trifluoromethyl; C.sub.7 -C.sub.11 phenylalkyl; phenyl; phenyl which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen; phenoxy; or phenoxy which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen;R.sub.6 is hydrogen, C.sub.1 -C.sub.24 alkyl, C.sub.5 -C.sub.12 cycloalkyl or C.sub.7 -C.sub.15 phenylalkyl;R.sub.7, in the case where n=1, and R'.sub.7, independently of one another, are hydrogen or C.sub.1 -C.sub.18 alkyl; or are C.sub.1 -C.sub.12 alkyl which is substituted by OH, C.sub.1 -C.sub.18 alkoxy, allyloxy, halogen, --COOH, --COOR.sub.8, --CONH.sub.2, --CONHR.sub.9, --CON(R.sub.9)(R.sub.10), --NH.sub.2, --NHR.sub.9, --N(R.sub.9)(R.sub.10), --NHCOR.sub.11, --CN, --OCOR.sub.11, phenoxy and/or phenoxy which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen; or R.sub.7 is C.sub.3 -C.sub.50 alkyl which is interrupted by --O-- and may be substituted by OH; or R.sub.7 is C.sub.3 -C.sub.6 alkenyl; glycidyl; C.sub.5 -C.sub.12 cycloalkyl; cyclohexyl which is substituted by OH, C.sub.1 -C.sub.4 alkyl or --OCOR.sub.11 ; C.sub.7 -C.sub.11 phenylalkyl which is unsubstituted or substituted by OH, Cl or CH.sub.3 ; --CO--R.sub.12 or --SO.sub.2 --R.sub.13 ;and R.sub.7, in the case where n=2, and R.sub.8 to R.sub.23 are as defined in claim 1, is highly suitable for stabilizing organic material.
摘要翻译：包含式I化合物和其中n为1或2的式II化合物（I）其中n为1或2的混合物; R 1，R'1，R 2，R'2，R 3和R 4彼此独立地是H，C 1 -C 12烷基; C 2 -C 6烯基; C1-C12烷氧基; C2-C18链烯氧基; 卤素; 三氟甲基 C7-C11苯基烷基; 苯基; 被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯基; 苯氧基或被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯氧基; R6是氢，C1-C24烷基，C5-C12环烷基或C7-C15苯基烷基; 在n = 1的情况下，R 7，R 7彼此独立地为氢或C 1 -C 18烷基; 或被C 1 -C 18烷氧基，烯丙氧基，卤素，-COOH，-COOR 8，-CONH 2，-CONHR 9，-CON（R 9）（R 10），-NH 2，-NHR 9，-N（R 9）取代的C 1 -C 12烷基）（R 10），-NHCOR 11，-CN，-OCOR 11，被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯氧基和/或苯氧基; 或R 7为被-O-间隔并可被OH取代的C 3 -C 50烷基; 或R 7为C 3 -C 6烯基; 缩水甘油基 C5-C12环烷基; 被OH，C1-C4烷基或-OCOR11取代的环己基; 未被取代或被OH，Cl或CH3取代的C7-C11苯基烷基; -CO-R12或-SO2-R13; 和R 7，在n = 2的情况下，R 8至R 23如权利要求1中所定义，非常适用于稳定有机材料。

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